Systems and methods for nanofunctionalization of powders

Patent metadata

Field	Value
Publication number	US-11779894-B2
Application number	US-201815996439-A
Country	US
Kind code	B2
Filing date	Jun 2, 2018
Priority date	Feb 1, 2017
Publication date	Oct 10, 2023
Grant date	Oct 10, 2023

Abstract

Some variations provide a system for producing a functionalized powder, comprising: an agitated pressure vessel; first particles and second particles contained within the agitated pressure vessel; a fluid contained within the agitated pressure vessel; an exhaust line for releasing the fluid from the agitated pressure vessel; and a means for recovering a functionalized powder containing the second particles disposed onto surfaces of the first particles. A preferred fluid is carbon dioxide in liquefied or supercritical form. The carbon dioxide may be initially loaded into the pressure vessel as solid carbon dioxide. The pressure vessel may be batch or continuous and is operated under reaction conditions to functionalize the first particles with the second particles, thereby producing a functionalized powder, such as nanofunctionalized metal particles in which nanoparticles act as grain refiners for a component ultimately produced from the nanofunctionalized metal particles. Methods for making the functionalized powder are also disclosed.

First claim

What is claimed is:

1. A method for producing a functionalized powder for additive manufacturing or welding, said method comprising:
(a) introducing a plurality of first particles into an agitated pressure vessel under an inert atmosphere, wherein said first particles have an average first-particle size from about 1 micron to about 1 millimeter;
(b) introducing a plurality of second particles into said agitated pressure vessel under said inert atmosphere, wherein said second particles are nanoparticles with an average second-particle size from about 1 nanometer to about 5000 nanometers, wherein said second particles are compositionally different than said first particles, and wherein said second particles are selected from the group consisting of zirconium hydrides, tantalum hydrides, niobium hydrides, titanium hydrides, and combinations thereof;
(c) after steps (a) and (b), introducing a fluid into said agitated pressure vessel,
wherein said fluid dissolves or suspends both of said first particles and said second particles, and wherein said agitated pressure vessel is operated at a vessel pressure from about 2 bar to about 200 bar;
(d) after step (c), in said agitated pressure vessel and at said vessel pressure, reacting said second particles with said first particles to generate a functionalized powder containing said second particles disposed onto surfaces of said first particles;
(e) after step (d), releasing said fluid from said agitated pressure vessel; and
(f) after step (e), recovering said functionalized powder from said agitated pressure vessel.

2. The method of claim 1 , wherein said fluid is selected from the group consisting of carbon dioxide, nitrous oxide, C 1 -C 4 hydrocarbons, C 1 -C 4 oxygenates, and combinations thereof.

3. The method of claim 1 , wherein said fluid includes carbon dioxide in a vapor state and/or a liquid state within said agitated pressure vessel.

4. The method of claim 1 , wherein said fluid includes carbon dioxide in a supercritical state within said agitated pressure vessel.

5. The method of claim 1 , wherein said fluid is carbon dioxide in vapor form and/or liquid form.

6. The method of claim 1 , wherein said reacting said second particles with said first particles is conducted at a reaction temperature from about 10° C. to about 200° C.

7. The method of claim 1 , wherein said reacting said second particles with said first particles is conducted for a reaction time from about 10 minutes to about 50 hours.

8. The method of claim 1 , wherein said method is operated in batch.

9. The method of claim 1 , wherein said method is operated continuously or semi-continuously.

10. The method of claim 1 , wherein said first particles are selected from the group consisting of metal particles, intermetallic particles, ceramic particles, and combinations thereof.

11. The method of claim 1 , wherein said first particles contain one or more metals selected from the group consisting of aluminum, iron, nickel, copper, titanium, magnesium, zinc, silicon, lithium, silver, chromium, manganese, vanadium, bismuth, gallium, lead, and combinations thereof.

12. The method of claim 1 , wherein said second particles are selected from the group consisting of metal particles, intermetallic particles, ceramic particles, and combinations thereof.

13. The method of claim 1 , wherein said inert atmosphere is argon or nitrogen.

14. The method of claim 1 , wherein step (c) comprises introducing a fluid precursor into said agitated pressure vessel, and then sealing said agitated pressure vessel, and then converting said fluid precursor, within said agitated pressure vessel, to said fluid.

15. The method of claim 14 , wherein said fluid precursor is solid carbon dioxide, wherein said fluid is carbon dioxide, and wherein said solid carbon dioxide melts or sublimates within said agitated pressure vessel to form said carbon dioxide in vapor form and/or liquid form.

16. The method of claim 1 , wherein said second particles are in the form of a discontinuous coating on said first particles.

17. The method of claim 1 , wherein said functionalized powder is melted and resolidified in an additive-manufacturing process.

18. The method of claim 1 , wherein said functionalized powder is melted and resolidified in a welding process.

Assignees

• Hrl Lab Llc

Inventors

• Martin John H
• Yahata Brennan D
• Mone Robert

Classifications

• B01J3/02 Primary

  Feed or outlet devices therefor · CPC title

• B01F33/401

  Methods · CPC title

• B01F35/2213

  Pressure · CPC title

• B01F35/2215

  Temperature · CPC title

• B01F35/22161

  duration of the mixing process or parts of it · CPC title