Negative electrode including silicon nanoparticles having a carbon coating thereon

Patent metadata

Field	Value
Publication number	US-11784305-B2
Application number	US-201916539647-A
Country	US
Kind code	B2
Filing date	Aug 13, 2019
Priority date	Oct 28, 2016
Publication date	Oct 10, 2023
Grant date	Oct 10, 2023

Abstract

An example of a negative electrode includes silicon nanoparticles having a carbon coating thereon. The carbon coating has an oxygen-free structure including pentagon rings. The negative electrode with the silicon nanoparticles having the carbon coating thereon may be incorporated into a lithium-based battery. In an example of a method, silicon nanoparticles are provided. A carbon precursor is applied on the silicon nanoparticles. The carbon precursor is an oxygen-free, fluorene-based polymer. Then the silicon nanoparticles are heated in an inert gas atmosphere to form the carbon coating on the silicon nanoparticles. The carbon coating formed on the silicon nanoparticles has an oxygen-free structure including pentagon rings.

First claim

What is claimed is:

1. A method, comprising:
providing silicon nanoparticles;
applying a carbon precursor on the silicon nanoparticles, the carbon precursor being an oxygen-free, fluorene-based polymer; and
then heating the silicon nanoparticles in an inert gas atmosphere, thereby forming a carbon coating on the silicon nanoparticles, the carbon coating having an oxygen-free structure including pentagon rings.

2. The method as defined in claim 1 , wherein the oxygen-free, fluorene-based polymer includes an allyl group.

3. The method as defined in claim 1 , the providing comprises providing silicon nanoparticles having a particle size ranging from about 30 nm to about 100 nm.

4. The method as defined in claim 1 , wherein the applying of the carbon precursor on the silicon nanoparticles is accomplished by,
mixing the carbon precursor, the silicon nanoparticles, and a solvent to form a slurry, and
drying the slurry.

5. The method as defined in claim 4 , wherein the slurry includes the carbon precursor in an amount 1 weight percent to about 10 weight percent and the silicon nanoparticles in an amount ranging from about 10 weight percent to about 50 weight percent.

6. The method as defined in claim 1 , wherein a weight ratio of the carbon precursor to the silicon nanoparticles is 1:5.

7. The method as defined in claim 1 , wherein the heating of the silicon nanoparticles is accomplished at a temperature ranging from about 650° C. to about 750° C.

8. The method as defined in claim 1 , wherein the heating is performed for a time period ranging from about 1 hour to about 10 hours.

9. The method as defined in claim 1 , further comprising synthesizing the carbon precursor via condensation reaction of a first fluorene-based monomer and a second fluorene-based monomer.

10. The method as defined in claim 9 , wherein
the first fluorene-based monomer is selected from a group consisting of:
(a) 9,9-dioctylfluorene-2,7-diboronic acid bis(1,3-propanediol) ester

(b) 9,9-Dihexylfluorene-2,7-diboronic acid bis(1,3-propanediol) ester

(c) 9,9-Didodecylfluorene-2,7-diboronic acid

 or
(d) 9,9-Dihexylfluorene-2,7-diboronic acid

 and

the second fluorene-based monomer is selected from a group consisting of:
(a) 2,7-dibromofluorene

(b) 2,7-Dibromo-9,9-dimethyl-9H-fluorene

(c) 2,7-Dibromo-9,9-diallyl-9H-fluorene

(d) 9,9-Didodecyl-2,7-dibromofluorene

 or
(e) 9,9-Dihexyl-2,7-dibromofluorene

11. The method as defined in claim 10 , wherein
the first fluorene-based monomer is the 9,9-dioctylfluorene-2,7-diboronic acid bis(1,3-propanediol) ester

 and
the second fluorene-based monomer is the 2,7-dibromofluorene

12. The method as defined in claim 9 , wherein a molar ratio of the first fluorene-based monomer to the second fluorene-based monomer is about 1:1.

13. The method as defined in claim 9 , wherein synthesizing comprises,
stirring a mixture of the first fluorene-based monomer, the second fluorene-based monomer, a solvent, and a catalyst to form the carbon precursor, and
separating the carbon precursor from a remainder of the mixture.

14. The method as defined in claim 13 , wherein the separating comprises,
vacuum filtration or centrifugal force separation.

15. The method as defined in claim 13 , wherein the catalyst comprises a palladium-based catalyst.

16. The method as defined in claim 1 , further comprising:
dry mixing the silicon nanoparticles having the carbon coating thereon into a mixture, the mixture including a conductive filler;
adding a binder and a solvent to the mixture;
mixing the mixture to form a slurry;
depositing the slurry onto a support; and
drying the slurry.

17. The method as defined in claim 16 , further comprising adding an additional active material to the mixture, wherein the additional active material is selected from the group consisting of graphite, tin, alloys of tin, antimony, alloys of antimony, crystalline silicon, amorphous silicon, silicon oxide, and silicon alloys.

18. The method as defined in claim 1 , wherein the oxygen-free, fluorene-based polymer is formed via a condensation reaction between a first fluorene-based monomer and a second fluorene-based monomer.

19. The method as defined in claim 18 , wherein the first fluorene-based monomer comprises boron and the second fluorene-based monomer comprises bromine.

20. A method, comprising:
providing silicon nanoparticles;
applying a carbon precursor on the silicon nanoparticles, the carbon precursor being an oxygen-free, fluorene-based polymer comprising an allyl group; and
then heating the silicon nanoparticles in an inert gas atmosphere to form a carbon coating on the silicon nanoparticles, the carbon coating having an oxygen-free structure including pentagon rings.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Yang Li
• Cai Mei
• Jiang Meng
• Ruthkosky Martin S

Classifications

• H01M4/366 Primary

  as layered products · CPC title

• H01M4/386

  Silicon or alloys based on silicon · CPC title

• H01M4/621

  Binders · CPC title

• H01M4/625

  Carbon or graphite · CPC title

• H01M10/0569

  characterised by the solvents · CPC title