Slow-release inhibitor for high-magnesium sulfide mineral flotation and application thereof

Patent metadata

Field	Value
Publication number	US-11779935-B2
Application number	US-201916693186-A
Country	US
Kind code	B2
Filing date	Nov 22, 2019
Priority date	Apr 10, 2019
Publication date	Oct 10, 2023
Grant date	Oct 10, 2023

Abstract

Disclosed are a slow-release inhibitor for high-magnesium sulfide mineral flotation and an application thereof, where the inhibitor is a nano colloidal particle of an alkaline earth fluoride such as CaF2 and BaF2 or a highly-reactive natural alkaline earth metal mineral powder. When applied to the flotation separation of a high-magnesium sulfide ore, the inhibitor can slowly release F ions to preferentially form a MgF2 layer on the magnesium-containing mineral surface, which provides a structure similar to MgF2 on a surface of oxidized gangue minerals such as magnesium oxide, changing surface electrical property of the magnesium-containing mineral, inhibiting heterogeneous coagulation of magnesium-containing minerals and sulfide ores due to electrostatic attraction and reducing entrainment, enveloping and agglomeration of gangue minerals to efficiently inhibit the flotation of oxidized gangue minerals such as magnesium oxide.

First claim

What is claimed is:

1. A method of separating a high-magnesium sulfide ore, comprising:
mixing alkaline earth metal fluoride in the form of a nano alkaline earth fluoride colloidal particle or in the form of a natural alkaline earth metal mineral with the high-magnesium sulfide mineral to produce an ore pulp;
stirring the ore pulp under 1,200-3,000 rpm for 5-30 min; and
introducing a collector to obtain a flotation system.

2. The method of claim 1 , wherein a mass ratio of the nano alkaline earth fluoride colloidal particle or the natural alkaline earth metal mineral to the high-magnesium sulfide mineral is 1:10-500;
and
a pulping time is 5-30 min.

3. The method of claim 1 , wherein a concentration of the ore pulp in the flotation is controlled at 30%-40%, and a pH of the flotation system is controlled to 7-9.

4. The method of claim 1 , wherein the nano alkaline earth fluoride colloidal particle or the natural alkaline earth metal mineral is used in combination with at least one of acidified sodium silicate, sodium hexametaphosphate, starch and tannin.

5. The method of claim 1 , wherein the collector is selected from the group consisting of copper sulfide, cobalt sulfide and nickel sulfide.

6. A method of separating a high-magnesium sulfide ore, comprising:
mixing alkaline earth metal fluoride in the form of a nano alkaline earth fluoride colloidal particle or in the form of a natural alkaline earth metal mineral with the high-magnesium sulfide mineral to produce an ore pulp;
stirring the ore pulp under 1,200-3,000 rpm for 5-30 min; and
introducing a collector to obtain a flotation system;
wherein the high-magnesium sulfide ore comprises at least one magnesium-containing gangue mineral selected from magnesite, serpentine, talc, olivine, pyroxene, hornblende, biotite, chlorite, vermiculite, montmorillonite and illite, and at least one metal sulfide ore selected from nickel sulfide mineral, cobalt sulfide mineral and copper sulfide mineral.

7. The method of claim 5 , wherein a mass ratio of the nano alkaline earth fluoride colloidal particle or the natural alkaline earth metal mineral to the high-magnesium sulfide mineral is 1:10-500; and a pulping time is 5-30 min.

8. The method of claim 5 , wherein the nano alkaline earth fluoride colloidal particle or the natural alkaline earth metal mineral is used in combination with at least one of acidified sodium silicate, sodium hexametaphosphate, starch and tannin.

9. The method of claim 6 , wherein the collector is selected from the group consisting of copper sulfide, cobalt sulfide and nickel sulfide.

Assignees

• Univ Central South

Inventors

• Han Haisheng
• Sun Wei
• Hu Yuehua
• Wang Ruolin
• Wei Zhao
• Sun Wenjuan
• Wang Li
• Yang Yue
• Tang Honghu
• Zhang Qingpeng
• Sun Lei

Classifications

• B03D1/002 Primary

  Inorganic compounds · CPC title

• B03D1/018

  Mixtures of inorganic and organic compounds · CPC title

• B03D1/02

  Froth-flotation processes · CPC title

• C01F11/22

  Fluorides · CPC title

• B03D2201/06

  Depressants · CPC title