Positive electrode active material for nonaqueous electrolyte secondary batteries, method for producing same, and nonaqueous electrolyte secondary battery

Patent metadata

Field	Value
Publication number	US-11777090-B2
Application number	US-202217864999-A
Country	US
Kind code	B2
Filing date	Jul 14, 2022
Priority date	Jun 28, 2017
Publication date	Oct 3, 2023
Grant date	Oct 3, 2023

Abstract

Provided is a positive electrode active material for a nonaqueous electrolyte secondary battery including a LiNi composite oxide having low internal resistance and excellent thermal stability. The positive electrode active material is obtained by performing a water washing process using a water spray on a LiNi composite oxide powder obtained by a firing step until the filtrate has an electric conductivity of 30 to 60 mS/cm, and then dried, where the LiNi composite oxide is represented by the composition formula (1): LibNi1-aM1aO2, where M1 represents at least one kind of element selected from transition metal elements other than Ni, group 2 elements, and group 13 elements, and 0.01≤a≤0.5, and 0.85≤b≤1.05.

First claim

The invention claimed is:

1. A positive electrode active material for a nonaqueous electrolyte secondary battery comprising a lithium nickel composite oxide represented by composition formula (1):
Li b Ni 1-a M1 a O 2 ,
where M1 represents at least one kind of element selected from transition metal elements other than Ni, group 2 elements, and group 13 elements, 0.01≤a≤0.5, and 0.85≤b≤1.05,
wherein
the lithium nickel composite oxide has a specific surface area in a range of 0.5 m 2 /g to 2.05 m 2 /g, a carbon content of 0.01% by mass or more and 0.08% by mass or less with respect to a total amount of the lithium nickel composite oxide, and a lithium amount of a lithium compound present on a surface of the lithium nickel composite oxide is 0.01% by mass or more and 0.10% by mass or less with respect to the total amount of the lithium nickel composite oxide.

2. The positive electrode active material for a nonaqueous electrolyte secondary battery according to claim 1 , wherein a moisture content of the lithium nickel composite oxide powder is 0.2% by mass or less.

3. The positive electrode active material for a nonaqueous electrolyte secondary battery according to claim 1 , wherein the composition formula (1) is a composition formula (2):
Li b Ni 1-x-y-z Co x Al y M2 z O 2 ,
where M2 represents at least one kind of element selected from a group of Mn, Ti, Ca and Mg, 0.85≤b≤1.05, 0.05≤x≤0.30, 0.01≤y≤0.1, and z is 0≤z≤0.05.

4. The positive electrode active material for a nonaqueous electrolyte secondary battery according to claim 1 , wherein the carbon content is in a range of 0.01% by mass to 0.04% by mass.

5. The positive electrode active material for a nonaqueous electrolyte secondary battery according to claim 1 , wherein the lithium amount is a mass ratio of lithium to the lithium nickel composite oxide determined by adding the lithium nickel composite oxide to solution to make a slurry, after which an amount of alkali content in the slurry is found by titration with acid using pH of the slurry as an index, and then performing lithium conversion from the amount of alkali content.

6. The positive electrode active material for a nonaqueous electrolyte secondary battery according to claim 5 , wherein the acid used for the titration is at least one selected from a group consisting of hydrochloric acid, sulfuric acid, nitric acid, and organic acid.

7. A nonaqueous electrolyte secondary battery comprising a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and a nonaqueous electrolyte, wherein the positive electrode active material according to claim 1 is used as a positive electrode material of the positive electrode.

Assignees

• Sumitomo Metal Mining Co

Inventors

• Nakayama Tomoko
• Yokoyama Jun
• Komukai Tetsufumi

Classifications

• C01G53/82

  Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements · CPC title

• H01M4/525 Primary

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M4/133

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M2004/027

  Negative electrodes · CPC title