Corrosion resistant electrodes

Patent metadata

Field	Value
Publication number	US-11774404-B2
Application number	US-202016736797-A
Country	US
Kind code	B2
Filing date	Jan 7, 2020
Priority date	Jan 31, 2013
Publication date	Oct 3, 2023
Grant date	Oct 3, 2023

Abstract

An electrode for use in instruments capable of measuring the electrophoretic mobility of particles in solution is disclosed. The electrode is comprised of an inexpensive support member, generally made of titanium, onto a flat surface of which has been connected, generally by microwelding, a flat electrically conductive but chemically inert foil member, preferably platinum. A uniform texture can be generated on the exposed surfaces of the electrode by various means including tumbling the electrode with an abrasive. An oxide layer can be generated on the support member by soaking the composite electrode in an appropriate medium, protecting the exposed surface of the support member from fluid contact with the sample solution, while the foil member, unaffected by the oxidation process, is able to contact the sample solution.

First claim

What is claimed is:

1. An electrode comprising:
an electrically conductive support member comprising at least one planar surface; and
a flat, chemically inert, electrically conductive foil member,
wherein the foil member is welded by an electron beam to the conductive support member about the perimeter of the foil member, resulting in a composite,
wherein the composite comprises an exposed surface of the foil member and an exposed surface of the support member,
wherein the exposed surface of the foil member comprises a uniform, non-smooth surface resulting from etching the exposed surface of the foil member,
wherein the etching the exposed surface of the foil member comprises mechanically tumbling the composite with an abrasive,
 wherein a final surface finish of the etching is controlled by adjusting a tumbling time of the tumbling and adjusting a bead size of the abrasive, and

wherein the exposed surface of the support member comprises an oxide layer resulting from exposing the composite to an oxidation agent,
resulting in the composite being chemically inert.

2. The electrode of claim 1 wherein the foil member comprises platinum.

3. The electrode of claim 2 wherein the foil member is a disc of platinum foil.

4. The electrode of claim 3 wherein the support member further comprises an o-ring groove milled about a perimeter of the support member,
wherein the perimeter does not intersect a planar surface to which the foil member is attached.

5. The electrode of claim 2 wherein the foil member is 100±5 μm thick, thereby permitting the foil member to be cleaned with mild abrasives without damage.

6. The electrode of claim 1
wherein the support member comprises a material or materials whose surface, when exposed to a strong oxidizer, causes an oxide layer to grow thereupon; and
wherein the foil member comprises a material or materials whose surface, when exposed to a strong oxidizer, resists an oxide layer forming thereupon.

7. The electrode of claim 1 wherein the oxidization agent is a solution comprising hydrogen peroxide and water.

8. The electrode of claim 7 wherein the solution consists of 30% hydrogen peroxide and 70% water.

9. The electrode of claim 6 wherein the oxide layer is formed by passing an electrical current through the composite bathed in a salt solution.

Assignees

• Wyatt Tech Corp

Inventors

• Trainoff Steven P

Classifications

• G01N27/44765 Primary

  of the counter-flow type · CPC title

• B23K15/0093

  characterised by the properties of the materials to be welded · CPC title

• C25B11/02

  characterised by shape or form · CPC title

• C25B11/081

  the element being a noble metal · CPC title

• C25D9/06

  by anodic processes · CPC title