Catalytic upcycling of polymers
US-2021061971-A1 · Mar 4, 2021 · US
US11780985B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11780985-B2 |
| Application number | US-202017000969-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 24, 2020 |
| Priority date | Aug 27, 2019 |
| Publication date | Oct 10, 2023 |
| Grant date | Oct 10, 2023 |
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A method of upcycling polymers to useful hydrocarbon materials. A catalyst with nanoparticles on a substrate selectively docks and cleaves longer hydrocarbon chains over shorter hydrocarbon chains. The nanoparticles exhibit an edge to facet ratio to provide for more interactions with the facets.
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What is claimed is: 1. A catalyst comprising: a SrTiO 3 substrate; a plurality of metal nanoparticles disposed on the substrate; and the plurality of metal nanoparticles having a diameter of 1 to 3 nm and a ratio of facets to edges of less than 0.286. 2. The catalyst of claim 1 , wherein the plurality of nanoparticles comprise Pt. 3. The catalyst of claim 1 , wherein the substrate comprises a perovskite having the formula of ABO 3−x where x is in the range 0≤x≤0.5 and A is an alkaline or rare earth element and B is a 3d, 4d, or 5d transition metal element. 4. The catalyst of claim 3 wherein the substrate comprises alumina platelets or alumina spheres. 5. The catalyst of claim 1 , wherein the substrate is porous. 6. The catalyst of claim 1 , wherein the substrate is non-porous. 7. The catalyst of claim 2 , wherein the plurality of nanoparticles are a plurality of ordered nanoparticles.
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