Gel containing condensation product of reactive silicon compound

Patent metadata

Field	Value
Publication number	US-11767401-B2
Application number	US-201916973313-A
Country	US
Kind code	B2
Filing date	Jun 25, 2019
Priority date	Jun 27, 2018
Publication date	Sep 26, 2023
Grant date	Sep 26, 2023

Abstract

The present invention provides a gel containing a water-absorbing crosslinked polymer, and a condensate of a reactive silicon compound having at least one selected from the group consisting of an acidic dissociative group, an acidic dissociative group in a salt form, and a derivative group of an acidic dissociative group.

First claim

The invention claimed is:

1. A gel comprising a water-absorbing crosslinked polymer, and a condensate of a reactive silicon compound having at least one selected from the group consisting of an acidic dissociative group, an acidic dissociative group in a salt form, and a derivative group of an acidic dissociative group, wherein the condensate of the reactive silicon compound and the water-absorbing crosslinked polymer form an interpenetrating network.

2. The gel according to claim 1 , wherein the reactive silicon compound is a compound represented by the formula (I):

wherein R 1 is an alkyl group optionally having substituent(s), an aryl group optionally having substituent(s), a halogen atom, a hydroxy group, or an alkoxy group optionally having substituent(s),
R 2 and R 3 are each independently a halogen atom, a hydroxy group, or an alkoxy group optionally having substituent(s), and
R 4 is an organic group having at least one selected from the group consisting of an acidic dissociative group, an acidic dissociative group in a salt form, and a derivative group of an acidic dissociative group, the organic group is an alkyl group optionally having substituent(s) or a cycloalkyl-alkyl group optionally having substituent(s), and one or more carbon atoms (excluding carbon atom adjacent to silicon atom and carbon atom adjacent to nitrogen atom) of the alkyl group or the cycloalkyl-alkyl group is/are optionally substituted by a nitrogen atom.

3. The gel according to claim 2 , wherein R 4 is an organic group having at least one selected from the group consisting of a carboxy group, a carboxy group in a salt form, an alkoxycarbonyl group optionally having substituent(s), a carbonyloxycarbonyl group, and a carbonyliminocarbonyl group optionally having substituent(s).

4. The gel according to claim 1 , wherein the water-absorbing crosslinked polymer has at least one selected from the group consisting of an acidic dissociative group, an acidic dissociative group in a salt form, and a derivative group of an acidic dissociative group.

5. The gel according to claim 1 , wherein the water-absorbing crosslinked polymer has at least one selected from the group consisting of a carboxy group, a carboxy group in a salt form and an alkoxycarbonyl group.

6. An acidic gas separation membrane comprising a gel comprising a water-absorbing crosslinked polymer, and a condensate of a reactive silicon compound having at least one selected from the group consisting of an acidic dissociative group, an acidic dissociative group in a salt form, and a derivative group of an acidic dissociative group.

7. An acidic gas separation apparatus comprising the acidic gas separation membrane according to claim 6 .

8. A method for separating at least one acidic gas, comprising contacting a mixed gas comprising the acidic gas and at least one nonacidic gas with the acidic gas separation membrane according to claim 6 .

9. A method for producing a gel comprising a water-absorbing crosslinked polymer, and a condensate of a reactive silicon compound having at least one selected from the group consisting of an acidic dissociative group, an acidic dissociative group in a salt form, and a derivative group of an acidic dissociative group, the method comprising forming a second condensate of a reactive silicon compound having at least one selected from the group consisting of an acidic dissociative group, an acidic dissociative group in a salt form, and a derivative group of an acidic dissociative group by drying and heating a mixture comprising
at least one selected from the group consisting of a reactive silicon compound having at least one selected from the group consisting of an acidic dissociative group, an acidic dissociative group in a salt form, and a derivative group of an acidic dissociative group, and a first condensate of a reactive silicon compound having at least one selected from the group consisting of an acidic dissociative group, an acidic dissociative group in a salt form, and a derivative group of an acidic dissociative group,
a water-absorbing crosslinked polymer, and
water.

10. The method according to claim 9 , wherein the reactive silicon compound is a compound represented by the formula (I):

wherein R 1 is an alkyl group optionally having substituent(s), an aryl group optionally having substituent(s), a halogen atom, a hydroxy group, or an alkoxy group optionally having substituent(s),
R 2 and R 3 are each independently a halogen atom, a hydroxy group, or an alkoxy group optionally having substituent(s), and
R 4 is an organic group having at least one selected from the group consisting of an acidic dissociative group, an acidic dissociative group in a salt form, and a derivative group of an acidic dissociative group, the organic group is an alkyl group optionally having substituent(s) or a cycloalkyl-alkyl group optionally having substituent(s), and one or more carbon atoms (excluding carbon atom adjacent to silicon atom and carbon atom adjacent to nitrogen atom) of the alkyl group or the cycloalkyl-alkyl group is/are optionally substituted by a nitrogen atom.

11. The method according to claim 10 , wherein R 4 is an organic group having at least one selected from the group consisting of a carboxy group, a carboxy group in a salt form, an alkoxycarbonyl group optionally having substituent(s), a carbonyloxycarbonyl group, and a carbonyliminocarbonyl group optionally having substituent(s).

12. The method according to claim 9 , wherein the water-absorbing crosslinked polymer has at least one selected from the group consisting of an acidic dissociative group, an acidic dissociative group in a salt form, and a derivative group of an acidic dissociative group.

13. The method according to claim 9 , wherein the water-absorbing crosslinked polymer has at least one selected from the group consisting of a carboxy group, a carboxy group in a salt form and an alkoxycarbonyl group.

14. The method according to claim 9 , wherein the condensate of the reactive silicon compound and the water-absorbing crosslinked polymer form an interpenetrating network.

15. The acidic gas separation membrane according to claim 6 , wherein the reactive silicon compound is a compound represented by the formula (I):

wherein R 1 is an alkyl group optionally having substituent(s), an aryl group optionally having substituent(s), a halogen atom, a hydroxy group, or an alkoxy group optionally having substituent(s),
R 2 and R 3 are each independently a halogen atom, a hydroxy group, or an alkoxy group optionally having substituent(s), and
R 4 is an organic group having at least one selected from the group consisting of an acidic dissociative group, an acidic dissociative group in a salt form, and a derivative group of an acidic dissociative group, the organic group is an alkyl group optionally having substituent(s) or a cycloalkyl-alkyl group optionally having substituent(s), and one or more carbon atoms (excluding carbon atom adjacent to silicon atom and carbon atom adjacent to nitrogen atom) of the alkyl group or the cycloalkyl-alkyl group is/are optionally substituted by a nitrogen atom.

16. The acidic gas separation membrane according to claim 15 , wherein R 4 is an organic group having at least one selected from the group cons

Assignees

• Sumitomo Chemical Co

Inventors

• Kashiwabara Taigo
• Ogawa Ayumi
• Kamikawa Takashi

Classifications

• B01D71/70 Primary

  Polymers having silicon in the main chain, with or without sulfur, nitrogen, oxygen or carbon only · CPC title

• C08G77/445 Primary

  containing polyester sequences · CPC title

• B01D53/228

  characterised by specific membranes · CPC title

• C07F7/1804

  Compounds having Si-O-C linkages (Si-O-acyl linkages C07F7/1896) · CPC title

• C08J3/075

  Macromolecular gels · CPC title