Method for producing pulp fibres for saccharification, and aqueous solution of pulp fibres for saccharification

Patent metadata

Field	Value
Publication number	US-11773536-B2
Application number	US-201816624957-A
Country	US
Kind code	B2
Filing date	May 10, 2018
Priority date	Jun 28, 2017
Publication date	Oct 3, 2023
Grant date	Oct 3, 2023

Abstract

The purpose of the present disclosure is to provide a method for producing pulp fibres for saccharification from the pulp fibres of used sanitary items, said pulp fibres for saccharification having low lignin contents distributed within a narrow range, and enabling the production of pulp fibres for saccharification having superior saccharification properties. The production method according to the present disclosure is characterised by comprising the following: a step for supplying a mixed solution (51) containing pulp fibres and highly-absorbent polymers sourced from used sanitary items to a treatment tank (31) via a mixed-solution supply port (32); a step for supplying an ozone-containing gas (53) to a treatment solution (52) within the treatment tank (31) via an ozone-containing-gas supply port (43); a step for lifting the ozone-containing gas (53) whilst lowering the pulp fibres and highly-absorbent polymers within the treatment tank (31), thereby bringing the ozone-containing gas (53) into contact with the pulp fibres and highly-absorbent polymers, and forming pulp fibres for saccharification from the pulp fibres; and a step for discharging the treatment solution (52) via a treatment-solution discharge port (33). The method is further characterised in that the pulp fibres for saccharification have lignin contents of 0.1% or less.

First claim

The invention claimed is:

1. A method of manufacturing pulp fibers for saccharification from pulp fibers of used hygiene products, comprising steps of:
a preparation step of preparing a treatment tank which includes a liquid mixture supply port, and a treatment liquid discharge port and an ozone containing gas supply port that are arranged below the liquid mixture supply port,
a liquid mixture supply step of supplying a liquid mixture which includes super absorbent polymers and the pulp fibers that derive from the used hygiene products and water, from the liquid mixture supply port to the treatment tank,
an ozone containing gas supply step of supplying ozone containing gas from the ozone containing gas supply port to a treatment liquid in the treatment tank, wherein the ozone concentration in the ozone containing gas is 40 to 200 g/m 3 to cause the decomposition of the super absorbent polymers,
a pulp fibers for saccharification formation step of forming the pulp fibers for saccharification from the pulp fibers while dissolving at least a portion of the super absorbent polymers in the treatment liquid, by, in the treatment tank, raising the ozone containing gas while lowering the super absorbent polymers and the pulp fibers so as to make the ozone containing gas come into contact with the super absorbent polymers and the pulp fibers, and
a treatment liquid discharge step of discharging the treatment liquid which includes the pulp fibers for saccharification from the treatment liquid discharge port, wherein
the pulp fibers for saccharification have a lignin content ratio of 0.1 mass % or less.

2. The method according to claim 1 , wherein the pulp fibers for saccharification have a water contact angle of 20° or less.

3. The method according to claim 1 , wherein the pulp fibers for saccharification have a beating degree reduction speed of 300 mL/h or more.

4. The method according to claim 1 wherein in the pulp fibers for saccharification formation step, the ozone containing gas is supplied from the ozone containing gas supply port as microbubbles or nanobubbles.

5. The method according to claim 1 , wherein the treatment liquid is acidic.

6. The method according to claim 1 , further comprising an inactivation step of inactivating the super absorbent polymers by an acid, before the liquid mixture supply step.

7. The method according to claim 6 , wherein the acid is an acid which can form a complex with metal ions included in an excrement.

8. The method according to claim 1 , wherein the pulp fibers for saccharification have an ash content ratio of 0.65 mass % or less.

9. The method according to claim 1 , wherein in the liquid mixture supply step, the liquid mixture is supplied continuously from the liquid mixture supply port to the treatment tank in a first flow rate, and in the treatment liquid discharge step, the treatment liquid is discharged continuously from the treatment liquid discharge port in a second flow rate.

10. The method according to claim 1 , further comprising a saccharification step of saccharifying the pulp fibers for saccharification, after the treatment liquid discharge step.

11. A method of manufacturing pulp fibers for saccharification from pulp fibers of used hygiene products according to claim 1 , wherein the ozone concentration in the treatment liquid is 1 to 50 mass ppm.

12. A method of manufacturing pulp fibers for saccharification from pulp fibers of used hygiene products according to claim 1 , wherein a flow rate R0 (L/minute) of the ozone containing gas and a volume V (L) of the treatment liquid inside the treatment tank satisfy 0.01≤R O /V≤1.25.

13. A method of manufacturing pulp fibers for saccharification from pulp fibers of used hygiene products according to claim 1 , wherein a CT value which is a product of an ozone concentration (mass ppm) in the treatment liquid and an in-tank treatment time (minute) is 100 to 6000 ppm·minute.

Assignees

• Unicharm Corp

Inventors

• Yamaki Kouichi
• Konishi Takayoshi
• Ohashi Naoto
• Hiraoka Toshio
• Kurita Noritomo

Classifications

• B09B2101/67

  Diapers or nappies · CPC title

• B09B3/32

  Compressing or compacting · CPC title

• B09B3/70

  Chemical treatment, e.g. pH adjustment or oxidation (involving an extraction step B09B3/80) · CPC title

• D21C5/022 Primary

  Chemicals therefor · CPC title

• A61F13/53

  characterised by the absorbing medium (A61F13/20 takes precedence) · CPC title