Laminate

Patent metadata

Field	Value
Publication number	US-11780212-B2
Application number	US-201515304344-A
Country	US
Kind code	B2
Filing date	Apr 15, 2015
Priority date	Apr 24, 2014
Publication date	Oct 10, 2023
Grant date	Oct 10, 2023

Abstract

The present invention aims to provide a laminate in which a fluororesin layer and a fluororubber layer are firmly bonded. The present invention relates to a laminate including: a fluororubber layer (A); and a fluororesin layer (B) stacked on the fluororubber layer (A), the fluororubber layer (A) being formed from a fluororubber composition, the fluororubber composition containing a fluororubber, a low molecular weight polytetrafluoroethylene, and a multifunctional compound, the amount of the multifunctional compound being 5 parts by mass or more relative to 100 parts by mass of the fluororubber.

First claim

The inventon claimed is:

1. A laminate comprising:
a fluororubber layer (A); and
a fluororesin layer (B) comprising a fluororesin stacked on the fluororubber layer (A),
the laminate having an initial interlayer adhesion strength of 10 N/cm or higher,
the fluororubber layer (A) being formed from a fluororubber composition,
the fluororubber composition containing a fluororubber, a low molecular weight polytetrafluoroethylene, and a multifunctional compound, the amount of the multifunctional compound being 7 to 15 parts by mass relative to 100 parts by mass of the fluororubber,
wherein the fluororubber composition contains the low molecular weight polytetrafluoroethylene in an amount of 20 to 40 parts by mass relative to 100 parts by mass of the fluororubber,
wherein the fluororubber is a non-perfluororubber having an iodine atom or a bromine atom at an end of the main chain thereof, and is a vinylidene fluoride unit-containing copolymer containing 30 to 80 mol % of the vinylidene fluoride unit and 70 to 20 mol % of a fluorine-containing ethylenic monomer unit (a) relative to 100 mol % of the total of the vinylidene fluoride unit and the fluorine-containing ethylenic monomer unit (a),
wherein the multifunctional compound is triallyl isocyanurate,
wherein the low molecular weight polytetrafluoroethylene is a tetrafluoroethylene polymer having a melt viscosity at 380° C. of 1×10 2 to 7×10 5 Pas, and an average particle size of 0.5 to 20 μm, and is a modified polytetrafluoroethylene in which an amount of a modifying monomer unit copolymerizable with tetrafluoroethylene is 0.01% to 1% by weight in all the monomer units,
wherein the vinylidene fluoride unit-containing copolymer is at least one copolymer selected from the group consisting of vinylidene fluoride/hexafluoropropylene copolymer and vinylidene fluoride/hexafluoropropylene/tetrafluoroethylene copolymer,
wherein the vinylidene fluoride/hexafluoropropylene copolymer has a mole ratio vinylidene fluoride/hexafluoropropylene of (45 to 85)/(55 to 15),
wherein the vinylidene fluoride/hexafluoropropylene/tetrafluoroethylene copolymer has a mole ratio vinylidene fluoride/hexafluoropropylene/tetrafluoroethylene of (40 to 80)/(10 to 35)/(10 to 35),
wherein the fluororesin is (I) a copolymer obtained by polymerization of at least 20 to 80 mol % of tetrafluoroethylene, 10 to 80 mol % of ethylene, 0 to 30 mol % of hexafluoropropylene, and 0 to 10 mol % of a monomer copolymerizable with tetrafluoroethylene and ethylene.

2. The laminate according to claim 1 ,
wherein the fluororubber composition contains a peroxide vulcanizing agent.

3. The laminate according to claim 1 ,
wherein the fluororubber layer (A) has an abrasion loss determined according to a wear test specified in JIS K 7204 of 0.10 g or less.

4. The laminate according to claim 1 ,
wherein the fluororubber layer (A) is stacked on both sides of the fluororesin layer (B).

5. The laminate according to claim 1 ,
wherein the fluororesin layer (B) is stacked on both sides of the fluororubber layer (A).

6. The laminate according to claim 1 , further comprising a fluorine-free rubber layer (C1a),
wherein the layers are stacked in the order of the fluororubber layer (A), the fluororesin layer (B), and the fluorine-free rubber layer (C1a).

7. The laminate according to claim 6 , further comprising a fluorine-free rubber layer (D1a),
wherein the layers are stacked in the order of the fluorine-free rubber layer (D1a), the fluororubber layer (A), the fluororesin layer (B), and the fluorine-free rubber layer (C1a); in the order of the fluororubber layer (A), the fluororesin layer (B), the fluorine-free rubber layer (D1a), and the fluorine-free rubber layer (C1a); or in the order of the fluororubber layer (A), the fluororesin layer (B), the fluorine-free rubber layer (C1a), and the fluorine-free rubber layer (D1a).

8. The laminate according to claim 1 ,
wherein the fluororubber layer (A) and the fluororesin layer (B) are vulcanization-bonded to each other.

9. The laminate according to claim 1 , which is a sealant for semiconductor manufacturing processes or a fuel pipe hose.

Assignees

• Daikin Ind Ltd

Inventors

• Kuwajima Yuuki
• Sumino Eisaku
• Inaba Takeshi
• Noguchi Tsuyoshi

Classifications

• B32B25/08 Primary

  of synthetic resin · CPC title

• B32B1/08

  Tubular products · CPC title

• B32B25/042

  of natural rubber or synthetic rubber · CPC title

• B32B25/14

  comprising {synthetic rubber copolymers (B32B25/18 and B32B25/20 take precedence)} · CPC title

• B32B27/304

  comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF · CPC title