Method for manufacturing an aluminium alloy part by additive manufacturing from a mixture of powders containing yttria-stabilized zirconia

Patent metadata

Field	Value
Publication number	US-11780007-B2
Application number	US-202016872469-A
Country	US
Kind code	B2
Filing date	May 12, 2020
Priority date	May 13, 2019
Publication date	Oct 10, 2023
Grant date	Oct 10, 2023

Abstract

Method for manufacturing an aluminium alloy part by additive manufacturing comprising a step during which a layer of a mixture of powders is locally melted and then solidified, characterised in that the mixture of powders comprises:
first particles comprising at least 80% by mass of aluminium and up to 20% by mass of one or more additional elements, and second yttria-stabilized zirconia particles, the mixture of powders comprising at least 1.5% by volume of second particles.

First claim

The invention claimed is:

1. A method for manufacturing an aluminum alloy part by additive manufacturing, the method comprising:
locally melting a layer of a mixture of powders and then solidifying,
wherein the mixture of powders comprises:
85 to 98.5 vol. % of first particles comprising at least 80% by mass of aluminum and up to 20% by mass of one or more additional elements; and
1.5 to 2.5 vol. % of second particles comprising yttria-stabilized zirconia,
wherein the second particles have a largest dimension in a range of from 5 to 600 nm.

2. The method of claim 1 , wherein the largest dimension of the second particles is in a range of from 100 to 400 nm.

3. The method of claim 1 , wherein the largest dimension of the second particles is in a range of from 200 to 300 nm.

4. The method of claim 1 , wherein the first particles have a largest dimension in a range of from 10 μm to 100 μm.

5. The method of claim 1 , wherein the first particles have a largest dimension in a range of from 20 μm to 65 μm.

6. The method of claim 1 , wherein the one or more additional elements are selected from the group consisting of Cu, Si, Zn, Mg, Fe, Ti, Mn, Zr, Ni, Pb, Bi, and Cr.

7. The method of claim 1 , wherein the aluminum alloy is alloy 7075, alloy 2024, alloy 2219, or alloy 6061.

8. The method of claim 1 , wherein the method for manufacturing an aluminum alloy part is a selective laser melting method or a selective electron beam melting method.

9. The method of claim 1 , comprising:
obtaining the mixture of powders in a 3D dynamic mixer or by mechano-synthesis.

10. The method of claim 1 , wherein the mixture of powders has a specific surface greater than 0.3 m 2 /g.

11. The method of claim 1 , wherein the mixture of powders further comprises a reducing element.

12. The method of claim 11 , wherein the reducing element is magnesium.

13. The method of claim 11 , wherein the mixture of powders comprises at least 0.5% by mass of the reducing element.

14. The method of claim 11 , wherein the mixture of powders comprises between 0.5% and 10% by mass of the reducing element.

15. The method of claim 11 , wherein the reducing element is present in the first particles.

16. The method of claim 1 , further comprising:
adding a reducing element comprising Mg to the mixture prior to the solidifying.

17. The method of claim 1 , wherein the aluminum alloy part has fewer cracks than an otherwise identical aluminum alloy part having no more than 1 vol. % of the first particles.

18. The method of claim 1 , wherein the largest dimension of the second particles is in a range of from 200 to 300 nm,
wherein the first particles have a largest dimension in a range of from 20 μm to 65 μm, and
wherein the mixture of powders has a specific surface greater than 0.3 m 2 /g.

Assignees

• Commissariat Energie Atomique

Inventors

• Opprecht Mathieu
• Garandet Jean-Paul
• Roux Guilhem
• Soulier Mathieu

Classifications

• B33Y70/10 Primary

  Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials · CPC title

• B22F3/105 Primary

  by using electric current {other than for infrared radiant energy}, laser radiation or plasma (B22F3/11 takes precedence){; by ultrasonic bonding (B22F3/115 takes precedence)} · CPC title

• B22F10/28

  Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM] · CPC title

• B22F10/32

  of the atmosphere, e.g. composition or pressure in a building chamber · CPC title

• B22F10/34

  of powder characteristics, e.g. density, oxidation or flowability · CPC title