Process for production of needle coke

Patent metadata

Field	Value
Publication number	US-11788013-B2
Application number	US-202117478692-A
Country	US
Kind code	B2
Filing date	Sep 17, 2021
Priority date	Sep 18, 2020
Publication date	Oct 17, 2023
Grant date	Oct 17, 2023

Abstract

High-quality graphite/needle grade coke is produced with reduced impurity levels and improved coefficient of thermal expansion using an integrated hydrotreatment, catalytic cracking and coking reaction sections, employing a combination of highly paraffinic hydrotreated VGO stream and aromatic CLO stream, which is thereafter processed in a delayed coking section.

First claim

The invention claimed is:

1. A process for production of graphite/needle grade coke with reduced impurity levels and improved coefficient of thermal expansion, wherein the process comprises:
(a) routing a vacuum gas oil (VGO) feed to a riser reactor of a fluid catalytic cracking unit, wherein the VGO feed reacts with a hot catalyst supplied from a regenerator, and wherein the fluid catalytic cracking unit is operated at a reactor outlet temperature of 550 to 650° C., at a pressure in a range of 0.7 to 2.5 Kg/cm 2 (g) and having a catalyst to oil ratio in a range of 10 to 25;
(b) sending products of reaction from step (a) along with a catalyst to a stripper for separation of a hydrocarbon vapor product from the catalyst;
(c) sending the hydrocarbon vapor product to a first fractionator column for separation into different products comprising off gases with naphtha, light cycle oil (LCO), and heavy cycle oil (HCO);
(d) mixing a VGO stream with H 2 and sending to a furnace for heating to obtain a hot feed;
(e) sending the hot feed from step (d) to a fixed bed reactor, wherein hydrotreatment of the VGO stream occurs to obtain a hydrotreated VGO stream at a reactor pressure in a range of 30-55 Kg/cm 2 (g) and a temperature in a range of 300-380° C., and wherein reaction products are sent to a high-pressure separator where lighter gases are removed and sent to a low-pressure separator;
(f) sending a liquid after removing the lighter gases from the reaction products to a second fractionator column for further separation of lighter products;
(g) routing a stream consisting of the hydrotreated VGO stream from the second fractionator column and a clarified oil (CLO) product fraction to a bottom section of the first fractionator column, wherein the clarified oil (CLO) product fraction is generated in the fluid catalytic cracking unit, wherein the hydrotreated VGO stream comprises aromatics about 19 wt % and a mixture of paraffins and naphthenes about 80 wt %, wherein the CLO product fraction comprises aromatics about 98 wt % and a mixture of paraffins and naphthenes about 2 wt %;
(h) exchanging heat between the hydrotreated VGO stream and the CLO product fraction occurring in the bottom section of the first fractionator column and forming a homogenous mixture, wherein a lighter fraction in the hydrotreated VGO stream boiling at a temperature of not more than 350° C. is separated in the first fractionator column, wherein weight percentage of the hydrotreated VGO stream in the homogenous mixture is in a range of 20-50 wt %;
(i) sending the homogenous mixture through a parallel filtration assembly for separation of entrained catalyst fines present; and
(j) routing the homogenous mixture after catalyst removal to a third fractionator column of a delayed coking section.

2. The process as claimed in claim 1 , wherein the homogenous mixture is mixed with an internal recycle fraction in the third fractionator column of the delayed coking section and is withdrawn from the third fractionator column as a secondary feed.

3. The process as claimed in claim 2 , wherein the secondary feed is heated in a furnace and a hot feed is produced.

4. The process as claimed in claim 3 , wherein the hot feed is sent to coke drums operated at a temperature in a range of 460-515° C., drum pressure in a range of 2-10 Kg/cm 2 (g) and cycle time of 18-42 hrs for delayed coking reaction.

5. The process as claimed in claim 1 , wherein a vapor product generated in the coke drums is sent to the third fractionator column for further separation into various streams comprising off gas with naphtha, light coker gas oil (LCGO), heavy coker gas (HCGO) and coker fuel oil (CFO).

6. The process as claimed in claim 1 , wherein a needle coke produced in the coke drums is removed after a filling cycle by high pressure water jet cutting.

7. The process as claimed in claim 1 , wherein after step (f) an aromatic CLO stream is injected at a bottom section of the second fractionator column to mix with the hydrotreated VGO stream.

8. The process as claimed in claim 1 , wherein sulfur content of the CLO product fraction is not more than 1 wt % and sulfur content of the hydrotreated VGO stream is not more than 0.4 wt %.

Assignees

• Indian Oil Corp Ltd

Inventors

• Pradeep Ponoly Ramachandran
• Dixit Shivam Ashok
• Mondal Prantik
• Brahma Jitumoni
• Rajesh
• Prasad Terapalli Hari Venkata Devi
• Das Satyen Kumar
• Sau Madhusudan
• Kapur Gurpreet Singh
• RAMAKUMAR Sankara Sri Venkata

Classifications

• C10B57/08 Primary

  Non-mechanical pretreatment of the charge (C10L9/00 takes precedence), {e.g. desulfurization} · CPC title

• C10B55/00

  Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material (cracking oils C10G) · CPC title

• C10B57/02

  Multi-step carbonising or coking processes · CPC title

• C10G7/00

  Distillation of hydrocarbon oils · CPC title

• C10G9/005 Primary

  Coking (in order to produce liquid products mainly) · CPC title