Electrically conductive cellulose-based composite material

Patent metadata

Field	Value
Publication number	US-11767439-B2
Application number	US-201917262669-A
Country	US
Kind code	B2
Filing date	Jul 19, 2019
Priority date	Jul 23, 2018
Publication date	Sep 26, 2023
Grant date	Sep 26, 2023

Abstract

Cellulose-based composite material comprising an electrically conductive material dispersed in a matrix comprising at least one plant-derived protein and a polymer of aleuritic acid, said composite material being obtainable by a process comprising the steps of dissolving at least one plant-derived protein and aleuritic acid in a dissolving solution to achieve a first mixture, dispersing an electrically conductive material in said first mixture to achieve a conductive ink, distributing said conductive ink on at least one side of a cellulose substrate to achieve a coated cellulose substrate, hot-pressing said coated cellulose substrate to obtain i) impregnation of the cellulose substrate with said conductive ink and ii) polymerization of aleuritic acid.

First claim

The invention claimed is:

1. Cellulose-based composite material comprising an electrically conductive material dispersed in a matrix containing at least one plant-derived protein and a polymer of aleuritic acid, said cellulose-based composite material being obtainable by a process comprising the steps of:
dissolving the at least one plant-derived protein and the aleuritic acid in a dissolving solution to achieve a first mixture,
dispersing an electrically conductive material in said first mixture to achieve a conductive ink,
distributing said conductive ink on at least one side of a cellulose substrate to achieve a coated cellulose substrate,
hot-pressing said coated cellulose substrate to obtain i) impregnation of the cellulose substrate with said conductive ink and ii) polymerization of the aleuritic acid.

2. Cellulose-based composite material according to claim 1 , wherein the at least one plant-derived protein is present in the dissolving solution in an amount comprised between 50 and 75% by weight of a total amount of the at least one plant-derived protein plus the aleuritic acid.

3. Cellulose-based composite material according to claim 1 , wherein said at least one plant-derived protein is selected between gliadin and zein.

4. Cellulose-based composite material according to claim 1 , wherein the aleuritic acid is present in the dissolving solution in an amount comprised between 25 and 50% of a total amount of the at least one plant-derived protein plus the aleuritic acid.

5. Cellulose-based composite material according to claim 1 , wherein the electrically conductive material is selected in the group consisting of graphene nanoplatelets, carbon nanofiber, carbon nanotube, carbon black, silver nanoparticles, gold nanoparticles, aluminum nanoparticles, and mixtures thereof.

6. Cellulose-based composite material according to claim 1 , wherein said electrically conductive material consists of graphene nanoplatelets.

7. Cellulose-based composite material according to claim 1 , wherein said electrically conductive material is dispersed in said dissolving solution in an amount comprised between 2 and 40% by weight of a total amount of the at least one plant-derived protein plus the aleuritic acid in order to achieve said conductive ink.

8. Cellulose-based composite material according to claim 1 , wherein the cellulose substrate has a thickness comprised between 30 and 100 μm.

9. Cellulose-based composite material according to claim 1 , wherein said hot-pressing is carried out at a temperature comprised between 160 and 200° C.

10. Cellulose-based composite material according to claim 1 , wherein said hot-pressing is carried out at a pressure comprised between 5 and 20 bar.

11. Cellulose-based composite material according to claim 1 , wherein the dissolving solution comprises methanol and chloroform.

12. Cellulose-based composite material according to claim 1 , wherein the distributing of said conductive ink on at least one side of a cellulose substrate to achieve a coated cellulose substrate is carried out by spray coating.

13. Cellulose-based composite material according to claim 1 , wherein the at least one plant-derived protein is present in the dissolving solution in an amount comprised between 50 and 60% of a total amount of the at least one plant-derived protein plus the aleuritic acid.

14. Cellulose-based composite material according to claim 1 , wherein the at least one plant-derived protein is present in the dissolving solution in an amount of 55% of a total amount of the at least one plant-derived protein plus the aleuritic acid.

15. Cellulose-based composite material according to claim 1 , wherein said at least one plant-derived protein is zein.

16. Cellulose-based composite material according to claim 1 , wherein the aleuritic acid is present in the dissolving solution in an amount comprised between 40 and 50% of a total amount of the at least one plant-derived protein plus the aleuritic acid.

17. Cellulose-based composite material according to claim 1 , wherein the aleuritic acid is present in the dissolving solution in an amount of 45% of a total amount of the at least one plant-derived protein plus the aleuritic acid.

18. Cellulose-based composite material according to claim 1 , wherein said electrically conductive material is dispersed in said dissolving solution in an amount comprised between 30 and 40% of a total amount of the at least one plant-derived protein plus the aleuritic acid in order to achieve said conductive ink.

19. Cellulose-based composite material according to claim 1 , wherein said electrically conductive material is dispersed in said dissolving solution in an amount of 30% of a total amount of the at least one plant-derived protein plus the aleuritic acid in order to achieve a conductive ink.

20. Cellulose-based composite material according to claim 1 , wherein the cellulose substrate has a thickness comprised between 30 and 70 μm.

21. Cellulose-based composite material according to claim 1 , wherein said hot-pressing is carried out at a temperature of 190° C.

22. Cellulose-based composite material according to claim 1 , wherein said hot-pressing is carried out at a pressure comprised between 10 and 20 bar.

23. Cellulose-based composite material according to claim 1 , wherein said hot-pressing is carried out at a pressure of 20 bar.

24. Cellulose-based composite material according to claim 1 , wherein the dissolving solution comprises methanol and chloroform in a volume ratio (v/v) of 1:1.

25. Cellulose-based composite material comprising a cellulose substrate impregnated with an electrically conductive material dispersed in a matrix containing at zein and polyaleuritate.

Assignees

• Fondazione St Italiano Tecnologia

Inventors

• Bayer Ilker S
• Cataldi Pietro
• Athanasiou Athanasia

Classifications

• C09D11/04 Primary

  based on proteins · CPC title

• C09D11/08

  based on natural resins · CPC title

• C09D11/14

  based on carbohydrates · CPC title

• C09D11/52

  Electrically conductive inks · CPC title

• D21H19/38

  characterised by the pigments · CPC title