Carbon composite material and method for producing same

Patent metadata

Field	Value
Publication number	US-11773233-B2
Application number	US-201615743437-A
Country	US
Kind code	B2
Filing date	Oct 17, 2016
Priority date	Feb 26, 2016
Publication date	Oct 3, 2023
Grant date	Oct 3, 2023

Abstract

The present invention relates to a carbon composite material and a method for producing the same, and more particularly, to a carbon composite material capable of improving electrostatic dispersibility and flame retardancy, and a method for producing the same. The carbon composite material according to the present invention can be effectively applied to products requiring conductivity and flame retardancy.

First claim

What is claimed is:

1. A carbon composite material in the form of a mixture comprising:
a polymer resin;
a carbon nanotube dispersed in the mixture;
a glass fiber; and
a phosphate ester derivative,
wherein the carbon nanotube has a thermal decomposition temperature of 600° C. or higher, and wherein a ratio of the weight of carbon nanotube to the weight of phosphate ester derivative present in the carbon composite material is 1:3-15, and
wherein the carbon composite material has a surface resistance of 10 4 -10 8 ohm/sq;
wherein a ratio of the maximum value to the minimum value of the surface resistance, as measured according to ASTM D257, of the composite material is 1×10 2 or less.

2. The carbon composite material according to claim 1 , wherein the polymer resin is a thermoplastic resin.

3. The carbon composite material according to claim 1 , wherein the polymer resin is at least one selected from the group consisting of a nylon resin, a polyethylene resin, a polyamide resin, a polyester resin, a polycarbonate resin, a polyarylate resin and a cyclopolyolefin resin.

4. The carbon composite material according to claim 1 , wherein an average length of the carbon nanotube is 0.1 to 500 μm.

5. The carbon composite material according to claim 1 , wherein a maximum length of the carbon nanotube is 1000 μm.

6. The carbon composite material according to claim 1 , wherein an average diameter of the carbon nanotube is 0.1 to 100 nm.

7. The carbon composite material according to claim 1 , wherein an aspect ratio of the carbon nanotube is 500 to 5000 and is calculated according to the following Equation (1)
Aspect ratio=Length ( L )/Diameter ( D )  [Equation 1].

8. The carbon composite material according to claim 1 , wherein the carbon nanotube comprises a single-wall carbon nanotube, a multi-wall carbon nanotube, or a combination thereof.

9. The carbon composite material according to claim 1 , wherein the carbon nanotube is in the form of a rigid random coil.

10. The carbon composite material according to claim 1 , wherein the phosphate ester derivative is at least one selected from the group consisting of phosphine-based, phosphine oxide-based, and mixtures thereof.

11. The carbon composite material according to claim 1 , wherein the phosphate ester derivative is at least one selected from the group consisting of trialkyl ester, dialkyl ester and monoalkyl ester.

12. The carbon composite material according to claim 1 , wherein an average length of the glass fiber is 1 mm to 10 mm.

13. The carbon composite material according to claim 1 , wherein the carbon composite material has a tensile strength of 1,050 kg/cm 2 or more.

14. The carbon composite material according to claim 1 , wherein the carbon composite material has a thermal deformation temperature of 95° C. or more.

15. The carbon composite material according to claim 1 , comprising 0.1 to 2 weight percent of the carbon nanotube.

16. The carbon composite material according to claim 1 , wherein the ratio of the maximum value to the minimum value of the surface resistance, as measured according to ASTM D257, of the composite material is 1×10 or less.

17. The carbon composite material according to claim 1 , wherein the polymer resin has a number average molecular weight (Mn) of the polymer resin of 15,000 to 100,000.

18. The carbon composite material according to claim 1 , wherein the polymer resin is a polycarbonate resin.

19. The carbon composite material according to claim 18 , wherein polycarbonate resin is a polycarbonate copolymer.

20. A carbon composite material in the form of a mixture comprising:
a polymer resin;
a carbon nanotube dispersed in the mixture;
a glass fiber; and
a phosphate ester derivative,
wherein the carbon nanotube has a thermal decomposition temperature of 600° C. or higher, and wherein a ratio of the weight of carbon nanotube to the weight of phosphate ester derivative present in the carbon composite material is 1:3-15,
wherein a ratio of the maximum value to the minimum value of the surface resistance, as measured according to ASTM D257, of the composite material is 1×10 2 or less, and
wherein, based on the total weight of the carbon composite material, the content of the carbon nanotuhes is 0.001 to 30% by weight, an average length of the carbon nanotube is 10 to 500 μm, and an aspect ratio of the carbon nanotube is 500 to 5000 and is calculated according to the following Equation (1)
Aspect ratio=Length ( L )/Diameter ( D ),  [Equation 1]

wherein the carbon composite material has a thermal deformation temperature of 95° C. or more.

21. The carbon composite material according to claim 20 , wherein the polymer resin has a number average molecular weight (Mn) of the polymer resin of 15,000 to 100,000.

22. The carbon composite material according to claim 20 , wherein the polymer resin is a polycarbonate resin.

23. The carbon composite material according to claim 22 , wherein polycarbonate resin is a polycarbonate copolytner.

24. The carbon composite material according to claim 20 , comprising 0.1 to 2 weight percent of the carbon nanotube.

25. The carbon composite material according to claim 20 , wherein the carbon composite material has a surface resistance of 10 4 to 10 8 ohm/sq.

26. A molded article comprising the carbon composite material claim 1 .

27. A method for producing the carbon composite material according to claim 1 , comprising mixing:
a polymer resin;
a carbon nanotube;
a glass fiber; and
a phosphate ester derivative,
wherein the carbon nanotube has an aspect ratio of 500 to 5000 and a thermal decomposition temperature of 550 °C or higher.

28. The method according to claim 27 wherein the method further comprises subjecting the mixture to melting, extruding, molding, or a combination thereof.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Seokwon
• Kim Se Hyun
• Kim Tae Hyung
• Kim Pyeong-Gi
• Choi Suk Jo
• Cho Dong Hyun

Classifications

• C08K3/016 Primary

  Flame-proofing or flame-retarding additives · CPC title

• C01B32/168 Primary

  After-treatment · CPC title

• C07F9/09

  Esters of phosphoric acids · CPC title

• C07F9/12

  with hydroxyaryl compounds · CPC title

• C08J5/047

  with mixed fibrous material · CPC title