Stress features for crack redirection and protection in glass containers

Patent metadata

Field	Value
Publication number	US-11787735-B2
Application number	US-202117376912-A
Country	US
Kind code	B2
Filing date	Jul 15, 2021
Priority date	Jul 20, 2020
Publication date	Oct 17, 2023
Grant date	Oct 17, 2023

Abstract

A glass container comprises a glass body comprising a first region under a compressive stress extending from a surface of the glass body to a depth of compression and a second region extending from the depth of compression into a thickness of the glass body, the second region being under a tensile stress. The glass container also includes a localized compressive stress region having a localized compressive stress extending from the surface to a localized depth of compression within the body. The localized depth of compression is greater than the depth of compression of the first region. The glass container also includes a crack re-direction region extending in a predetermined propagation direction, wherein the crack re-direction region possesses a higher tensile stress than the tensile stress in the second region in a sub-region of the crack re-direction region, the sub-region extending substantially perpendicular to the predetermined propagation direction.

First claim

What is claimed is:

1. A glass container comprising:
a body comprising a glass composition, the body having an interior surface, an exterior surface, and a wall thickness extending between the interior surface and the exterior surface, wherein the body comprises a localized compressive stress region having a localized compressive stress extending from the exterior surface to a localized depth of compression within the body, wherein:
the localized compressive stress region extends farther into the body than any regions of compressive stress adjacent to the localized compressive region.

2. The glass container of claim 1 , wherein the glass container comprises a pharmaceutical container.

3. The glass container of claim 1 , wherein the localized depth of compression extends greater than or equal to 2% of the wall thickness and less than or equal to 25% of the wall thickness.

4. The glass container of claim 3 , wherein the localized depth of compression extends greater than or equal to 20% of the wall thickness and less than or equal to 25% of the wall thickness.

5. The glass container of claim 1 , wherein the localized compressive stress region comprises a compressive stress of greater than or equal to 50 MPa.

6. The glass container of claim 2 , wherein the localized compressive stress region comprises a surface compressive stress of greater than or equal to 75 MPa.

7. The glass container of claim 3 , wherein the surface compressive stress is greater than or equal to 100 MPa.

8. The glass container of claim 1 , wherein the localized compressive stress region overlaps with a compressively stressed layer of the glass container under a compressive stress such that, within the localized compressive stress region, the body comprises the compressive stress of the compressively stressed layer to the first depth of compression and the localized depth of stress from the first depth of compression to the localized depth of compression.

9. The glass container of claim 1 , wherein the glass composition comprises an aluminosilicate glass composition.

10. The glass container of claim 1 , wherein the glass container comprises a vial having a base, a barrel connected to the base via a heel, a shoulder extending from the barrel, and a neck extending from the shoulder, wherein the localized compressive stress region is disposed in at least one of the neck, the heel, and the barrel.

11. The glass container of claim 10 , wherein the localized compressive stress region is disposed in the heel.

12. The glass container of claim 1 , further comprising an additional localized compressive stress region having an additional localized compressive stress extending from the interior surface to an additional localized depth of compression within the body.

13. The glass container of claim 12 , wherein localized compressive stress region and the additional localized compressive stress region oppose one another to form a region of central tension between the localized compression stress region and the additional localized compressive stress region, wherein the region of central tension facilitates branching of a crack propagating through the wall thickness to render the glass container unusable.

14. A glass container comprising:
a glass body comprising a first region under a compressive stress extending from a surface of the glass body to a depth of compression and a second region extending from the depth of compression into a thickness of the glass body, the second region being under a tensile stress; and
a localized compressive stress region having a localized compressive stress extending from the surface to a localized depth of compression within the body, wherein:
the localized depth of compression is greater than or equal to 2% of the wall thickness of the body and less than or equal to 25% of the wall thickness of the body, and
the localized depth of compression is greater than the depth of compression of the first region.

15. The glass container of claim 14 , wherein the localized compressive stress region overlaps with the first region such that, within the localized compressive stress region, the glass body possesses the compressive stress of the first region to the first depth of compression and the localized depth of stress from the first depth of compression to the localized depth of compression.

16. The glass container of claim 14 , wherein the localized compressive stress region comprises a compressive stress of greater than or equal to 50 MPa.

17. The glass container of claim 14 , wherein the surface of the glass body is an exterior surface of the glass container.

18. A method forming a glass container having a localized compressive stress region, the method comprising:
providing a stock material formed from a glass composition;
shaping the stock material into a glass article having a body with a thickness extending between an interior surface and an exterior surface, the body defining an interior volume;
forming a localized compressive stress region in the glass article, the localized compressive stress region having a localized compressive stress extending from the exterior surface or the interior surface to a localized depth of compression within the body, wherein the localized depth of compression is greater than or equal to 2% of the thickness and less than or equal to 25% of the thickness, wherein forming the localized compressive stress region comprises locally applying a coolant to a portion of the glass article when the glass article is heated to a starting temperature above a softening temperature of the glass composition such that the localized compressive stress region extends farther into the body than any regions of compressive stress adjacent to the localized compressive region.

19. The method of claim 18 , further comprising subjecting the glass article to ion-exchange strengthening after forming the localized compressive stress region to form a first region on the exterior surface under a compressive stress, the first region extending from the exterior surface to a depth of compression that is less than the localized depth of compression.

20. The method of claim 18 , wherein locally applying the coolant to the portion of the glass article induces a transient tensile stress in a central portion of the thickness that induces propagation of any cracks formed in the central portion.

21. The method of claim 18 , further comprising flame washing an entirety of the exterior surface prior to forming the localized compressive stress region to eliminate conversion flaws induced by the shaping of the stock material into the glass article.

22. The method of claim 18 , wherein locally applying the coolant to the portion of the glass article comprises:
positioning a collar proximate to the portion of the glass article when the glass article is heated to the starting temperature, the collar including at least one feed for the coolant, wherein the collar is shaped in a manner that corresponds to the portion of the glass article, wherein the collar comprises contact points that contact the portion of the glass article to control a gap between a fluid manifold of the collar and the portion of the glass article; and
providing the coolant to the portion of the glass article to form the localized compressive stress region.

23. The method of claim 18 , wherein the glass article is not subjected to annealing heat treatments after the formation of the localized compressive stress region.

Assignees

• Corning Inc

Inventors

• Demartino Steven Edward
• Domey Jeffrey John
• Timmons Christopher Lee

Classifications

• C03C21/002 Primary

  to perform ion-exchange between alkali ions (C03C21/005 takes precedence) · CPC title

• A61J1/1468

  Containers characterised by specific material properties · CPC title

• C03B23/04

  Re-forming tubes or rods · CPC title

• C03B27/012

  by heat treatment, e.g. for crystallisation; Heat treatment of glass products before tempering by cooling (C03B27/008, C03B27/016 take precedence) · CPC title

• C03C23/0025

  by a laser beam · CPC title