Emulsifier package with quaternary ammonium surfactant for fuel emulsion

Patent metadata

Field	Value
Publication number	US-11788024-B2
Application number	US-202017608360-A
Country	US
Kind code	B2
Filing date	Apr 23, 2020
Priority date	May 3, 2019
Publication date	Oct 17, 2023
Grant date	Oct 17, 2023

Abstract

A fuel emulsion for powering a diesel engine contains water, a fuel, and an emulsifier package which contains a quaternary ammonium surfactant. A method for powering a diesel engine with the fuel emulsion involves preparing the fuel emulsion by emulsifying a fuel and water in the presence of the emulsifier package. An emulsifier package for emulsifying a fuel and water contains a quaternary ammonium surfactant and at least one nonionic surfactant, which is an alkoxylate. The quaternary ammonium surfactant is obtainable by reacting a quaternizable nitrogen compound containing at least one quaternizable, especially tertiary, amino group with a quaternizing agent; which converts the at least one quaternizable, especially tertiary, amino group to a quaternary ammonium group, where the quaternizing agent is a hydrocarbyl epoxide in combination with a free hydrocarbyl-substituted polycarboxylic acid.

First claim

The invention claimed is:

1. A fuel emulsion for powering a diesel engine, comprising:
water,
a fuel, and
an emulsifier package, which comprises a quaternary ammonium surfactant which is a reaction product obtained by
reacting a quaternizable nitrogen compound comprising at least one quaternizable amino group with a quaternizing agent, which converts the at least one quaternizable amino group to a quaternary ammonium group,
wherein the quaternizing agent is a hydrocarbyl epoxide in combination with a free hydrocarbyl-substituted polycarboxylic acid.

2. The fuel emulsion according to claim 1 , wherein the emulsifier package comprises at least one nonionic surfactant, which is an alkoxylate.

3. The fuel emulsion according to claim 1 , wherein the emulsifier package comprises at least two nonionic surfactants, which are alkoxylates selected from the group consisting of an ethoxylate of fatty amide, castor oil ethoxylate, and ethoxylated fatty alcohol.

4. The fuel emulsion according to claim 2 , wherein the emulsifier package comprises at least 60 wt % of the at least one nonionic surfactant.

5. The fuel emulsion according to claim 1 , wherein the emulsifier package comprises 1 to 40 wt % of the quaternary ammonium surfactant.

6. The fuel emulsion according to claim 1 , wherein the fuel emulsion comprises the emulsifier package in an amount of 0.05 to 0.5 wt %, based on the fuel emulsion.

7. The fuel emulsion according to claim 1 , wherein the fuel emulsion is an oil-in-water emulsion.

8. The fuel emulsion according to claim 1 , wherein the fuel emulsion comprises 50 to 80 wt % water.

9. The fuel emulsion according to claim 1 , wherein the fuel is marine fuel.

10. A method for powering a diesel engine with a fuel emulsion, the method comprising:
preparing the fuel emulsion according to claim 1 by emulsifying the fuel and water in the presence of the emulsifier package.

11. An emulsifier package for emulsifying a fuel and water, comprising:
a quaternary ammonium surfactant, which is obtained by reacting a quaternizable nitrogen compound comprising at least one quaternizable amino group with a quaternizing agent, which converts the at least one quaternizable amino group to a quaternary ammonium group, wherein the quaternizing agent is a hydrocarbyl epoxide in combination with a free hydrocarbyl-substituted polycarboxylic acid, and
at least one nonionic surfactant, which is an alkoxylate.

12. The emulsifier package according to claim 11 , comprising at least two nonionic surfactants, which are alkoxylates selected from the group consisting of an ethoxylate of fatty amide, castor oil ethoxylate, and ethoxylated fatty alcohol.

13. The emulsifier package according to claim 11 , comprising 1 to 40 wt % of the quaternary ammonium surfactant.

14. The emulsifier package according to claim 11 , comprising at least 60 wt % of the at least one nonionic surfactant.

15. The fuel emulsion according to claim 1 , wherein the at least one quaternizable amino group is at least one quaternizable tertiary amino group.

16. The emulsifier package according to claim 11 , wherein the at least one quaternizable amino group is at least one quaternizable tertiary amino group.

17. The fuel emulsion according to claim 1 , wherein said fuel is at least one marine fuel selected from the group consisting of Marine gas oil, Marine diesel oil, Intermediate fuel oil, Marine fuel oil, Heavy fuel oil, an Intermediate fuel oil with a maximum viscosity of 380 centistokes (<3.5% sulphur), an Intermediate fuel oil with a maximum viscosity of 180 centistokes (<3.5% sulphur), a Low-sulphur (<1.0%) intermediate fuel oil with a maximum viscosity of 380 centistokes, a Low-sulphur (<1.0%) intermediate fuel oil with a maximum viscosity of 180 centistokes, a Low-sulphur (<0.1%) Marine Gas Oil according to EU Sulphur directive 2005/33/EC, or an Ultra-Low-Sulphur Marine Gas Oil and fuels according to DIN ISO 8217.

18. The fuel emulsion according to claim 1 , wherein said fuel is at least one selected from the group consisting of ISO-F-DMX, DMA, DFA, DMZ, DFZ, DFB, ISO-F RMA, RMB, RMD, RME, RMG and RMK.

19. The fuel emulsion according to claim 1 , wherein said fuel has a sulfur content of less than 1 wt. %.

Assignees

• Basf Se

Inventors

• Harhausen Marcel
• Schoeppe Thorsten

Classifications

• C10L1/328 Primary

  Oil emulsions containing water or any other hydrophilic phase · CPC title

• C10L1/143

  mixtures of organic macromolecular compounds with organic non-macromolecular compounds · CPC title

• C10L1/2225

  hydroxy containing (C10L1/221 takes precedence) · CPC title

• C10L2250/084

  Water in oil (w/o) emulsion · CPC title

• C10L1/2222 Primary

  (cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates (C10L1/221 takes precedence) · CPC title