Method and system for examining a fuel cell by means of a cyclic voltammetric measurement

Patent metadata

Field	Value
Publication number	US-11791485-B2
Application number	US-202017614033-A
Country	US
Kind code	B2
Filing date	Apr 17, 2020
Priority date	May 31, 2019
Publication date	Oct 17, 2023
Grant date	Oct 17, 2023

Abstract

A method of examining a fuel cell by means of a cyclic voltammetry analysis, wherein the cyclic voltammetry analysis is used to ascertain a gas composition in the fuel cell. The fuel cell has a first gas space for a first reactant and a second gas space for a second reactant, where no reactant is supplied at least to one of the two gas spaces, especially to either gas space, during the cyclic voltammetry analysis. The cyclic voltammetry analysis is used to ascertain a concentration of hydrogen in the gas spaces.

First claim

The invention claimed is:

1. A method of examining a fuel cell by means of a cyclic voltammetry analysis, the method comprising:
ascertaining a gas composition in the fuel cell using the cyclic voltammetry analysis,
wherein the fuel cell comprises a first gas space for a first reactant and a second gas space for a second reactant, where no reactant is supplied at least to one of the two gas spaces during the cyclic voltammetry analysis, and
wherein the cyclic voltammetry analysis is used to ascertain a concentration of hydrogen in the gas spaces,
the method further comprising:
monitoring of a state of a stored or nonoperational fuel cell; and/or
monitoring and/or controlling of a shutdown operation of the fuel cell.

2. The method as claimed in claim 1 , further comprising:
generating a piece of information and/or an optical signal when a criterion in relation to a threshold value is satisfied for at least one measurement in the cyclic voltammetry analysis and/or at least one value derived therefrom.

3. The method as claimed in claim 2 ,
wherein the threshold value represents a minimum permissible concentration of hydrogen in the gas spaces.

4. The method as claimed in claim 1 ,
wherein a scan rate for the cyclic voltammetry analysis of the fuel cell is less than 0.7 mV/s.

5. The method as claimed in claim 4 ,
wherein the scan rate for the cyclic voltammetry analysis of the fuel cell is between 0.15 mV/s and 0.5 mV/s.

6. The method as claimed in claim 1 , further comprising:
ascertaining a moisture content of an electrolyte in the fuel cell, and
adjusting a parameter from the cyclic voltammetry analysis comprising a scan rate, a minimum potential, and/or a maximum potential, depending on the moisture content ascertained.

7. The method as claimed in claim 6 ,
wherein the moisture content of the electrolyte in the fuel cell is ascertained by means of impedance spectroscopy.

8. The method of examining a fuel cell as claimed in claim 1 , further comprising:
generating measurements from the cyclic voltammetry analysis on the fuel cell,
transmitting the measurements and/or values derived therefrom to an evaluation device that is spatially separated from the fuel cell and/or is cloud-based, for ascertainment of the gas composition in the fuel cell depending on the values transmitted.

9. The method as claimed in claim 1 ,
where no reactant is supplied to either gas space during the cyclic voltammetry analysis.

10. A system for examining a fuel cell, comprising:
an analysis device for a cyclic voltammetry analysis on the fuel cell comprising a first gas space for a first reactant and a second gas space for a second reactant,
an evaluation device designed to ascertain a gas composition in the fuel cell depending on the cyclic voltammetry analysis,
wherein the evaluation device is designed to ascertain a concentration of hydrogen in the fuel cell,
wherein the analysis device is configured to perform the cyclic voltammetry analysis when no reactant is supplied at least to one of the two gas spaces; and
wherein the system is further configured to:
monitor a state of a stored or nonoperational fuel call; and/or
monitor and/or control a shutdown operation of the fuel cell.

11. The system as claimed in claim 10 ,
wherein the evaluation device is designed to generate a piece of information, and/or an optical signal, when a criterion in relation to a threshold value is satisfied for at least one measurement in the cyclic voltammetry analysis and/or at least one value derived therefrom.

12. The system as claimed in claim 11 ,
wherein the threshold value represents a minimum permissible concentration of hydrogen in the gas spaces.

13. The system as claimed in claim 10 , further comprising:
a device for ascertaining a moisture content of an electrolyte in the fuel cell
wherein the analysis device is designed to adjust a parameter from the cyclic voltammetry analysis comprising a scan rate, a minimum potential, and/or a maximum potential, depending on the moisture content ascertained.

14. The system as claimed in claim 13 ,
wherein the moisture content of the electrolyte in the fuel cell is ascertained by means of impedance spectroscopy.

15. A fuel cell apparatus, comprising:
at least one fuel cell; and
the system for examining the fuel cell as claimed in claim 10 .

Assignees

• Siemens Energy Global Gmbh & Co Kg

Inventors

• Braunecker Michael
• Reiner Andreas

Classifications

• H01M8/04447 Primary

  of anode reactants at the inlet or inside the fuel cell · CPC title

• H01M8/04201

  Reactant storage and supply, e.g. means for feeding, pipes · CPC title

• H01M8/04529

  of the electrolyte · CPC title

• H01M8/04955

  Shut-off or shut-down of fuel cells · CPC title

• H01M8/0447 Primary

  of cathode exhausts · CPC title