Flexible foaming process for producing thermally insulated articles

Patent metadata

Field	Value
Publication number	US-11772309-B2
Application number	US-202017757461-A
Country	US
Kind code	B2
Filing date	Dec 8, 2020
Priority date	Dec 17, 2019
Publication date	Oct 3, 2023
Grant date	Oct 3, 2023

Abstract

A flexible discontinuous process produces a series of at least two articles containing thermally insulating polyurethane foam from at least three streams (A), (B) and (C). The process involves mixing the at least three streams with different mixing ratios and injecting the mixture into cavities of the articles. A production unit can be used for performing this process.

First claim

The invention claimed is:

1. A discontinuous process for producing a series of at least two articles containing thermally insulating polyurethane foam from at least
a stream (A) comprising at least one isocyanate reactive compound,
a stream (B) comprising at least one organic polyisocyanate, and
a stream (C) comprising either
at least one compound selected from the group consisting of catalysts, blowing agents, chain extenders, stabilizers, crosslinkers, flame retardants, and additives, or
at least one isocyanate reactive compound or at least one organic polyisocyanate, and optionally, at least one further compound selected from the group consisting of catalysts, blowing agents, chain extenders, stabilizers, crosslinkers, flame retardants, and additives;
wherein stream (C) is different from both streams (A) and (B);

wherein the process comprises:
(a) producing at least one first article containing a first thermally insulating polyurethane foam by
(a1) providing a first polyurethane reaction mixture in a mixing device (MD) by mixing at least two of streams (A), (B), and (C);
(a2) injecting the first polyurethane reaction mixture provided in (a1) into a cavity of the at least one first article and forming the first thermally insulating polyurethane foam; and

(b) producing at least one second article containing a second thermally insulating polyurethane foam by
(b1) providing a second polyurethane reaction mixture in the mixing device (MD) by mixing at least two of streams (A), (B), and (C);
(b2) injecting the second polyurethane reaction mixture provided in (b1) into a cavity of the at least one second article and forming the second thermally insulating polyurethane foam;

wherein a mixing ratio of streams (A), (B), and (C) in (at) is different from a mixing ratio of streams (A), (B), and (C) in (b1),
wherein an amount of stream (C) may be zero either in (a1) or in (b1), and
wherein in case the amount of stream (C) is not zero in (a1) or (b1), an amount of stream (A) may be zero if stream (C) comprises at least one isocyanate reactive compound, and an amount of stream (B) may be zero if stream (C) comprises at least one organic polyisocyanate.

2. The process according to claim 1 , wherein the at least one first article and the at least one second article differ in at least one physical and/or chemical property.

3. The process according to claim 1 , wherein each of the first thermally insulating polyurethane foam and the second thermally insulating polyurethane foam is a rigid closed-cell polyurethane foam.

4. The process according to claim 1 , wherein the at least one first article and the at least one second article are each selected from the group consisting of refrigerators: freezers; insulating boxes for cold and hot goods; water heaters; hot water storage tanks; insulation boards; and pipes.

5. The process according to claim 1 , wherein in (a1) and/or (b1), the streams (A), (B), and (C) are fed simultaneously into the mixing device (MD), or
wherein in (a1) and/or (b1), two of the streams (A), (B), and (C) are premixed and fed into the mixing device (MD) simultaneously with a remaining stream of the streams (A), (B), and (C).

6. The process according to claim 1 , wherein in (a1) and (b1), the streams (A), (B), and (C) are provided from separate reservoirs for each of streams (A), (B), and (C), respectively, wherein each of the separate reservoirs are connected with the mixing device (MD) during (a1) and (b1).

7. The process according to claim 1 , wherein in (a1) and/or (b1), an amount of each of streams (A), (B), and (C) is not zero.

8. The process according to claim 1 , wherein the mixing device (MD) is not cleaned between (a) and (b).

9. A computer implemented process for producing a series of at least two articles containing thermally insulating polyurethane foam, the process comprising:
performing the process according to claim 1 with a control unit,
wherein mixing ratios in (a1) and (b1) are controlled by the control unit which is configured to control the feeding of the streams (A), (B), and (C) in (a1) and (b1) into the mixing device (MD).

10. The computer implemented process according to claim 9 , wherein the control unit is programmed to repeat (a) with a first predefined mixing ratio for a first predefined number of times and to repeat (b) with a second predefined mixing ratio for a second predefined number of times.

11. The computer implemented process according to claim 9 , wherein information about the at least one first article and the at least one second article is provided to the control unit by a sensor reading a sensor readable information tag provided with the at least one first article and the at least one second article, and/or
wherein information about ambient conditions of production is provided to the control unit by a sensor for detecting the information about the ambient conditions of production.

12. The computer implemented process according to claim 11 , wherein the sensor readable information tag is a RFID (radio-frequency identification) chip or a 2D code.

13. The computer implemented process according to claim 11 , wherein the sensor for detecting the information about the ambient conditions of production detects at least one ambient condition parameter selected from the group consisting of temperature, humidity, and air pressure.

14. The computer implemented process according to claim 11 , wherein the information about the at least one first article and the at least one second article and/or the information about the ambient conditions of production provided to the control unit either contains the mixing ratio of the streams (A), (B), and (C), or is aligned with data about the mixing ratio from a data base for determining the mixing ratio; and
wherein the control unit adjusts the feeding of the streams (A), (B), and (C) into the mixing device (MD) in (a1) and (b1) according to the mixing ratio.

15. The computer implemented process according to claim 12 , wherein the 2D code is at least one selected from the group consisting of a QR (quick response) code, a variant of a QR code, a data matrix, an Aztec code, a JAB (just another bar code) code, and a bar code.

Assignees

• Basf Se

Inventors

• Wagner Hendrik
• Grever Marko
• Holle Joachim
• Krogmann Joerg

Classifications

• C08J9/146

  only fluorine as halogen atoms · CPC title

• C08G2330/00

  Thermal insulation material · CPC title

• C08G18/4845

  containing oxypropylene or higher oxyalkylene end groups · CPC title

• B29L2031/7622

  Refrigerators · CPC title

• B29C44/08

  using several expanding {or moulding} steps · CPC title