Integration of fermentation and gasification

Patent metadata

Field	Value
Publication number	US-11772994-B2
Application number	US-202117445160-A
Country	US
Kind code	B2
Filing date	Aug 16, 2021
Priority date	Nov 19, 2018
Publication date	Oct 3, 2023
Grant date	Oct 3, 2023

Abstract

The description describes the integration of a gas fermentation process with a gasification process whereby effluent from the gas fermentation process is recycled to the gasification process. The one or more effluents which can be recycled include a stream comprising microbial biomass, a product stream comprising at least a portion of the at least one fermentation product, a by-product stream comprising fusel oil, and a waste water stream comprising microbial biomass. The stream comprising biomass can be dried before it is passed to the gasification zone. At least a portion of the waste water stream can be passed to the gasification process where one use is to replace at least a portion of the process water. The waste water stream can be further processed to produce a clarified water stream and a biogas stream comprising methane either or both of which can be passed to the gasification process.

First claim

The invention claimed is:

1. An integrated process comprising:
a) passing a carbonaceous material to a gasification process to produce a syngas stream comprising CO and H 2 ;
b) passing the syngas stream to a fermentation process comprising a bioreactor containing a C1-fixing bacteria in a liquid nutrient medium to produce an effluent stream comprising at least one fermentation product and microbial biomass;
c) passing the effluent stream to a product recovery zone to produce a stream comprising microbial biomass, a product stream comprising at least a portion of the at least one fermentation product, a by-product stream comprising fusel oil, and a waste water stream comprising microbial biomass; and
d) passing at least a portion of the waste water stream, to the gasification process wherein the temperature of the syngas stream is reduced by at least 100° C.

2. The process of claim 1 wherein the product stream comprises crude ethanol and at least a portion of the crude ethanol product stream is passed to the gasifier for use as a heat source.

3. The process of claim 2 wherein at least a portion of the crude ethanol product stream is used as a heat source for melting at least a portion of a slag produced by the gasification process.

4. The process of claim 1 wherein at least a portion of the waste water stream is passed to the gasification process and replaces at least a portion of process water required by the gasification process.

5. The method of claim 4 , wherein the process water required by the gasification process is reduced by at least 45 percent.

6. The process of claim 1 further comprising passing at least a portion of the waste water stream comprising microbial biomass to a waste water treatment process to produce a biogas stream and a clarified water stream and passing the biogas stream to the gasifier.

7. The process of claim 6 wherein the biogas stream is used in the gasifier as a heating source.

8. The process of claim 6 wherein the biogas stream is used in the gasifier as a heating source for melting at least a portion of a slag produced by the gasification process.

9. The process of claim 6 wherein the clarified water stream is passed to the gasification process and injected into the syngas stream produced by the gasification process to reduce the temperature of the syngas stream.

10. The process of claim 9 , wherein the temperature of the syngas stream is reduced by at least 100° C.

11. The process of claim 6 wherein the biogas comprises methane and the methane is reformed in the gasifier to produce CO and H 2 .

12. The process of claim 1 wherein at least a part of the by-product stream comprising fusel oil is passed to the gasifier and used as a heating source.

13. The process of claim 1 wherein the stream comprising biomass is passed to a drying zone to produce a dried biomass and the dried biomass is passed to the gasification process.

14. The process of claim 13 wherein the dried biomass contains greater than 20% water to about 40% water by weight.

15. The process of claim 1 wherein the C1-fixing bacteria is selected from the group consisting of: Moorella, Clostridium, Ruminococcus, Acetobacterium, Eubacterium, Butyribacterium, Oxobacter, Methanosarcina , and Desulfotomaculum.

16. An integrated process comprising:
a) passing a carbonaceous material to a gasification process to produce a syngas stream comprising CO and H 2 ;
b) passing the syngas stream to a fermentation process comprising a bioreactor containing a C1-fixing bacteria in a liquid nutrient medium to produce an effluent stream comprising at least one fermentation product and microbial biomass;
c) passing the effluent stream to a product recovery zone to produce a stream comprising microbial biomass, a product stream comprising at least a portion of the at least one fermentation product, a by-product stream comprising fusel oil, and a waste water stream comprising microbial biomass; and
d) passing at least a portion the by-product stream comprising fusel oil to the gasification process for use as a heat source.

17. An integrated process comprising:
a) passing a carbonaceous material to a gasification process to produce a syngas stream comprising CO and H 2 ;
b) passing the syngas stream to a fermentation process comprising a bioreactor containing a C1-fixing bacterium in a liquid nutrient medium to produce an effluent stream comprising an ethanol fermentation product and microbial biomass;
c) passing the effluent stream to a product recovery zone to produce a stream comprising microbial biomass, a product stream comprising crude ethanol, a by-product stream comprising fusel oil, and a waste water stream comprising microbial biomass; and
d) passing at least a portion of the product stream comprising crude ethanol to the gasification process for use as a heat source.

18. The process of claim 17 , wherein at least a portion of the crude ethanol product stream is used as a heat source for melting at least a portion of a slag produced by the gasification process.

Assignees

• Lanzatech Inc

Inventors

• Conrado Robert John
• Gao Allan Haiming

Classifications

• C02F3/2893 Primary

  with biogas recycling · CPC title

• C02F3/121

  Multistep treatment · CPC title

• C10J3/00

  Production of combustible gases containing carbon monoxide from solid carbonaceous fuels (destructive distillation processes C10B) · CPC title

• C10L3/08

  Production of synthetic natural gas · CPC title

• C12M21/04

  for producing gas, e.g. biogas (digesters for manure with production of biogas A01C3/028, biological treatment of water, waste water or sewage C02F3/00, C02F11/02, preparation of natural gas or syngas C10L3/06, C10L3/10) · CPC title