Water soluble film, packets employing the film, and methods of making and using same

Patent metadata

Field	Value
Publication number	US-11767405-B2
Application number	US-201716090035-A
Country	US
Kind code	B2
Filing date	Apr 13, 2017
Priority date	Apr 13, 2016
Publication date	Sep 26, 2023
Grant date	Sep 26, 2023

Abstract

A water-soluble film including a polyvinyl alcohol resin blend is disclosed herein. Also disclosed are related packets incorporating the film, and related methods of making and using the film and packets.

First claim

What is claimed is:

1. A film comprising a blend of at least two different polyvinyl alcohol (PVOH) polymers, comprising
a. from 10% to 50% by weight of the blend of at least two different polyvinyl alcohol polymers of a first polyvinyl alcohol polymer comprising at least two monomers, the first monomer comprising a maleic acid derived monomer unit, a second monomer comprising a vinyl alcohol monomer unit, and optionally third monomer comprising a vinyl acetate monomer unit, the amount of maleic acid derived monomer unit is between 3 mol % and 6 mol % of the first polyvinyl alcohol polymer,
b. from 50% to 90% by weight of the blend of at least two different polyvinyl alcohol polymers of a second polyvinyl alcohol polymer consisting of vinyl alcohol monomer units and (optionally) vinyl acetate monomer units.

2. The film of claim 1 wherein the viscosity of the second polyvinyl alcohol polymer is in a range of about 3.0 to about 40.0 cP.

3. The film of claim 1 wherein the DH of the second polyvinyl alcohol polymer is in a range of about 60% to about 99%.

4. The film of claim 1 wherein the first polyvinyl alcohol polymer comprises maleic acid derived monomer unit in a range of about 3 mol % to about 5 mol %.

5. The film of claim 1 wherein the first polyvinyl alcohol polymer has a viscosity in a range of about 10 cP to about 30 cP.

6. The film of claim 1 wherein the blend of at least two different polyvinyl alcohol polymers has a blend viscosity in a range of about 10.0 to about 25.0 cP.

7. The film of claim 1 wherein the first polyvinyl alcohol polymer comprises a first viscosity (μ1) between about 10 cP to about 30 cP and the second polyvinyl alcohol polymer comprises a second viscosity (μ2) of about 40 cP or less.

8. The film of claim 7 wherein |μ2 −μ1| is in a range from about 0 cP to about 10 cP.

9. The film of claim 1 wherein the second polyvinyl alcohol polymer comprises at least two different polyvinyl alcohol homopolymers.

10. The film of claim 1 wherein the film comprises a thickness of about 50 to 80 μm.

11. The film of claim 1 wherein the film further comprises one or more components selected from the group consisting of plasticizers, plasticizer compatibilizers, lubricants, release agents, fillers, extenders, cross-linking agents, antiblocking agents, antioxidants, detackifying agents, antifoams, nanoparticles, bleaching agents, surfactants, and combinations thereof.

12. A packet made from one or more films of claim 1 .

13. A method of making a water soluble film according to claim 1 comprising the steps of:
a. admixing a blend of at least two different polyvinyl alcohol (PVOH) polymers in a solvent, the blend comprising:
i. from 10% to 50% by weight of the blend of at least two different polyvinyl alcohol polymers of a first polyvinyl alcohol polymer comprising at least two monomers, the first monomer comprising a maleic acid derived monomer unit, a second monomer comprising a vinyl alcohol monomer unit, and optionally third monomer comprising a vinyl acetate monomer unit, the amount of maleic acid derived monomer unit is between 3 mol % and 6 mol % of the first polyvinyl alcohol polymer; and
ii. from 50% to 90% by weight of the blend of at least two different polyvinyl alcohol polymers of a second polyvinyl alcohol polymer consisting of vinyl alcohol monomer units and (optionally) vinyl acetate monomer units to form a casting solution

b. metering the casting solution onto a surface,
c. allowing the casting solution to substantially dry to form a cast film, and
d. removing the resulting cast film from the casting surface.

14. The method of claim 13 where in the casting solution further comprises one or more components selected from the group consisting of plasticizers, plasticizer compatibilizers, lubricants, release agents, fillers, extenders, cross-linking agents, antiblocking agents, antioxidants, detackifying agents, antifoams, nanoparticles, bleaching agents, surfactants, and combinations thereof.

15. The film of claim 2 , wherein the viscosity of the second polyvinyl alcohol polymer is in the range of about 7.0 to about 35.0 cP.

16. The film of claim 2 , wherein the viscosity of the second polyvinyl alcohol polymer is in a range of about 10.0 to about 30.0 cP.

17. The film of claim 3 , wherein the DH of the second polyvinyl alcohol polymer is in a range of about 80% to about 98%.

18. The film of claim 17 , wherein the DH of the second polyvinyl alcohol polymer is in a range of about 83% to about 95%.

19. The film of claim 18 , wherein the DH of the second polyvinyl alcohol polymer is in a range of about 84% to about 90%.

20. The film of claim 19 , wherein the DH of the second polyvinyl alcohol polymer is in a range of about 85% to about 92%.

21. The film of claim 4 wherein the first polyvinyl alcohol polymer comprises maleic acid derived monomer unit in a range of about 3.5 mol. % to about 4.5 mol. %.

22. The film of claim 21 wherein the first polyvinyl alcohol polymer comprises maleic acid derived monomer unit in a range of about 4 mol. % to about 4.5 mol. %.

23. The film of claim 5 wherein the first polyvinyl alcohol polymer has a viscosity in a range of about 12 cP to about 25 cP.

24. The film of claim 23 wherein the first polyvinyl alcohol polymer has a viscosity in a range of about 14 cP to about 20 cP.

25. The film of claim 24 wherein the first polyvinyl alcohol polymer has a viscosity in a range of about 15 and about 20 cP.

26. The film of claim 25 wherein the first polyvinyl alcohol polymer has a viscosity in a range of about 15 and about 18 cP.

27. The film of claim 6 wherein the blend of at least two different polyvinyl alcohol polymers has a blend viscosity in a range of about 12.0 to about 20.0 cP.

28. The film of claim 27 wherein the blend of at least two different polyvinyl alcohol polymers has a blend viscosity in a range of about 13.0 to about 16.0 cP.

29. The film of claim 28 wherein the blend of at least two different polyvinyl alcohol polymers has a blend viscosity in a range of about 14.0 to about 15.5 cP.

30. The film of claim 8 wherein |μ2 −μ1| is in a range of about 0 cP to about 5 cP.

Assignees

• Monosol Llc

Inventors

• Friedrich Steven G
• Lee David M
• Nii Shinsuke

Classifications

• C08J5/18 Primary

  Manufacture of films or sheets · CPC title

• B65D65/46 Primary

  Applications of disintegrable, dissolvable or edible materials · CPC title

• C08L29/04 Primary

  Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids · CPC title

• C11D17/042

  Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions · CPC title

• C11D17/043

  Liquid or thixotropic (gel) compositions · CPC title