rABS/PBT/ASG composite material and preparation method thereof

Patent metadata

Field	Value
Publication number	US-11767422-B2
Application number	US-201917311008-A
Country	US
Kind code	B2
Filing date	Oct 18, 2019
Priority date	Dec 6, 2018
Publication date	Sep 26, 2023
Grant date	Sep 26, 2023

Abstract

A rABS/PBT/ASG composite material and a preparation method thereof utilize the characteristics of rABS with carboxyl and hydroxyl groups, wherein rABS are pre-blended with ASG to increase the viscosity, so that the epoxy groups on the ASG molecules react with the hydroxyl groups and the carboxyl groups on the rABS, and the acrylonitrile-styrene segments in ASG and rABS are thermodynamically miscible, followed by reacting and blending with PBT to prepare the rABS/PBT/ASG composite material. ASG acts as a chain extender and solubilizer in the mixture. The mixture prepared in this way have good compatibility, and the tensile strength, impact strength and elongation at break of the composite material are comprehensively improved. The composite material obtained has the advantages of both ABS and PBT materials, which has broad application prospects in the field of ABS plastic recycling.

First claim

The invention claimed is:

1. A method for preparing a rABS/PBT/ASG composite material, characterized in that it comprises the following steps: melt blending rABS and ASG, then adding PBT for melt blending, successively cooling, air-drying, crushing and drying the resulted mixture to obtain the rABS/PBT/ASG composite material.

2. The method for preparing the rABS/PBT/ASG composite material according to claim 1 , wherein:
the rABS is particles obtained by screening, crushing by a crusher, washing, drying, extruding, pelletizing and drying of waste ABS;
the PBT is commonly used commercially available extrusion-grade particles.

3. The method for preparing the rABS/PBT/ASG composite material according to claim 1 , wherein: the mass ratio of styrene, acrylonitrile and glycidyl methacrylate in the ASG is St/AN/GMA=65/25/6.

4. The method for preparing the rABS/PBT/ASG composite material according to claim 1 , wherein: the mass parts of rABS and PBT in the mixture are 70 parts of rABS and 30 parts of PBT.

5. The method for preparing the rABS/PBT/ASG composite material according to claim 1 , wherein: the weight of ASG in the mixture is 2%-8% of the total weight of rABS and PBT.

6. The method for preparing the rABS/PBT/ASG composite material according to claim 1 , wherein:
the time for melt blending rABS and ASG is 4-6 min;
the total blending time for melt blending the rABS is 10-12 min.

7. The method for preparing the rABS/PBT/ASG composite material according to claim 1 , wherein: the temperature of the melt blending is 220-250° C.

8. The method for preparing the rABS/PBT/ASG composite material according to claim 1 , wherein: the rotor speed of the melt blending is 40-60 rpm.

9. The method for preparing the rABS/PBT/ASG composite material according to claim 3 , wherein: the ASG is prepared by the following method: measuring 200 mL of deionized water in a beaker, adding 1 g of polyvinyl alcohol, stirring and pouring into a 1 L three-necked flask; successively measuring 100 ml of deionized water to wash the beaker for 3 times, pouring the washed solution into the three-necked flask, heating and stirring at a heating temperature of 65° C., wherein the stirring speed is configured to allow the liquid to swirl but not splashing; after the temperature is stable for 30 minutes, adding 65 g of refined styrene, 25 g of acrylonitrile, 6 g of glycidyl methacrylate, and 1 g of dibenzoyl peroxide in a three-necked flask, heating and stirring for 7˜8 h, raising the temperature to 75° C. to harden for 1˜2 h, conducting suction filtration and washing the product with hot water for 3˜5 times to remove monomers, and drying the obtained ASG beads at 45° C. for 12 h.

10. A rABS/PBT/ASG composite material, obtained by the method of claim 1 .

Assignees

• Univ South China Tech

Inventors

• He Hezhi
• Zhan Zhiming
• Feng Yanhong
• Yin Xiaochun
• Qu Jinping

Classifications

• C08L55/02 Primary

  ABS [Acrylonitrile-Butadiene-Styrene] polymers · CPC title

• C08J3/005

  Processes for mixing polymers · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C08L2207/20

  Recycled plastic · CPC title

• C08J3/18 Primary

  Plasticising macromolecular compounds (plasticisers C08K) · CPC title