Heat exchange system and preparation system of diester-based composition comprising the same

Patent metadata

Field	Value
Publication number	US-11794162-B2
Application number	US-202017600284-A
Country	US
Kind code	B2
Filing date	Jul 2, 2020
Priority date	Jul 4, 2019
Publication date	Oct 24, 2023
Grant date	Oct 24, 2023

Abstract

The present disclosure relates to a heat exchange system which is capable of saving energy consumed in a whole process by exchanging heat of different streams from each other, included in a continuous preparation system of a diester-based composition.

First claim

The invention claimed is:

1. A preparation system of a diester-based composition having a heat exchange system, the preparation system comprising:
a first alcohol tank that stores and injects a first alcohol;
a second alcohol tank that stores and injects a second alcohol;
a reaction part that performs esterification reaction of the first alcohol and a dicarboxylic acid to produce a first reaction product;
a preliminary purification part that removes an unreacted first alcohol from the first reaction product to produce a purified product;
a trans reaction part that performs trans esterification reaction of the purified product and the second alcohol to obtain a second reaction product;
a first washing part that neutralizes and washes the purified product to obtain a first neutralized product;
a second washing part that neutralizes and washes the second reaction product to obtain a second neutralized product;
a first purification part that removes an unreacted first alcohol from the first neutralized product and injects the removed unreacted first alcohol into the first alcohol tank to obtain a remaining first diester-based composition;
a second purification part that removes a mixed alcohol of an unreacted first alcohol and a second alcohol from the second neutralized product and injects the removed mixed alcohol into a mixed alcohol tank to obtain a remaining second diester-based composition;
a mixed alcohol tank that cools and stores the mixed alcohol; and
a separation part that separates the mixed alcohol into a first alcohol and a second alcohol and injects thereof into at least one among the first alcohol tank and the reaction part, and the second alcohol tank, respectively,
wherein the heat exchange system comprises a heat exchange part including one or more heat exchangers,
wherein the heat exchange part exchanges heat between:
one or more high temperature streams selected from the group consisting of a first high temperature stream discharged from the second purification part and injected into the mixed alcohol tank, a second high temperature stream discharged from the preliminary purification part and injected into the first alcohol tank, a third high temperature stream discharged from the trans reaction part and injected into the second washing part, a fourth high temperature stream discharged from the preliminary purification part and injected into the first washing part, and a fifth high temperature stream discharged from the separation part and injected into the first alcohol tank, and
one or more low temperature streams selected from the group consisting of a first low temperature stream discharged from the second washing part and injected into the second purification part, a second low temperature stream discharged from the second alcohol tank and injected into the trans reaction part, a third low temperature stream discharged from the first washing part and injected into the first purification part, and a fourth low temperature stream discharged from the mixed alcohol tank and injected into the separation part.

2. The preparation system of a diester-based composition according to claim 1 , wherein the heat exchange part exchanges heat between the selected one high temperature stream and the selected multiple low temperature streams.

3. The preparation system of a diester-based composition according to claim 1 , wherein the heat exchange part exchanges heat between the selected multiple high temperature streams and the selected one low temperature stream.

4. The preparation system of a diester-based composition according to claim 1 , wherein the heat exchange part exchanges heat between:
the first high temperature stream and the third low temperature stream,
the second and third high temperature streams and the first low temperature stream,
the fourth high temperature stream and the second low temperature stream, and
the fifth high temperature stream and the fourth low temperature stream.

5. The preparation system of a diester-based composition according to claim 1 , wherein the heat exchange part exchanges heat between:
the first high temperature stream and the second low temperature stream,
the second and third high temperature streams and the first low temperature stream,
the fourth high temperature stream and the third low temperature stream, and
the fifth high temperature stream and the fourth low temperature stream.

6. The preparation system of a diester-based composition according to claim 1 , wherein the heat exchange part exchanges heat between:
the first high temperature stream and the second low temperature stream,
the second and third high temperature streams and the first low temperature stream,
the fourth high temperature stream and the fourth low temperature stream, and
the fifth high temperature stream and the third low temperature stream.

7. The preparation system of a diester-based composition according to claim 1 , wherein the heat exchange part exchanges heat between:
the first high temperature stream and the second and fourth low temperature streams,
the second and third high temperature streams and the first low temperature stream, and
the fourth high temperature stream and the third low temperature stream.

8. The preparation system of a diester-based composition according to claim 1 , wherein the heat exchange part exchanges heat between:
the first high temperature stream and the second and fourth low temperature streams,
the second and third high temperature streams and the first low temperature stream, and
the fifth high temperature stream and the third low temperature stream.

9. The preparation system of a diester-based composition according to claim 1 , wherein the heat exchange part exchanges heat between:
the first high temperature stream and the fourth low temperature stream,
the second and third high temperature streams and the first low temperature stream,
the fourth high temperature stream and the third low temperature stream, and
the fifth high temperature stream and the second low temperature stream.

10. The preparation system of a diester-based composition according to claim 1 , wherein the heat exchange part exchanges heat between:
the first high temperature stream and the third and fourth low temperature streams,
the second and third high temperature streams and the first low temperature stream,
the fourth high temperature stream and the third low temperature stream, and
the fifth high temperature stream and the second low temperature stream.

11. The preparation system of a diester-based composition according to claim 1 , wherein the heat exchange part exchanges heat between:
the first high temperature stream and the fourth low temperature stream,
the second and third high temperature streams and the first low temperature stream,
the fourth high temperature stream and the second low temperature stream, and
the fifth high temperature stream and the third low temperature stream.

12. The preparation system of a diester-based composition according to claim 1 , wherein the heat exchange part exchanges heat between:
the first and second high temperature streams and the first low temperature stream,
the third high temperature stream and the fourth low temperature stream,
the fourth high temperature stream and the second low temperature stream, and
the fifth high temperature stream and the third low temperature stream.

13. The preparation system of a diester-based composition according to claim 1 , wherein the heat exchange part exchanges heat between:
the first and second high temperature streams and the first low temperature stream,

Assignees

• Lg Chemical Ltd

Inventors

• Jeong Jae Hun
• Lee Sung Kyu
• Choo Yeon Uk
• Jun Hyoung
• Jin Chan Hyu

Classifications

• B01J19/0013 Primary

  Controlling the temperature of the process · CPC title

• B01D3/143

  by two or more of a fractionation, separation or rectification step · CPC title

• B01J19/245

  placed in series · CPC title

• B01J2219/00074

  by indirect heating or cooling employing heat exchange fluids · CPC title

• C07C67/03 Primary

  by reacting an ester group with a hydroxy group · CPC title