Composite photocatalyst structure, and photocatalytic filter and air purification device including the same

Patent metadata

Field	Value
Publication number	US-11794173-B2
Application number	US-202117387448-A
Country	US
Kind code	B2
Filing date	Jul 28, 2021
Priority date	Mar 8, 2021
Publication date	Oct 24, 2023
Grant date	Oct 24, 2023

Abstract

A composite photocatalyst, a photocatalytic filter for air purification, and an air purification device that includes the photocatalytic filter. The composite photocatalyst includes: a first metal oxide particle; and second metal oxide particles arranged on a surface of the first metal oxide particle, wherein specific surface area of the second metal oxide particles is greater than specific surface area of the first metal oxide particle, and bandgap energy of the second metal oxide particles is greater than bandgap energy of the first metal oxide particle. The composite photocatalyst structure may degrade and remove gaseous pollutants under room temperature and atmospheric pressure conditions. The composite photocatalyst may be applied to various indoor and outdoor air purification systems in the form of a photocatalytic filter.

First claim

What is claimed is:

1. A composite photocatalyst comprising:
a first metal oxide particle; and
a second metal oxide particles arranged on a surface of the first metal oxide particle,
wherein a specific surface area of the first metal oxide particle is 90 square meters per gram or less, and a specific surface area of the second metal oxide particle is 100 square meters per gram or greater, and
a bandgap energy of the second metal oxide particle is greater than a bandgap energy of the first metal oxide particle.

2. The composite photocatalyst of claim 1 , wherein the bandgap energy of the first metal oxide particle is less than 3 electron Volts, and the bandgap energy of the second metal oxide particle is greater than 3 electron Volts.

3. The composite photocatalyst of claim 1 , wherein the first metal oxide particle comprises at least one metal oxide of bismuth (Bi), vanadium (V), tungsten (W), iron (Fe), copper (Cu), nickel (Ni), silver (Ag), or an alloy metal oxides thereof.

4. The composite photocatalyst of claim 1 , wherein the first metal oxide particle is undoped, or the first metal oxide particle is doped selectively with a halogen, nitrogen, sulfur, carbon, or any combination thereof.

5. The composite photocatalyst of claim 1 , wherein the first metal oxide particle comprises a metal oxide represented by Formula 1:
BiOX  Formula 1

wherein X is a halogen.

6. The composite photocatalyst of claim 1 , wherein the second metal oxide particle comprises at least one metal oxide of titanium (Ti), zinc (Zn), zirconium (Zr), tantalum (Ta), niobium (Nb), or an alloy of metal oxides thereof.

7. The composite photocatalyst of claim 1 , wherein the second metal oxide particle comprises titanium oxide.

8. The composite photocatalyst of claim 1 , wherein the second metal oxide particle comprises a metal oxide undoped, or the second metal oxide is doped selectively with a halogen, nitrogen, sulfur, carbon, or any combination thereof.

9. The composite photocatalyst of claim 1 , wherein an average particle diameter of the first metal oxide particle is from 0.5 micrometers to 50 micrometers, and an average particle diameter of the second metal oxide particle is from 1 nanometer to 200 nanometers.

10. The composite photocatalyst of claim 1 , wherein an amount of the first metal oxide particle is in a range of 0.01 weight percent to 10 weight percent, and an amount of the second metal oxide particle is in a range of 90 weight percent to 99.99 weight percent, based on a total weight of the first metal oxide particle and the second metal oxide particle.

11. The composite photocatalyst of claim 1 , wherein at least a majority of first metal oxide particles and at least a majority of second metal oxide particles have different shapes, and each independently have a spherical shape, a tubular shape, a rod shape, a fibrous shape, a sheet shape, a conical shape, a pyramidal shape, a toroidal shape or any combined shape thereof.

12. The composite photocatalyst of claim 1 , wherein the first metal oxide particle is a micrometer-scale primary or secondary particle, and the second metal oxide particle is a nanometer-scale primary or secondary particle, and the surface of the first metal oxide particle is surrounded by a plurality of the second metal oxide particles.

13. The composite photocatalyst of claim 1 , wherein the composite photocatalyst adsorbs a gaseous pollutant in air at room temperature, the first metal oxide particle absorbs visible light, and the second metal oxide particle absorbs ultraviolet light, which results in a photolysis of adsorbed gaseous pollutant.

14. The composite photocatalyst of claim 1 , wherein the composite photocatalyst photocatalyzes in an ultraviolet wavelength range.

15. A photocatalytic filter comprising the composite photocatalyst according to claim 1 .

16. An air purification device comprising the photocatalytic filter according to claim 15 .

17. A composite photocatalyst comprising:
a first metal oxide particle, and
a second metal oxide particles arranged on a surface of the first metal oxide particle,
wherein a specific surface area of the second metal oxide particle is greater than a specific surface area of the first metal oxide particle,
wherein an amount of the second metal oxide particle is in a range of 85 weight percent to 99.99 weight percent, based on a total weight of the first metal oxide particle and the second metal oxide particle, and
a bandgap energy of the second metal oxide particle is greater than a bandgap energy of the first metal oxide particle.

Assignees

• Samsung Electronics Co Ltd
• Myongji Univ Industry And Academia Cooperation

Inventors

• Ji Sangmin
• Kwon Hyukjae
• Koo Minseok
• Kuk Sukeun
• Yang Dongsik
• Lee Hyun Chul
• Seo Joeng Gil
• So Namjun

Classifications

• B01J35/54

  Bars or plates · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J27/08 Primary

  Halides · CPC title

• B01D53/885

  Devices in general for catalytic purification of waste gases · CPC title

• B01J21/063

  Titanium; Oxides or hydroxides thereof · CPC title