Use of carbon nanomaterials produced with low carbon footprint to produce composites with low CO2 emission

Patent metadata

Field	Value
Publication number	US-11767261-B2
Application number	US-202217874907-A
Country	US
Kind code	B2
Filing date	Jul 27, 2022
Priority date	Oct 29, 2018
Publication date	Sep 26, 2023
Grant date	Sep 26, 2023

Abstract

A low carbon footprint material is used to decrease the carbon dioxide emission for production of a high carbon footprint substance. A method of forming composite materials comprises providing a first high carbon footprint substance; providing a carbon nanomaterial produced with a carbon-footprint of less than 10 unit weight of carbon dioxide (CO 2 ) emission during production of 1 unit weight of the carbon nanomaterial; and forming a composite comprising the high carbon footprint substance and from 0.001 wt % to 25 wt % of the carbon nanomaterial, wherein the carbon nanomaterial is homogeneously dispersed in the composite to reduce the carbon dioxide emission for producing the composite material relative to the high carbon footprint substance.

First claim

What is claimed is:

1. A method of forming a composite material, comprising steps of:
providing a high carbon footprint substance that is a metal;
providing a carbon nanomaterial produced with a negative carbon-footprint indicating a net consumption of carbon dioxide during the production of the carbon nanomaterial; and
forming a composite comprising the high carbon footprint substance and from 0.001 wt % to 25 wt % of the carbon nanomaterial by one of:
a. heating the high carbon footprint substance and adding the carbon nanomaterial thereto;
b. coating one or more individual particles of the carbon nanomaterial with a second metal and adding the coated carbon nanomaterial to the high carbon footprint material for providing an interface between the coated carbon nanomaterial and the metal;
c. mixing a powder of the metal and a powder of the carbon nanomaterial and sintering the powder mixture; and
d. making a suspension of the carbon nanomaterial in a solvent and mixing the suspension with a powder of the metal, treating the mixture of the suspension and the metal powder to form a powder mixture of the carbon nanomaterial and the metal,
wherein the carbon nanomaterial is dispersed in the composite material to reduce the carbon dioxide emission for producing the composite material relative to the high carbon footprint substance.

2. The method of claim 1 , wherein the carbon nanomaterial comprises carbon nanofibers with an average aspect ratio of 10 to 1000 and a thickness of 3 nm to 999 nm.

3. The method of claim 2 , wherein the nanofibers comprise one or more of carbon nanotubes, helical carbon nanotubes, untangled carbon nanofibers, carbon nano-onions, a carbon nano-scaffold, a nano-platelet, and graphene.

4. The method of claim 1 , wherein the carbon nanomaterial is formed from a molten carbonate by electrolysis.

5. The method of claim 4 , wherein the molten carbonate is generated by a reaction of carbon dioxide and a metal oxide in a molten electrolyte.

6. The method of claim 5 , wherein the metal oxide is lithium oxide.

7. The method of claim 4 , wherein the molten carbonate comprises a lithium carbonate or a lithiated carbonate.

8. The method of claim 1 , wherein the metal is aluminum or alloy thereof and the step of forming the composite comprises heating the aluminum to a molten state and adding the carbon nanomaterial thereto.

9. The method of claim 1 , wherein the metal is magnesium or alloy thereof and the step of forming the composite comprises coating one or more individual particles of the carbon nanomaterial with a second metal and adding the coated carbon nanomaterial to a magnesium powder for providing an interface between the coated carbon nanomaterial and the magnesium.

10. The method of claim 9 , wherein the second metal is a transition metal.

11. The method of claim 10 , wherein the second metal is nickel or alloy thereof.

12. The method of claim 1 , wherein the step of forming the composite comprises mixing a powder of the metal and a powder of the carbon nanomaterial and sintering the powder mixture.

13. The method of claim 12 , wherein the metal is one of titanium, steel, a titanium alloy or a steel alloy.

14. The method of claim 12 , wherein the step of forming the composite comprises a step of milling the powder mixture before the step of sintering.

15. The method of claim 12 , wherein the step of sintering is spark plasma sintering.

16. The method of claim 1 , wherein the metal is copper or an alloy thereof and the step of forming the composite further comprises:
a. making a suspension of the carbon nanomaterial in an aqueous solvent;
b. mixing the suspension with a powder of the metal;
c. treating the mixture of the suspension and the metal powder to produce a powder mixture of the carbon nanomaterial and the metal; and
d. sintering the powder mixture, wherein the carbon nanomaterial is dispersed within the powder mixture.

17. The method of claim 16 , wherein the step of treating the mixture of the suspension and the metal powder comprises a step of calcinating, a step of reducing, or both.

18. The method of claim 16 , wherein the step of sintering is spark plasma sintering or microwave sintering.

19. The method of claim 1 , wherein the composite material has an enhanced mechanical strength property as compared to the metal.

Assignees

• C2Cnt Llc

Inventors

• Licht Stuart
• Licht Gad

Classifications

• C22C1/1047

  by mixing and casting liquid metal matrix composites · CPC title

• C01B32/18 Primary

  Nanoonions; Nanoscrolls; Nanohorns; Nanocones; Nanowalls · CPC title

• B22F1/18 Primary

  Non-metallic particles coated with metal · CPC title

• C01B32/184

  Preparation · CPC title

• C01B32/15 Primary

  Nano-sized carbon materials · CPC title