Inverting aids for latex-based drag reducing agents

Patent metadata

Field	Value
Publication number	US-11767487-B2
Application number	US-202016927619-A
Country	US
Kind code	B2
Filing date	Jul 13, 2020
Priority date	Jul 13, 2020
Publication date	Sep 26, 2023
Grant date	Sep 26, 2023

Abstract

An oxyalkylated branched aliphatic compound produced by oxyalkylating a branched aliphatic compound having 12 or more carbon atoms in which the branched aliphatic compound having 12 or more carbon atoms is grafted with a polyether via a crosslinking reaction, wherein the polyether is a polymer of ethylene oxide, propylene oxide, butylene oxide, and combinations thereof, may be useful as an inverting aid for increasing the dissolution rate of a latex-based drag reducing agent in a liquid hydrocarbon.

First claim

What is claimed is:

1. A method for enhancing the dissolution rate of a latex-based drag reducing agent in a liquid hydrocarbon stream, the method comprising:
providing a branched aliphatic compound having a chain of 12 or more carbon atoms, wherein the branched aliphatic compound comprises branches, each branch comprising a functional group selected from the group consisting of alkyl groups, arylalkyl groups, cycloalkyl groups, and combinations thereof, wherein the functional group has 2 to 28 carbons;
oxyalkylating the branched aliphatic compound to form an oxyalkylated branched aliphatic compound having 12 or more carbon atoms;
admixing the oxyalkylated branched aliphatic compound with the latex-based drag reducing agent in the liquid hydrocarbon stream in an amount effective to increase the dissolution rate of the latex-based drag reducing agent into the liquid hydrocarbon stream; and
increasing the dissolution rate of the latex-based drag reducing agent in the liquid hydrocarbon stream.

2. The method of claim 1 , wherein the branched aliphatic compound having 12 or more carbon atoms is crosslinked to another branched aliphatic compound to form dendrimers.

3. The method of claim 2 , wherein the dendrimers are hyperbranched aliphatic compound.

4. The method of claim 1 , wherein the branches further comprise functional groups selected from the group consisting of oxygen functional groups, nitrogen functional groups, sulfur functional groups, phosphorous functional groups, and combinations thereof.

5. The method of claim 1 , wherein the branched aliphatic compound having 12 or more carbon atoms is grafted with a polyether via a ring-opening reaction.

6. The method of claim 5 , wherein the polyether is selected from a group consisting of a polymer of ethylene oxide, a polymer of propylene oxide, a polymer of butylene oxide, and combinations thereof.

7. The method of claim 1 , wherein the latex-based drag reducing agent is selected from a group consisting of polymers of acrylates, methacrylates, acrylamide, methacrylamides, vinyl formamides, styrenic-based polymers and combinations thereof; olefin maleic esters; aliphatic olefin maleic imides; polyol-based polymers; acrylate-based polymers; methacrylate-based polymers; maleate-based polymers; and combinations thereof.

8. The method of claim 1 , wherein:
the liquid hydrocarbon is crude oil, and
the effective amount of oxyalkylated branched aliphatic compound ranges from 0.1 wt. % to about 50 wt. %, based on total weight of oxyalkylated branched aliphatic compound and the latex-based drag reducing agent.

9. An inverting aid-enhanced latex-based drag reducing agent formulation, the formulation comprising:
an oxyalkylated branched aliphatic compound having a chain of 12 or more carbons and comprising branches, wherein each of the branches comprises a functional group selected from the group consisting of alkyl groups having 2 to 28 carbon atoms, arylalkyl groups having 2 to 28 carbon atoms, cycloalkyl groups having 2 to 28 carbon atoms, and combinations thereof; and
a latex-based drag reducing agent;
where the oxyalkylated branched aliphatic compound is present in an amount ranging from 0.1 wt. % to about 10 wt. %, based on total weight of oxyalkylated branched aliphatic compound and the latex-based drag reducing agent.

10. The formulation of claim 9 , wherein the oxyalkylated branched aliphatic compound is formed by oxyalkylating a branched aliphatic compound having 12 or more carbon atoms.

11. The formulation of claim 9 , wherein the branches of the oxyalkylated branched aliphatic compound further comprise functional groups selected from the group consisting of oxygen functional groups, nitrogen functional groups, sulfur functional groups, phosphorous functional groups, and combinations thereof.

12. The formulation of claim 10 , wherein the branched aliphatic compound having 12 or more carbon atoms is grafted with a polyether via a crosslinking-reaction.

13. The formulation of claim 12 , wherein the polyether is selected from a group consisting of a polymer of ethylene oxide, a polymer of propylene oxide, a polymer of butylene oxide, and combinations thereof.

14. The formulation of claim 9 , wherein the latex-based drag reducing agent is selected from a group consisting of polymers of acrylates, methacrylates, acrylamide, methacrylamides, vinyl formamides, styrenic-based polymers and combinations thereof; olefin maleic esters; aliphatic olefin maleic imides; polyol-based polymers; acrylate-based polymers; methacrylate-based polymers; maleate-based polymers; and combinations thereof.

15. A treated hydrocarbon stream comprising:
a liquid hydrocarbon stream;
an oxyalkylated branched aliphatic compound having a chain of 12 or more carbons and comprising branches, wherein each of the branches comprises a functional group selected from the group consisting of alkyl groups having 2 to 28 carbon atoms, arylalkyl groups having 2 to 28 carbon atoms, cycloalkyl groups having 2 to 28 carbon atoms, and combinations thereof; and
a latex-based drag reducing agent;
wherein the oxyalkylated branched aliphatic compound is present in an amount effective to increase the dissolution rate of the latex-based drag reducing agent in the liquid hydrocarbon stream, the amount ranging from 0.1 wt. % to about 50 wt. %, based on total weight of oxyalkylated branched aliphatic compound and the latex-based drag reducing agent.

16. The treated hydrocarbon stream of claim 15 , wherein the liquid hydrocarbon stream is crude oil.

Assignees

• Baker Hughes Oilfield Operations Llc

Inventors

• Carrasco Analette
• Mangadlao Joey Dacula

Classifications

• C10M145/26 Primary

  Polyoxyalkylenes · CPC title

• C10G71/00 Primary

  Treatment by methods not otherwise provided for of hydrocarbon oils or fatty oils for lubricating purposes · CPC title

• C10M169/041

  the additives being macromolecular compounds only · CPC title

• C10M173/02

  not containing mineral or fatty oils · CPC title

• C10M2205/043

  used as base material · CPC title