Electrode material, method for manufacturing electrode material, electrode, and lithium ion battery

Patent metadata

Field	Value
Publication number	US-11769875-B2
Application number	US-201916559773-A
Country	US
Kind code	B2
Filing date	Sep 4, 2019
Priority date	Mar 7, 2019
Publication date	Sep 26, 2023
Grant date	Sep 26, 2023

Abstract

An electrode material including a carbonaceous-coated electrode active material having primary particles of the electrode active material and secondary particles that are aggregates of the primary particles, and a carbonaceous film that coats the primary particles of the electrode active material and the secondary particles that are the aggregates of the primary particles, in which a specific surface area, which is obtained using a nitrogen adsorption method, is 4 m 2 /g or more and 40 m 2 /g or less, a volume of micropores per unit mass is 0.05 cm 3 /g or more and 0.3 cm 3 /g or less, and an average micropore diameter, which is obtained from the volume of the micropores per unit mass and the specific surface area, is 26 nm or more and 90 nm or less.

First claim

What is claimed is:

1. A carbonaceous-coated electrode active material having
primary particles of the electrode active material and secondary particles that are aggregates of the primary particles, and
a carbonaceous film that coats the primary particles of the electrode active material and the secondary particles that are the aggregates of the primary particles,
wherein the carbonaceous-coated electrode active material has a specific surface area, which is obtained using a nitrogen adsorption method, being 4 m 2 /g or more and 40 m 2 /g or less, and a volume of micropores having a micropore diameter of 200 nm or less per unit mass, which is obtained using the nitrogen adsorption method, is 0.122 cm 3 /g or more and 0.162 cm 3 /g or less, and the carbonaceous-coated electrode active material has an average micropore diameter, which is obtained from the volume of the micropores having a micropore diameter of 200 nm or less per unit mass and the specific surface area, being 26 nm or more and 90 nm or less, and
wherein a crystallite diameter of the electrode active material is 30 nm or more and 250 nm or less.

2. The carbonaceous-coated electrode active material according to claim 1 , wherein the electrode active material is an electrode active material represented by General Formula (1):
Li a A x M y BO z   (1)

in the formula,
A represents at least one element selected from the group consisting of Mn, Fe, Co, and Ni,
M represents at least one element selected from the group consisting of Na, K, Mg, Ca, Al, Ga, Ti, V, Cr, Cu, Zn, Y, Zr, Nb, Mo, and rare earth elements,
B represents at least one element selected from the group consisting of B, P, Si, and S,
0≤a<4,
0<x<1.5,
0≤y<1, and
0<z≤4.

3. The carbonaceous-coated electrode active material according to claim 2 , wherein the electrode active material represented by General Formula (1) is an electrode active material represented by General Formula (2):
Li a A x M y PO 4   (2)

in the formula,
A represents at least one element selected from the group consisting of Mn, Fe, Co, and Ni,
M represents at least one element selected from the group consisting of Na, K, Mg, Ca, Al, Ga, Ti, V, Cr, Cu, Zn, Y, Zr, Nb, Mo, and rare earth elements,
0≤a<4, 0<x<1.5, and
0≤y<1.

4. A method for manufacturing the carbonaceous-coated electrode active material according to claim 1 , the method comprising:
drying a slurry obtained by mixing an organic substance including sugar and an ionic organic substance as a carbon source, one or more selected from the electrode active material and an electrode active material precursor, and a solvent by using a spray dryer and granulating the slurry to form a granulated substance, wherein the ionic organic substance is alkyl benzene sulfonate; and
thermally treating the granulated substance in a non-oxidative atmosphere at 600° C. or higher and 1,000° C. or lower.

5. An electrode formed using the carbonaceous-coated electrode active material, according to claim 1 , as one component of the electrode.

6. A lithium ion battery comprising:
a positive electrode made of the electrode according to claim 5 .

Assignees

• Sumitomo Osaka Cement Co Ltd
• Sumitomo Metal Mining Co

Inventors

• Oono Kouji
• Oshitari Satoru
• Nozoe Tsutomu
• Oyama Masataka

Classifications

• H01M4/382 Primary

  Lithium (H01M4/405 takes precedence) · CPC title

• H01M4/0419

  involving spraying · CPC title

• H01M4/133

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M4/23

  Drying or preserving electrodes after forming · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title