Aqueous suspension comprising a zeolitic material and a zirconium chelate complex

Patent metadata

Field	Value
Publication number	US-11786887-B2
Application number	US-201917309443-A
Country	US
Kind code	B2
Filing date	Dec 6, 2019
Priority date	Dec 6, 2018
Publication date	Oct 17, 2023
Grant date	Oct 17, 2023

Abstract

An aqueous suspension comprising water, a zeolitic material and one or more of copper and iron, and a chelate complex comprising a zirconium ion and a bidentate organic ligand bonded to said zirconium ion via zirconium oxygen bonds from two oxygen atoms comprised in said ligand, said chelate complex being dissolved in the water.

First claim

The invention claimed is:

1. An aqueous suspension comprising:
(i) water;
(ii) a zeolitic material and one or more ions of copper and iron, wherein the copper and iron is either comprised in the zeolitic material, in a source of copper and iron, or in the zeolitic material and in a source of one or more of copper and iron; and
(iii) an aqueous chelate complex solution comprising a zirconium ion and a bidentate organic ligand bonded to the zirconium ion via zirconium oxygen bonds from two oxygen atoms comprised in the ligand.

2. The suspension of claim 1 , wherein the zeolitic material according to (ii) has framework type chosen from ABW, ACO, AEI, AEL, AEN, AET, AFG, AFI, AFN, AFO, AFR, AFS, AFT, AFV, AFX, AFY, AHT, ANA, APC, APD, AST, ASV, ATN, ATO, ATS, ATT, ATV, AVL, AWO, AWW, BCT, BEA, BEC, BIK, BOF, BOG, BOZ, BPH, BRE, BSV, CAN, CAS, CDO, CFI, CGF, CGS, CHA, -CHI, -CLO, CON, CSV, CZP, DAC, DDR, DFO, DFT, DOH, DON, EAB, EDI, EEI, EMT, EON, EPI, ERI, ESV, ETR, EUO, *-EWT, EZT, FAR, FAU, FER, FRA, GIS, GIU, GME, GON, GOO, HEU, IFO, IFR, -IFU, IFW, IFY, IHW, IMF, IRN, IRR, -IRY, ISV, ITE, ITG, ITH, *-ITN, ITR, ITT, -ITV, ITW, IWR, IWS, IWW, IWW, JBW, JNT, JOZ, JRY, JSN, JSR, JST, JSW, KFI, LAU, LEV, LIO, -LIT, LOS, LOV, LTA, LTF, LTJ, LTL, LTN, MAR, MAZ, MEI, MEL, MEP, MER, MFI, MFS, MON, MOR, MOZ, *MRE, MSE, MSO, MTF, MTN, MTT, MTW, MVY, MWF, MWW, NAB, NAT, NES, NON, NPO, NPT, NSI, OBW, OFF, OKO, OSI, OSO, OWE, -PAR, PAU, PCR, PHI, PON, POS, PSI, PUN, RHO, -RON, RRO, RSN, RTE, RTH, RUT, RWR, RWY, SAF, SAO, SAS, SAT, SAV, SBE, SBN, SBS, SBT, SEW, SFE, SFF, SFG, SFH, SFN, SFO, SFS, *SFV, SFW, SGT, SIV, SOD, SOF, SOS, SSF, *-SSO, SSY, STF, STI, *STO, STT, STW, -SVR, SVV, SZR, TER, THO, TOL, TON, TSC, TUN, UEI, UFI, UOS, UOV, UOZ, USI, UTL, UWY, VET, VFI, VNI, VSV, WEI, -WEN, YUG, ZON, a mixture of two or more thereof, and a mixed type of two or more thereof.

3. The suspension of claim 1 , wherein from 95 wt. % to 100 wt. %, of the framework structure of the zeolitic material according to (ii) consist of Si, Al, O, and optionally one or more of H and P, and wherein the framework structure of the zeolitic material according to (ii), comprises the molar ratio of Si to Al, calculated as SiO 2 :Al 2 O 3 range from
2:1 to 50:1.

4. The suspension of claim 1 , wherein according to (ii), the suspension comprises a zeolitic material and copper, wherein the copper is comprised in the zeolitic material, in a source of copper, or in the zeolitic material and in a source of copper.

5. The suspension of claim 4 , wherein the suspension according to (iii) does not comprise a source of copper, in addition to the zeolitic material comprising copper.

6. The suspension of claim 1 , wherein the bidentate organic ligand according to (iii) comprises one or more of an alpha hydroxy acid, a beta hydroxy acid, a 2,4-diketone, and a 1,3-dicarbonyl compound.

7. The suspension of claim 1 , wherein the bidentate organic ligand according to (iii) consists of the elements carbon, hydrogen and oxygen.

8. The suspension of claim 1 , wherein the weight ratio of the water employed according to (i) relative to the total weight of Si, Al and O of the zeolitic material framework structure employed according to (ii), weight(water):weight(total sum of Si, Al and O of the zeolitic material), ranges from 80:20 to 40:60.

9. The suspension claim 1 , wherein the weight ratio of the zirconium ion comprised in the complex according to (iii), calculated as zirconium (IV) oxide, relative to the total weight of Si, Al and O of the zeolitic material framework structure according to (ii), weight(zirconium oxide): weight(total sum of framework Si, Al and O of the zeolitic material), ranges from 0.02:1 to 0.1:1.

10. The suspension of claim 1 , wherein the weight ratio of the bidentate organic ligand relative to the zirconium ion, calculated as zirconium (IV) oxide ranges from 0.01 to 2.0.

11. The suspension claim 1 , wherein the liquid phase of the suspension has a pH ranging from 0 to 12, determined at 100 s-1.

12. The suspension of claim 1 , further comprising:
(iv) at least one refractory metal oxide or a precursor thereof,
wherein the refractory metal oxide or precursor thereof comprises one or more of an alumina, a silica, a titania, an aluminum hydroxide, an aluminum oxyhydroxide, an aluminum salt, a colloidal alumina, a silicon alcoholate, a colloidal silica, a fumed silica, a water glass, a titanium alcoholate, and a colloidal titania
wherein the weight ratio of the refractory metal oxide or precursor thereof relative to the total weight of the framework Si, Al and O of the zeolitic material, weight(iv):weight(total sum of framework Si, Al and O of the zeolitic material), ranges from 0.01:1 to 0.13:1.

13. The suspension of claim 12 , wherein the liquid phase of the suspension has a pH ranging from 0 to 12, and having a viscosity ranging from 2 mPas to 1000 mPas, determined at 100 s-1.

14. The suspension of claim 1 , wherein the zeolitic material according to (ii) has a particle size distribution with a Dv90 value ranging from 0.5 micrometer to 100 micrometer.

15. The suspension of claim 1 , wherein the suspension has a storage stability ranging from 1 d to 120 d.

16. The aqueous suspension according to claim 1 , wherein the aqueous suspension is prepared as a selective catalytic reduction catalyst, or as a selective catalytic reduction catalyst for the treatment of the exhaust gas stream of a diesel engine.

17. A process for preparing an aqueous suspension, wherein the process comprises:
(a) mixing water and a zirconium salt;
(b) adding a bidentate organic ligand to the mixture obtained from (a), and obtaining an aqueous chelate complex solution comprising a zirconium ion and the bidentate organic ligand bonded to the zirconium ion via zirconium oxygen bonds from two oxygen atoms comprised in the ligand; and
(c) adding a zeolitic material and one or more ions of copper and iron to the aqueous solution obtained from (b), and obtaining an aqueous suspension, wherein the copper and iron is either comprised in the zeolitic material, or in a source of copper and iron, or in the zeolitic material and in a source of copper and iron.

Assignees

• Basf Se
• Basf Corp

Inventors

• Hemgesberg Maximilian
• Ranft Meik
• Schneider Edith
• Buchholz Marko
• Schlesinger Maik
• Schwall Denis
• Liu Yi

Classifications

• B01J35/40

  characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title

• B01J29/763 Primary

  CHA-type, e.g. Chabazite, LZ-218 · CPC title

• B01D53/9418

  for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas · CPC title

• B01J35/023

  Operations & Transport · mapped topic

• B01J37/0219

  the coating containing organic compounds · CPC title