Hydrocarbon generation system and hydrocarbon generation method

Patent metadata

Field	Value
Publication number	US-11795121-B2
Application number	US-202217857255-A
Country	US
Kind code	B2
Filing date	Jul 5, 2022
Priority date	Mar 23, 2020
Publication date	Oct 24, 2023
Grant date	Oct 24, 2023

Abstract

A hydrocarbon generation system includes a first generation apparatus configured to generate a hydrocarbon with two or more carbon atoms from a first raw material containing: at least one of carbon monoxide or carbon dioxide; and hydrogen. The hydrocarbon generation system includes a second generation apparatus configured to generate methane from a second raw material including: hydrogen; and at least one of carbon monoxide or carbon dioxide contained in the first raw material and discharged from the first generation apparatus.

First claim

What is claimed is:

1. A hydrocarbon generation system comprising:
a first generation apparatus configured to generate a hydrocarbon with two or more carbon atoms from a first raw material containing:
at least one of carbon monoxide or carbon dioxide; and
hydrogen; and

a second generation apparatus configured to generate methane from a second raw material containing:
hydrogen; and
at least one of carbon monoxide or carbon dioxide contained in the first raw material and discharged from the first generation apparatus;

wherein
the first generation apparatus is provided with an iron catalyst for generating the hydrocarbon with two or more carbon atoms from the first raw material, and
the second generation apparatus is provided with a nickel catalyst for generating the methane from the second raw material.

2. The hydrocarbon generation system according to claim 1 , wherein the first generation apparatus generates the hydrocarbon with two or more carbon atoms from 20% by mass or more and less than 85% by mass of the carbon dioxide contained in the first raw material.

3. The hydrocarbon generation system according to claim 1 , wherein the second generation apparatus generates the methane from 85% by mass or more of the carbon dioxide contained in the second raw material.

4. The hydrocarbon generation system according to claim 1 , further comprising:
a carbon dioxide capture apparatus configured to capture carbon dioxide from a gas containing carbon dioxide,
wherein the carbon dioxide contained in the first raw material includes carbon dioxide separated at the carbon dioxide capture apparatus.

5. The hydrocarbon generation system according to claim 4 , wherein the carbon dioxide capture apparatus comprises:
an absorption apparatus configured to form an alkaline solution containing carbon dioxide by gas-liquid contact between a gas containing carbon dioxide and an alkaline solution; and
a separation apparatus configured to separate carbon dioxide from the alkaline solution containing carbon dioxide,
wherein the carbon dioxide contained in the first raw material includes the carbon dioxide separated at the separation apparatus.

6. The hydrocarbon generation system according to claim 5 , wherein the separation apparatus separates carbon dioxide from the alkaline solution containing carbon dioxide by using at least a part of one of heat of reaction when the hydrocarbon with two or more carbon atoms is generated in the first generation apparatus, or heat of reaction when the methane is generated in the second generation apparatus.

7. The hydrocarbon generation system according to claim 1 , wherein at least a part of one of heat of reaction when the hydrocarbon with two or more carbon atoms is generated in the first generation apparatus, or heat of reaction when the methane is generated in the second generation apparatus is recovered.

8. The hydrocarbon generation system according to claim 1 , wherein the hydrocarbon with two or more carbon atoms comprises an olefin with two or more and four or less carbon atoms.

9. The hydrocarbon generation system according to claim 1 , wherein a gas discharged from the first generation apparatus is supplied to the second generation apparatus with the pressure of the gas being maintained.

10. A hydrocarbon generation method, comprising:
a first generation step of generating, in a first generation apparatus, a hydrocarbon with two or more carbon atoms from a first raw material containing:
at least one of carbon monoxide or carbon dioxide; and
hydrogen; and

a second generation step of generating, in a second generation apparatus, methane from a second raw material containing:
hydrogen; and
at least one of carbon monoxide or carbon dioxide contained in the first raw material and discharged in the first generation step;

wherein
the first generation apparatus is provided with an iron catalyst for generating the hydrocarbon with two or more carbon atoms from the first raw material, and
the second generation apparatus is provided with a nickel catalyst for generating the methane from the second raw material.

Assignees

• Ihi Corp

Inventors

• Kamata Hiroyuki
• Choi Wonyoung
• Suda Toshiyuki
• Nariai Kentaro

Classifications

• Y02P20/151

  Reduction of greenhouse gas [GHG] emissions, e.g. CO2 · CPC title

• Y02C20/40

  of CO2 · CPC title

• C07C1/12 Primary

  from carbon dioxide with hydrogen · CPC title

• C07C1/042

  Temperature controlling devices; Heat exchangers · CPC title

• C07C1/044

  containing iron · CPC title