Method and apparatus for treating, sorting and recycling oil-containing discharged catalyst

Patent metadata

Field	Value
Publication number	US-11772091-B2
Application number	US-201716646330-A
Country	US
Kind code	B2
Filing date	Dec 8, 2017
Priority date	Sep 13, 2017
Publication date	Oct 3, 2023
Grant date	Oct 3, 2023

Abstract

The present disclosure relates to a method and an apparatus for treating, sorting and recycling an oil-containing discharged catalyst. There is provided a method for treating, sorting and recycling an oil-containing discharged catalyst, wherein the method comprises the following steps: (A) cyclonic washing and on-line activation of a discharged catalyst; (B) cyclonic spinning solvent stripping of the catalyst; (C) gas stream acceleration sorting of a high activity catalyst; (D) cyclonic restriping and particle capture of the high activity catalyst; and (E) cooling of the gas and condensation removal of the solvent. There is further provided an apparatus for treating, sorting and recycling an oil-containing discharged catalyst.

First claim

What is claimed is:

1. A method for treating, sorting and recycling an oil-containing discharged catalyst, wherein the method comprises the following steps:
(A) cyclonic washing and on-line activation of a discharged catalyst: asphaltenes, resins and heavy aromatics in the discharged catalyst are subjected to cyclonic washing to achieve on-line activation of the catalyst;
(B) cyclonic spinning solvent stripping of the catalyst: catalyst particles obtained in step (A) are subjected to high-temperature gas cyclonic spinning reinforced stripping using a gas stream to remove a solvent entrained in the catalyst;
(C) gas stream acceleration sorting of a high activity catalyst: high activity catalyst particles are sorted out from the catalyst obtained in step (B) using the gas stream, wherein the high activity catalyst and a low activity catalyst are subject to different net pulsing displacement directions in a pulsing gas flow field of the gas stream;
(D) cyclonic restriping and particle capture of the high activity catalyst: the high activity catalyst particles discharged along with the gas stream after the sorting in step (C) are further subjected to cyclonic spinning reinforced solvent stripping, while cyclonic capture of the catalyst particles is performed at the same time to recycle the high activity catalyst particles; and
(E) cooling of the gas and condensation removal of the solvent: the gas stream from step (D) is cooled after the cyclonic capture, and the entrained solvent is condensed, so as to obtain a pure gas for circulation.

2. The method of claim 1 , wherein, in step (A), the discharged catalyst includes liquid-containing solid particles in a process selected from the group consisting of heavy oil hydrogenation, catalytic reformation, catalytic cracking, hydrocracking and hydrogenation refining; and wherein the solvent used is gasoline, diesel, or an organic solvent capable of dissolving asphaltenes, resins and heavy aromatics in the discharged catalyst;
wherein the cyclonic washing is performed in a cyclonic field, wherein oil on a surface of the discharged catalyst and in pores of the discharged catalyst is subjected to cyclonic reinforced washing under a mechanical detaching action in a shear force field in the cyclonic field and a centrifugal desorption action of spinning of the catalyst particles on pollutants in the pores; and
wherein the discharged catalyst particles spin in the cyclonic field to renew the catalyst particle surface coated by heavy hydrocarbons, and strengthen active sites of the catalyst, so as to achieve on-line activation of the catalyst.

3. The method of claim 1 , wherein, in step (B), the solvent stripping is performed in a cyclonic field, wherein spinning of the particles in the cyclonic field accelerates renewal of a contact interface between the solvent on the particle surface and the gas stream, so as to reinforce the stripping process for removing the solvent, wherein the gas is nitrogen, hydrogen, dry gas or low gas, and a temperature is 200-400° C.

4. The method of claim 1 , wherein, in step (C), the gas stream has a cyclically pulsing flow rate, wherein catalysts having different activities have different particle densities, and have different accelerations in the pulsing gas flow field, so as to have different motion tracks and displacements, thereby realizing efficient separation of high activity and low activity catalysts.

5. The method of claim 1 , wherein, in step (D), the high activity catalyst in a gas phase is separated wherein the separation has a separation factor greater than 1000 times a separation factor of gravity settling, such that the gas phase is free of the catalyst particles after separation, and at the same time, spinning of the catalyst particles in a cyclone further reinforces the solvent stripping.

6. An apparatus for use in the method of claim 1 for treating, sorting and recycling an oil-containing discharged catalyst, wherein the apparatus comprises:
a catalyst charge/discharge tank 4 and a cyclonic activation washer 5 coupled to the catalyst charge/discharge tank 4 for cyclonic washing and on-line activation of the discharged catalyst in step (A);
a cyclonic desorption stripping tank 7 coupled with the cyclonic activation washer 5 for cyclonic spinning solvent stripping of the catalyst in step (B);
a gas stream acceleration sorter 9 coupled with the cyclonic desorption stripping tank 7 and a pulsing gas stream generator 8 coupled with the gas stream acceleration sorter 9 for gas stream acceleration sorting of the high activity catalyst in step (C);
a high activity agent storage tank 11 coupled with the gas stream acceleration sorter 9 for cyclonic restripping and particle capture of the high activity catalyst in step (D); and
a gas purifying tower 13 coupled with the high activity agent storage tank 11 for cooling of the gas and condensation removal of the solvent in step (E).

7. The apparatus of claim 6 , wherein a liquid-solid cyclone is arranged in each of the catalyst charge/discharge tank 4 and the cyclonic activation washer 5 , wherein spinning of the particles in the cyclone enables the reinforced washing and on-line activation of the catalyst.

8. The apparatus of claim 6 , wherein the apparatus further comprises a pipeline heater 6 coupled with the cyclonic desorption stripping tank 7 for heating the gas stream in the cyclonic desorption stripping tank 7 to 200-400° C. to enable cyclonic reinforced stripping of the solvent entrained in the catalyst particles after the cyclonic washing, so as to remove the entrained solvent.

9. The apparatus of claim 6 , wherein the gas stream acceleration sorter 9 comprises a catalyst inlet, a gas stream inlet, a gas stream distributing plate, a high activity agent outlet and a low activity agent outlet;
wherein the pulsing gas stream generator 8 enables generation of a pulsing gas stream in the gas stream acceleration sorter 9 , wherein a maximum flow rate of the gas stream is such that a maximum flow velocity of the gas stream in a sorting column resides between a final free settling velocity of the high activity particles and a final free settling velocity of the low activity particles;
wherein under impact of the pulsing gas stream, the low activity particles having a larger density has a negative displacement that is larger than a positive displacement, resulting in a net displacement that is negative, and move downward directly from the low activity agent outlet to the low activity agent storage tank 10 ; wherein the high activity particles having a smaller density has a positive displacement that is larger than a negative displacement, resulting in a net displacement that is positive, and are discharged from the high activity catalyst outlet along with the gas stream; and
wherein the pulsing gas stream generator 8 comprises a variable frequency pulse valve.

10. The apparatus of claim 6 , wherein a gas-solid cyclone separator is positioned in the high activity agent storage tank 11 to enable reinforcement of the spinning restripping as well as the cyclonic separation and capture of the high activity catalyst entrained in the gas stream, resulting in dry high activity catalyst particles for recycling, wherein the capture of the catalyst has an efficiency of higher than 99%.

Assignees

• Shanghai Huachang Env Prot Co Ltd
• Univ Sichuan

Inventors

• Wang Hualin
• Fu Pengbo
• Huang Zhaohui
• Huang Aibin
• Huang Cheng
• Sun Jianhuai
• Zhao Ying
• Li Liquan
• Chen Chonggang
• Zeng Qian
• Li Jianping
• Fang Yilin
• Wang Fei
• Jiang Xia

Classifications

• B01J38/58 Primary

  and gas addition thereto · CPC title

• B01D5/00

  Condensation of vapours; Recovering volatile solvents by condensation (B01D8/00 takes precedence; condensers F28B) · CPC title

• B01D45/16

  generated by the winding course of the gas stream {, the centrifugal forces being generated solely or partly by mechanical means, e.g. fixed swirl vanes} · CPC title

• B01J8/0055

  using cyclones · CPC title

• B01J8/16

  with particles being subjected to vibrations or pulsations (B01J8/40 takes precedence) · CPC title