Porous polymer actuator and method for fabricating the same

Patent metadata

Field	Value
Publication number	US-11767437-B2
Application number	US-202117234800-A
Country	US
Kind code	B2
Filing date	Apr 20, 2021
Priority date	Nov 19, 2020
Publication date	Sep 26, 2023
Grant date	Sep 26, 2023

Abstract

The present disclosure relates to a porous polymer actuator which maintains the porous structure of the polymer actuator by forming a conductive polymer layer on a commercially available porous polymer separation membrane by vapor-phase polymerization and is capable of improving fast responsiveness to organic solvents and durability by ensuring structural anisotropy, and a method for fabricating the same. The porous polymer actuator according to the present disclosure includes: a porous polymer separation membrane having pores; and a conductive polymer layer coated on one surface and in the pores of the porous polymer separation membrane, wherein the porous polymer actuator has a gradient wherein the amount of the conductive polymer coated in the pores decreases from the one surface of the porous polymer separation membrane toward the other surface.

First claim

The invention claimed is:

1. A porous polymer actuator comprising:
a porous polymer separation membrane having pores; and
a conductive polymer layer coated on one surface and in the pores of the porous polymer separation membrane,
wherein the porous polymer actuator has a gradient wherein the amount of the conductive polymer coated in the pores decreases from the one surface of the porous polymer separation membrane toward the other surface.

2. The porous polymer actuator according to claim 1 , which has, due to the gradient wherein the amount of the conductive polymer coated in the pores decreases from the one surface of the porous polymer separation membrane toward the other surface, a gradient wherein volume expansivity decreases from the one surface of the porous polymer separation membrane toward the other surface upon contact of the porous polymer actuator with an organic solvent.

3. The porous polymer actuator according to claim 2 , wherein the organic solvent is a liquid organic solvent or an organic solvent vapor.

4. The porous polymer actuator according to claim 1 , wherein
a conductive polymer is coated partly also on the other surface of the porous polymer separation membrane, and
the porous polymer actuator has a gradient wherein the content of a specific element comprised in the conductive polymer decreases from the one surface of the porous polymer separation membrane toward the other surface.

5. The porous polymer actuator according to claim 4 , which has, if the conductive polymer is polypyrrole or poly(3-heptylpyrrole) (P3HP), a gradient wherein the content of nitrogen (N) comprised in the conductive polymer decreases from the one surface of the porous polymer separation membrane toward the other surface.

6. The porous polymer actuator according to claim 4 , which has, if the conductive polymer is any of poly(3,4-ethylenedioxythiophene) (PEDOT), poly(3-hexylthiophene) (P3HT) and polythiophene, a gradient wherein the content of sulfur (S) comprised in the conductive polymer decreases from the one surface of the porous polymer separation membrane toward the other surface.

7. The porous polymer actuator according to claim 4 , which has, if the conductive polymer is polyfuran, a gradient wherein the content of oxygen (O) comprised in the conductive polymer decreases from the one surface of the porous polymer separation membrane toward the other surface.

8. The porous polymer actuator according to claim 4 , wherein if the conductive polymer is polypyrrole, the porous polymer actuator has a gradient wherein the content of nitrogen (N) contained in the conductive polymer decreases from the one surface of the porous polymer separation membrane toward the other surface, and the difference in nitrogen content between the one surface and the other surface of the porous polymer separation membrane is 2% or greater.

9. The porous polymer actuator according to claim 1 , wherein the porous polymer separation membrane is made of any of polyvinylidene fluoride (PVDF), polycarbonate (PC), polyimide (PI), nylon, and fluorodyne.

10. The porous polymer actuator according to claim 1 , wherein the conductive polymer is any of polypyrrole (PPy), poly(3,4-ethylenedioxythiophene) (PEDOT), poly(3-hexylthiophene) (P3HT), poly(3-heptylpyrrole) (P3HP), polythiophene, and polyfuran.

11. A method for fabricating a porous polymer actuator, comprising:
a step of preparing a porous polymer separation membrane having pores;
a step of forming an oxidizing agent for vapor-phase polymerization on one surface of the porous polymer separation membrane; and
a step of forming a conductive polymer layer on the one surface and in the pores of the porous polymer separation membrane through vapor-phase polymerization,
wherein the porous polymer actuator has a gradient wherein the amount of the conductive polymer coated in the pores decreases from the one surface of the porous polymer separation membrane toward the other surface.

12. The method for fabricating a porous polymer actuator according to claim 11 , wherein,
in the step of forming the conductive polymer layer on the one surface and in the pores of the porous polymer separation membrane through vapor-phase polymerization,
the conductive polymer formed by vapor-phase polymerization is coated in the pores of the porous polymer separation membrane by diffusion of monomers and also is partly coated on the other surface of the porous polymer separation membrane, and
the porous polymer actuator has a gradient wherein the content of a specific element comprised in the conductive polymer decreases from the one surface of the porous polymer separation membrane toward the other surface.

13. The method for fabricating a porous polymer actuator according to claim 11 , wherein the porous polymer separation membrane is made of any of polyvinylidene fluoride (PVDF), polycarbonate (PC), polyimide (PI), nylon, and fluorodyne.

14. The method for fabricating a porous polymer actuator according to claim 11 , wherein the step of forming the conductive polymer layer on the one surface and in the pores of the porous polymer separation membrane through vapor-phase polymerization comprises:
a process wherein the porous polymer separation membrane with the oxidizing agent for vapor-phase polymerization is provided in a chamber,
a process wherein a monomer solution is added dropwise on a region of the chamber where the porous polymer separation membrane is not located, and
a process wherein the added monomer solution is vaporized and the monomer is polymerized into a conductive polymer by the oxidizing agent for vapor-phase polymerization by diffusion of the monomers on the one surface of the porous polymer separation membrane.

15. The method for fabricating a porous polymer actuator according to claim 14 , wherein
the monomer is any of pyrrole, 3,4-ethylenedioxythiophene (EDOT), 3-hexylthiophene (3HT), 3-heptylpyrrole (3HP), thiophene, and furan, and
the conductive polymer is any of polypyrrole (PPy), poly(3,4-ethylenedioxythiophene) (PEDOT), poly(3-hexylthiophene) (P3HT), poly(3-heptylpyrrole) (P3HP), polythiophene, and polyfuran.

16. The method for fabricating a porous polymer actuator according to claim 11 , wherein the oxidizing agent for vapor-phase polymerization is a trivalent iron salt or ammonium peroxydisulfate.

17. The method for fabricating a porous polymer actuator according to claim 11 , wherein the step of forming the oxidizing agent for vapor-phase polymerization on the one surface of the porous polymer separation membrane comprises:
a process wherein an oxidizing agent solution for vapor-phase polymerization is coated on the one surface of the porous polymer separation membrane, and
a process wherein the porous polymer separation membrane coated with the oxidizing agent solution for vapor-phase polymerization is dried,
wherein a solute content of the oxidizing agent solution for vapor-phase polymerization is 10-70 wt %.

18. The method for fabricating a porous polymer actuator according to claim 11 , wherein the step of forming the oxidizing agent for vapor-phase polymerization on the one surface of the porous polymer separation membrane comprises:
a process wherein an oxidizing agent solution for vapor-phase polymerization is coated on the one surface of the porous polymer separation membrane, and
a process wherein the porous polymer separation membrane coated with the oxidizing agent solution for vapor-phase polymerization is dried,
wherein 10-50 μL of the oxidizing agent solution for vapor-phase polymerization i

Assignees

• Korea Inst Sci & Tech

Inventors

• Byun Jee Hye
• Jeong Seong Pil

Classifications

• C09D5/24 Primary

  Electrically-conducting paints {(conductive materials H01B1/00)} · CPC title

• B05D1/60

  Deposition of organic layers from vapour phase (vapour phase deposition in general C23C14/00, C23C16/00) · CPC title

• C08J7/044

  Forming conductive coatings; Forming coatings having anti-static properties · CPC title

• C08J7/0427

  with only one layer of a composition containing a polymer binder (with more layers C08J7/042) · CPC title

• C09D165/00

  Coating compositions based on macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain (C09D107/00 - C09D157/00, C09D161/00 take precedence); Coating compositions based on derivatives of such polymers · CPC title