Resin composition for masterbatch

Patent metadata

Field	Value
Publication number	US-11767404-B2
Application number	US-201916962898-A
Country	US
Kind code	B2
Filing date	Mar 7, 2019
Priority date	Mar 7, 2018
Publication date	Sep 26, 2023
Grant date	Sep 26, 2023

Abstract

A masterbatch of a liquid additive is provided, the resin composition for the masterbatch comprising (a) a block copolymer or a hydrogenated product thereof, the block copolymer containing a polymer block having a vinyl aromatic compound as a main component and a polymer block having a conjugated diene compound as a main component, and 40 to 100 parts by mass of a polyolefinic resin and 100 to 150 parts by mass of an ethylene·α-olefin copolymer with respect to 100 parts by mass of the (a) component, wherein the kinematic viscosity at 100° C. is 10 to 5,000 mm 2 /s; the ethylene molar content is in the range of 30 to 85 mol %; and the molecular weight distribution (Mw/Mn) for the molecular weight measured by gel permeation chromatography (GPC) with reference to polystyrene is not more than 2.5.

First claim

The invention claimed is:

1. A molded article, comprising
any one resin of polyacetal resins, ABS resins, polyamide resins, thermoplastic polyester resins, polyimide resins and polycarbonate resins, and
0.5 to 10 parts by mass of a resin composition for a masterbatch with respect to 100 parts by mass of the one resin of polyacetal resins, ABS resins, thermoplastic polyester resins, polyimide resins and polycarbonate resins,
wherein the resin composition for a masterbatch comprises:
(a) a block copolymer or a hydrogenated product thereof, the block copolymer containing a polymer block having a structural unit derived from a vinyl aromatic compound as a main component and a polymer block having a structural unit derived from a conjugated diene compound as a main component; and
40 to 100 parts by mass of (b) a polyolefinic resin; and
100 to 150 parts by mass of (c) an ethylene·α-olefin copolymer having characteristics (c1) to (c3) described below, with respect to 100 parts by mass of the (a) component,
(c1) a kinematic viscosity at 100° C. is 10 to 5,000 mm 2 /s;
(c2) a content of a structural unit derived from ethylene is in the range of 30 to 85 mol %; and
(c3) a molecular weight distribution (Mw/Mn) for the molecular weight measured by gel permeation chromatography (GPC) with reference to polystyrene is not more than 2.5.

2. The molded article according to claim 1 , wherein the (a) component is a hydrogenated product of the block copolymer.

3. The molded article according to claim 1 , wherein the kinematic viscosity of the (c) ethylene·α-olefin copolymer at 100° C. is 500 to 3,000 mm 2 /s.

4. The molded article according to claim 1 , wherein the α-olefin of the (c) ethylene·α-olefin copolymer is propylene.

5. The molded article according to claim 1 , wherein the (b) polyolefinic resin is polypropylene.

6. The molded article according to claim 1 , wherein the conjugated diene compound is butadiene.

7. A resin composition, comprising:
any one resin of polyacetal resins, ABS resins, polyamide resins, thermoplastic polyester resins, polyimide resins and polycarbonate resins; and
0.2 to 3 parts by mass of (a) a block copolymer or a hydrogenated product thereof, the block copolymer containing a polymer block having a structural unit derived from a vinyl aromatic compound as a main component and a polymer block having a structural unit derived from a conjugated diene compound as a main component;
0.08 to 3 parts by mass of (b) a polyolefinic resin; and
0.2 to 4.5 parts by mass of (c) an ethylene·α-olefin copolymer having characteristics (c1) to (c3) described below above,
with respect to 100 parts by mass of the one resin of polyacetal resins, ABS resins, thermoplastic polyester resins, polyimide resins and polycarbonate resins,
(c1) a kinematic viscosity at 100° C. is 10 to 5,000 mm 2 s;
(c2) a content of a structural unit derived from ethylene is in the range of 30 to 85 mol %; and
(c3) a molecular weight distribution (Mw/Mn) for the molecular weight measured by gel permeation chromatography (GPC) with reference to polystyrene is not more than 2.5:

wherein a content of the (b) component is 40 to 100 parts by mass and a content of the (c) component is 100 to 150 parts by mass with respect to 100 parts by mass of the (a) component.

8. A molded article comprising the resin composition according to claim 7 .

Assignees

• Mitsui Chemicals Inc

Inventors

• Yoshida Yuto
• Abe Shota
• Takeshima Atsushi
• Suzuki Terufumi
• MATSUNAGA Kouzi

Classifications

• C08J3/22 Primary

  using masterbatch techniques · CPC title

• C08F8/04

  Reduction, e.g. hydrogenation · CPC title

• C08F212/08

  Styrene · CPC title

• C08F236/06

  Butadiene · CPC title

• C08J3/12

  Powdering or granulating · CPC title