CMS membrane, method for the production thereof and use thereof

Patent metadata

Field	Value
Publication number	US-11786870-B2
Application number	US-201917277368-A
Country	US
Kind code	B2
Filing date	Sep 16, 2019
Priority date	Sep 21, 2018
Publication date	Oct 17, 2023
Grant date	Oct 17, 2023

Abstract

Disclosed are a CMS membrane, characterized in that it is obtainable by pyrolysis of a polyimide composed of the monomers 1-(4-aminophenyl)-1,3,3-trimethyl-2H-inden-5-amine and 5-(1,3-dioxo-2-benzofuran-5-carbonyl-2-benzofuran-1,3-dione of the following formulae:

preferably by pyrolysis of the polyimide having the CAS number 62929-02-6, and a supported CMS membrane comprising a CMS membrane obtainable from a polyimide by pyrolysis and a porous support, characterized in that a mesoporous intermediate layer is provided between the CMS membrane and the porous support.

Further disclosed are a process for preparing the supported membrane, the use of the membranes for separating gas mixtures or liquid mixtures, an apparatus for gas separation or for liquid separation, and the use of the polyimide for preparing a CMS membrane by pyrolysis.

First claim

The invention claimed is:

1. A supported CMS membrane comprising a CMS membrane obtainable from a polyimide by pyrolysis and a porous support, wherein;
a mesoporous intermediate layer is provided between the CMS membrane and the porous support,
the polyimide is composed of the monomers 1-(4-aminophenyl)-1,3,3-trimethyl-2H-inden-5-amine and 5-(1,3-dioxo-2-benzofuran-5-carbonyl-2-benzofuran-1,3-dione of the following formulae:

the pores in the mesoporous intermediate layer have an average pore diameter of 3 to 6 nm, determined by porosimetry of the final supported membrane,
the pores in the porous support have an average pore diameter of 60 to 90 nm, determined by scanning electron microscopy,
the polyimide is a polyimide of CAS No. 62929-02-6, and
the CMS membrane has a pore size in the range of the kinetic diameter of CO 2 of 0.33 nm.

2. A process for preparing the supported CMS membrane according to claim 1 , comprising the following steps:
i) applying a suitable precursor sol to the porous support,
ii) calcining, thereby forming the mesoporous intermediate layer,
iii) applying the polyimide by dip coating followed by drying,
iv) pyrolysis, and
v) cooling to room temperature.

3. The process according to claim 2 , wherein:
steps i) and ii) are each repeated once, and
calcining is carried out at 500 to 700° C. in air, and/or
the pyrolysis is carried out in vacuum at 10 −5 to 10 −7 mbar and by step-wise heating.

4. The process according to claim 2 , wherein the immersion and removal during dip coating in step iii) is carried out at a speed of 5 to 15 mm/s and the immersion time is 10 to 30 s and/or a solution of the polyimide in N-methyl-2-pyrrolidone is used.

5. A method of use of the supported CMS membrane according to claim 1 for the separation of gas mixtures or for the separation of liquid mixtures comprising:
applying a gas mixture or a liquid mixture to the supported CMS membrane, and
collecting retentate and permeate from the supported CMS membrane separately.

6. The method according to claim 5 , wherein the gas mixtures are H 2 /CO 2 or H 2 /CH 4 mixtures.

7. The method according to claim 5 , wherein:
the fluid mixture comprises one or more alcohols, and
the method is used for dehydration of the one or more alcohols.

8. The method according to claim 7 , wherein the one or more alcohols comprise methanol or ethanol.

9. An apparatus for gas separation or for liquid separation, comprising the supported CMS membrane according to claim 1 .

Assignees

• Forschungszentrum Juelich Gmbh

Inventors

• Ngamou Patrick Tchoua
• Ivanova Mariya E
• Meulenberg Wilhelm Albert
• Guillon Olivier

Classifications

• B01D71/021 Primary

  Carbon · CPC title

• B01D2323/081

  Heating · CPC title

• B01D69/1216

  Three or more layers · CPC title

• B01D2325/02832

  1-10 nm · CPC title

• B01D69/108

  Inorganic support material · CPC title