Organic electroluminescent devices

Patent metadata

Field	Value
Publication number	US-11778908-B2
Application number	US-201916683276-A
Country	US
Kind code	B2
Filing date	Nov 14, 2019
Priority date	Dec 29, 2017
Publication date	Oct 3, 2023
Grant date	Oct 3, 2023

Abstract

The present disclosure relates to display technologies, and particularly discloses an organic electroluminescent device. This organic electroluminescent device includes a light-emitting layer, the light-emitting includes an exciplex composed of a donor molecule and an acceptor molecule, and a wide band gap material for increasing the inter-molecular spacing between the donor molecule and the acceptor molecule. According to the device of the present disclosure, the degree of orbital overlap of HOMO and LUMO of the formed exciplex and the singlet-triplet energy level difference can be reduced, the reverse intersystem crossing rate (k RISC ) of the exciplex host can be increased, the Föster energy transferred to the guest molecule can be enhanced, and the efficiency and the lifetime of the device can be improved.

First claim

The invention claimed is:

1. An organic electroluminescent device, comprising: a light-emitting layer, the light-emitting layer comprising a host material and a guest material, the host material comprising a wide band gap material and an exciplex, the exciplex composed of and formed by a donor molecule and an acceptor molecule,
wherein the wide band gap material is a compound containing a carbazolyl and an aryl,
wherein the guest material is a fluorescent doping dye,
wherein the donor molecule is a compound having hole transport property,
wherein the acceptor molecule is a compound having electron transport property,
wherein a mass ratio of the wide band gap material to the exciplex is between 1:19 to 4:1, and
wherein in the exciplex, a mass ratio of the donor molecule to the acceptor molecule is between 1:9 and 9:1.

2. The organic electroluminescent device of claim 1 , wherein a triplet energy level of the wide band gap material is higher than a singlet energy level of the exciplex.

3. The organic electroluminescent device of claim 1 , wherein a triplet level of the donor molecule and a triplet level of the acceptor molecule are respectively higher than a triplet level of the exciplex.

4. The organic electroluminescent device of claim 1 , wherein an energy level difference between a singlet level and a triplet level of the exciplex is less than 0.15 eV.

5. The organic electroluminescent device of claim 1 , wherein the wide band gap material is selected from at least one of compounds of structures shown below:

6. The organic electroluminescent device of claim 1 , wherein the donor molecule is a compound containing at least one of a carbazolyl, a triphenylamine, and an aryl.

7. The organic electroluminescent device of claim 6 , wherein the donor molecule is selected from at least one of compounds of structures shown below:

8. The organic electroluminescent device of claim 1 , wherein the acceptor molecule is a compound containing at least one of a pyridyl, a pyrimidinyl, a triazinyl, a carbazolyl, an aryl, a cyano, and a diphenylphosphono.

9. The organic electroluminescent device of claim 8 , wherein the acceptor molecule is selected from at least one of compounds of structures shown below:

10. The organic electroluminescent device of claim 1 , wherein the fluorescent doping dye is selected from at least one of compounds of structures shown below:

11. The organic electroluminescent device of claim 1 , wherein a doping ratio of the exciplex is between 5 wt % and 80 wt %.

12. The organic electroluminescent device according to claim 10 , wherein a doping ratio of the fluorescent doping dye is between 0.1 wt % and 10 wt %.

13. The organic electroluminescent device of claim 1 , wherein in the exciplex, a mass ratio of the donor molecule to the acceptor molecule is between 1:5 and 5:1.

14. The organic electroluminescent device of claim 11 , wherein the content of the exciplex is between 20 wt % and 50 wt % based on the total weight of the light-emitting layer.

15. The organic electroluminescent device of claim 12 , wherein the content of the fluorescent doping dye is between 0.1 wt % and 3 wt % based on the total weight of the light-emitting layer.

16. The organic electroluminescent device of claim 1 , wherein the organic electroluminescent device includes a first electrode, a second electrode, and an organic functional layer between the first electrode and the second electrode, the organic functional layer comprising a hole injection layer, a hole transport layer, the light-emitting layer, an electron transport layer, and an electron injection layer which are stacked.

17. The organic electroluminescent device of claim 16 , wherein the wide band gap material is a compound as represented by a formula (W-1), the donor molecule is a compound as represented by a formula (D-1), and the acceptor molecule is a compound as represented by a formula (A-19):

18. The organic electroluminescent device of claim 17 , wherein the fluorescent doping dye is being a compound as represented by a formula (F-8):

wherein the fluorescent doping dye has a content between 0.1 wt % and 3 wt %.

19. The organic electroluminescent device of claim 17 , wherein a mass ratio of the donor molecule to the acceptor molecule is between 1:5 to 5:1, and wherein the exciplex has a content between 20 wt % and 50 wt %.

20. The organic electroluminescent device of claim 16 , wherein the first electrode is made of ITO material, the hole injection layer is made of HATCN, the hole transport layer is made of TAPC, the electron transport layer is made of BPhen, the electron injection layer is made of electron injection material LiF, and the second electrode is made of Al.

Assignees

• Kunshan Govisionox Optoelectronics Co Ltd
• Univ Tsinghua

Inventors

• Duan Lian
• Song Xiaozeng
• Zhang Dongdong
• Wei Jinbei

Classifications

• H10K85/6572 Primary

  comprising only nitrogen in the heteroaromatic polycondensed ring system, e.g. phenanthroline or carbazole · CPC title

• C07C13/72

  Spiro hydrocarbons · CPC title

• C07C15/38

  containing four rings · CPC title

• C07C211/54

  having amino groups bound to two or three six-membered aromatic rings · CPC title

• C07D209/86 Primary

  with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the ring system · CPC title