Bonding dissimilar ceramic components

Patent metadata

Field	Value
Publication number	US-11780781-B2
Application number	US-202017123616-A
Country	US
Kind code	B2
Filing date	Dec 16, 2020
Priority date	Dec 30, 2014
Publication date	Oct 10, 2023
Grant date	Oct 10, 2023

Abstract

Adhesive compositions and methods for bonding materials with different thermal expansion coefficients is provided. The adhesive is formulated using a flux material, a low flux material, and a filler material, where the filler material comprises particulate from at least one of the two components being bonded together. A thickening agent can also be used as part of the adhesive composition to aid in applying the adhesive and establishing a desired bond thickness. The method of forming a high strength bond using the disclosed adhesive does not require the use of intermediary layer or the use of high cure temperatures that could damage one or both of the components being bonded together.

First claim

What is claimed:

1. A method of joining ceramic materials comprising the following steps:
(a) providing a first component comprising a ceramic characterized by a first coefficient of thermal expansion and having a first bonding surface;
(b) providing a second component comprising a ceramic characterized by a second coefficient of thermal expansion and having a second bonding surface, where the second coefficient of thermal expansion is different than the first coefficient of thermal expansion;
(c) applying an adhesive to one or both of the first and second bonding surfaces to form a bond layer, where the adhesive comprises,
i) particulate selected from one or more of glass coated ceramic matrix composites and metal matrix ceramics;
ii) a fluxing agent;
iii) a low flux material;
iv) water; and
v) a thickening agent;

(d) joining the first and second bonding surfaces with the bond layer;
(e) applying pressure to one or both of the first and second components in direction perpendicular to the adhesive layer to form an adhered composite;
(f) heating the adhered composite to form a bond between the first and second components, where the adhesive layer during heating causes chemical composition changes to at least one the first and second bonding surfaces.

2. The method of claim 1 where the adhered composite is heated to a temperature of at least about 2,000° F. and held at the temperature for at least about 30 minutes.

3. The method of claim 1 where the adhesive is formulated by mixing together water, a chemically modified cellulose thickening agent, lithium metaborate, and zirconium oxide, and the particulate.

4. The method of claim 3 , wherein the adhesive is applied to one or both of the first and second bonding surfaces to produce a layer of adhesive having a thickness of less than 1 mil.

5. The method of claim 1 wherein the fluxing agent lowers the melting point or softening temperature of the chemical matrix located at the bonding surfaces of the ceramic components to be bonded.

6. The method of claim 1 wherein the fluxing agent is lithium metaborate, sodium carbonate, boron carbide, high borate glass, lime, alkaline ash, or a mixture thereof.

7. The method of claim 1 wherein the fluxing agent is lithium metaborate.

8. The method of claim 1 , wherein the total amount of fluxing agent in the adhesive formulation is from about 25% by weight to about 80% by weight.

9. The method of claim 1 wherein the low flux material is zirconium oxide, silicon nitride, silicon carbide, aluminates, silicates, alumino-silicates, titanates, zirconates, or a mixture thereof.

10. The method of claim 1 where the low flux material is zirconium oxide.

11. The method of claim 1 , wherein the amount of low flux material in the adhesive is from about 20% by weight to about 75% by weight.

12. The method of claim 1 where the thickening agent comprises chemically modified cellulose.

13. The method of claim 1 , wherein the thickening agent comprises methyl cellulose, ethyl cellulose, cellulose, flour, grain, wood, or a mixture thereof.

14. The method of claim 1 where the formed bond between the first and second components establishes a coefficient of thermal expansion transition region between the first and second components.

15. The method of claim 1 where the percent by weight of the particulate of the adhesive is determined by the difference between the coefficient of thermal expansion of the first component and the coefficient of thermal expansion of the second component.

16. The method of claim 1 , wherein the adhesive is applied to only one of the first and second bonding surfaces.

17. The method of claim 1 , wherein the adhesive is applied to one or both of the first and second bonding surfaces to produce a layer of adhesive having a thickness of less than 1 mil.

18. The method of claim 1 where the adhered composite is heated to a temperature of at least about 800° F. and held at the temperature for at least about 30 minutes.

19. A method of joining ceramic materials comprising the following steps:
(a) providing a first component comprising a ceramic characterized by a first coefficient of thermal expansion and having a first bonding surface;
(b) providing a second component comprising a ceramic characterized by a second coefficient of thermal expansion and having a second bonding surface, where the second coefficient of thermal expansion is different than the first coefficient of thermal expansion;
(c) applying an adhesive to one or both of the first and second bonding surfaces to form a bond layer, where the adhesive comprises,
i) particulate selected from one or more of glass coated ceramic matrix composites and metal matrix ceramics;
ii) a fluxing agent; and
iii) a low flux material;

(d) joining the first and second bonding surfaces with the bond layer;
(e) applying pressure to one or both of the first and second components in direction perpendicular to the adhesive layer to form an adhered composite;
(f) heating the adhered composite to form a bond between the first and second components, where the adhesive layer during heating causes chemical composition changes to at least one of the first and second bonding surfaces.

20. The method of claim 19 where the adhered composite is heated to a temperature of at least about 2,000° F. and held at the temperature for at least about 30 minutes.

21. The method of claim 19 , wherein the adhesive is applied to one or both of the first and second bonding surfaces to produce a layer of adhesive having a thickness of less than 1 mil.

22. The method of claim 19 wherein the fluxing agent lowers the melting point or softening temperature of the chemical matrix located at the bonding surfaces of the ceramic components to be bonded.

23. The method of claim 19 wherein the fluxing agent is lithium metaborate, sodium carbonate, boron carbide, high borate glass, lime, alkaline ash, or a mixture thereof.

24. The method of claim 19 wherein the fluxing agent is lithium metaborate.

25. The method of claim 19 , wherein the total amount of fluxing agent in the adhesive formulation is from about 25% by weight to about 80% by weight.

26. The method of claim 19 wherein the low flux material is zirconium oxide, silicon nitride, silicon carbide, aluminates, silicates, alumino-silicates, titanates, zirconates, or a mixture thereof.

27. The method of claim 19 where the low flux material is zirconium oxide.

28. The method of claim 19 , wherein the amount of low flux material in the adhesive is from about 20% by weight to about 75% by weight.

29. The method of claim 28 where the thickening agent comprises chemically modified cellulose.

Assignees

• Boeing Co

Inventors

• Crooks Tab Hunter
• Muench Maryann S

Classifications

• C04B37/005 Primary

  consisting of glass or ceramic material · CPC title

• B32B7/027

  Thermal properties · CPC title

• B32B7/12

  using interposed adhesives or interposed materials with bonding properties · CPC title

• B32B18/00

  Layered products essentially comprising ceramics, e.g. refractory products · CPC title

• C04B35/638

  Removal thereof · CPC title