Method for correcting two measured values from different analytical measuring devices and measuring point for carrying out the method

Patent metadata

Field	Value
Publication number	US-11782008-B2
Application number	US-202016942707-A
Country	US
Kind code	B2
Filing date	Jul 29, 2020
Priority date	Jul 29, 2019
Publication date	Oct 10, 2023
Grant date	Oct 10, 2023

Abstract

Disclosed is an apparatus for determining a process variable of a medium in a containment, comprising first and second oscillatory elements, first and second driving/receiving units, and electronics. The first driving/receiving unit is embodied to excite the first oscillatory element using a first electrical excitation signal to execute mechanical oscillations, and to receive the mechanical oscillations of the first oscillatory element and to convert such into a first electrical, received signal, wherein the second driving/receiving unit is embodied to excite the second oscillatory element by means of a second electrical excitation signal to execute mechanical oscillations, and to receive the mechanical oscillations of the second oscillatory element and to convert such into a second electrical, received signal, and wherein the electronics is embodied to determine the process variable from the first received signal and/or the second received signal.

First claim

The invention claimed is:

1. A method for correcting a first measured value of a first measurand of a first analytical measuring device and a second measured value of a second measurand of a second analytical measuring device, wherein the first analytical measuring device has a first cross-sensitivity to the second measurand and the second analytical measuring device has a second cross-sensitivity to the first measurand, the method comprising the following steps:
providing a measuring system comprising:
the first analytical measuring device which is suitable for determining the first measured value of the first measurand,
the second analytical measuring device which is suitable for determining the second measured value of the second measurand which differs from the first measurand,
a third analytical measuring device which is suitable for determining a third measured value of a third measurand which differs from the first measurand and the second measurand, and
a control unit which is connected to the first analytical measuring device, the second analytical measuring device and the third analytical measuring device,
the first analytical measuring device having the first cross-sensitivity to the second measurand and the first measured value having a dependence on the third measured value,
the second analytical measuring device having the second cross-sensitivity to the first measurand,
the third analytical measuring device not having any cross-sensitivity to the first measurand or to the second measurand;

determining the first measured value using the first analytical measuring device;
determining the second measured value using the second analytical measuring device;
determining the third measured value by using the third analytical measuring device;
calculating a corrected first measured value using the control unit by taking into account the first measured value, the second measured value, the cross-sensitivity of the first analytical measuring device to the second measurand and compensating for the dependence of the first measured value on the third measured value; and
calculating a corrected second measured value using the control unit by taking into account the first measured value, the second measured value and the cross-sensitivity of the second analytical measuring device to the first measurand and compensating for the dependence of the first measured value on the third measured value;
wherein the first analytical measuring device is an electrochemical sensor for measuring free chlorine of a common liquid medium, the second analytical measuring device is an electrochemical sensor for measuring chlorine dioxide of the common liquid medium, and the third analytical measuring device is an electrochemical pH sensor of the common liquid medium.

2. A measuring system for carrying out a method for correcting a first measured value of a first measurand of a first analytical measuring device and a second measured value of a second measurand of a second analytical measuring device, wherein the measuring system comprises:
the first analytical measuring device which is suitable for determining the first measured value of the first measurand,
the second analytical measuring device which is suitable for determining the second measured value of the second measurand which differs from the first measurand,
a third analytical measuring device which is suitable for determining a third measured value of a third measurand which differs from the first measurand and the second measurand; and
a control unit which is connected to the first analytical measuring device, the second analytical measuring device and the third analytical measuring device;
the first analytical measuring device having a first cross-sensitivity to the second measurand and the first measured value having a dependence on the third measured value;
the second analytical measuring device having a second cross-sensitivity to the first measurand;
the third analytical measuring device not having any cross-sensitivity to the first measurand or to the second measurand;
the control unit being suitable for calculating a corrected first measured value and a corrected second measured value;
wherein the first analytical measuring device is a free chlorine sensor, the second analytical measuring device is a chlorine dioxide sensor and the third analytical measuring device is a pH sensor, or the first analytical measuring device is a bromine sensor, the second analytical measuring device is a total chlorine sensor and the third analytical measuring device is the pH sensor, wherein all sensors detect measured values of a common liquid medium.

Assignees

• Endress Hauser Conducta Gmbh Co Kg

Inventors

• Hennings Erik
• Kaschuba Dagmar
• Bezzon Marco

Classifications

• G01N27/27 Primary

  Association of two or more measuring systems or cells, each measuring a different parameter, where the measurement results may be either used independently, the systems or cells being physically associated, or combined to produce a value for a further parameter · CPC title

• G01N27/4163 Primary

  checking the operation of, or calibrating, the measuring apparatus (G01N27/3274, G01N27/4175 and G01N33/0006 take precedence) · CPC title

• G01N27/4167

  pH (electrodes therefor G01N27/302, G01N27/36) · CPC title

• G01N27/302 Primary

  pH sensitive, e.g. quinhydron, antimony or hydrogen electrodes (ion selective electrodes G01N27/333, glass electrodes G01N27/36) · CPC title

• G01N27/304

  Gas permeable electrodes · CPC title