Filter and metal ion removal device

Patent metadata

Field	Value
Publication number	US-11767239-B2
Application number	US-201917053479-A
Country	US
Kind code	B2
Filing date	May 29, 2019
Priority date	May 31, 2018
Publication date	Sep 26, 2023
Grant date	Sep 26, 2023

Abstract

To provide a filter capable of efficiently removing metal ions in a treatment liquid, and capable of easily obtaining a solution having an extremely low metal ion content. A depth filter includes a porous molded article. The porous molded article is a sintered material of mixed powder or a swollen material of the sintered material. The mixed powder contains dried gel powder and thermoplastic resin powder. The dried gel powder contains an ion exchange resin including a sulfonic acid group, and a nitrogen-containing chelating resin.

First claim

The invention claimed is:

1. A metal ion removal device comprising:
a first filter configured such that, when water having a specific electrical resistance value of 18 MΩ·cm or greater is caused to pass through the first filter at a space velocity of 1200 hr −1 , a specific electrical resistance value of the water after being caused to pass through the first filter is less than 15 MΩ·cm; and
a second filter configured to remove metal ions from a treatment liquid that has passed through the first filter, wherein
the first filter is a filter including a porous molded article, the porous molded article being a sintered material of mixed powder or a swollen material of the sintered material, the mixed powder containing dried gel powder including a nitrogen-containing chelating resin, and thermoplastic resin powder, and
the second filter comprising a porous molded article being a sintered material of mixed powder or a swollen material of the sintered material, the mixed powder containing dried gel powder and thermoplastic resin powder, wherein
the dried gel powder contains an ion exchange resin including a sulfonic acid group, and a nitrogen-containing chelating resin; and
a ratio (C 1 /C 2 ) of a content C 1 of the ion exchange resin to a content C 2 of the nitrogen-containing chelating resin is 0.1 or higher and 100 or lower in a mass ratio.

2. A depth filter comprising
a porous molded article being a sintered material of mixed powder or a swollen material of the sintered material, the mixed powder containing dried gel powder including an ion exchange resin, and thermoplastic resin powder, wherein
an average particle diameter of the dried gel powder is two or more times as large as an average particle diameter of the thermoplastic resin powder, and
when each of a surface of the porous molded article and a cross-sectional surface dividing the porous molded article into two in a thickness direction is observed with a scanning electron microscope in a range of a field of view of 950 μm×950 μm and subsequently an average projected area of five particles having large projected areas of the dried gel powder is calculated in each field of view,
the average projected area on the surface is smaller than the average projected area on the cross-sectional surface.

3. A metal ion removal device comprising:
a first filter; and
a second filter configured to remove metal ions from a treatment liquid that has passed through the first filter, wherein
the first filter is a filter including a porous molded article, the porous molded article being a sintered material of mixed powder or a swollen material of the sintered material, the mixed powder containing dried gel powder including a nitrogen-containing chelating resin, and thermoplastic resin powder, and
the second filter comprising
a porous molded article being a sintered material of mixed powder or a swollen material of the sintered material, the mixed powder containing dried gel powder including an ion exchange resin, and thermoplastic resin powder, wherein
the ion exchange resin is an ion exchange resin including a sulfonic acid group, and the dried gel powder further includes a nitrogen-containing chelating resin,
a ratio (C 1 /C 2 ) of a content C 1 of the ion exchange resin to a content C 2 of the nitrogen-containing chelating resin is 0.1 or more and 100 or less in a mass ratio,
a number of particles of powder P 1 contained on a surface per unit area is smaller than a number of particles of powder P 2 contained on a cross-sectional surface per unit area, the surface being a surface of the porous molded article, the cross-sectional surface being a surface dividing the porous molded article into two in a thickness direction, where, among particles of the dried gel powder, P 1 denotes a particle of powder having a projected area 10 or more times as large as an average projected area of a particle of the thermoplastic resin powder, the projected area of the particle of the powder P 1 being an area on the surface, and P 2 denotes a particle of powder having a projected area 10 or more times as large as an average projected area of a particle of the thermoplastic resin powder, the projected area of the particle of the powder P 2 being an area on the cross-sectional surface, and
the first filter is a filter configured such that, when water having a specific electrical resistance value of 18 MΩ·cm or greater is caused to pass through the first filter at a space velocity of 1200 1 hr −1 , a specific electrical resistance value of the water after being caused to pass through the first filter is less than 15 MΩ·cm.

Assignees

• 3M Innovative Properties Company

Inventors

• Kobayashi Mitsuaki
• Okada Hideyuki
• Okada Yukihisa
• Shirai Takaaki

Classifications

• C02F1/42 Primary

  by ion-exchange (ion-exchange in general B01J) · CPC title

• B01D39/16 Primary

  of organic material, e.g. synthetic fibres · CPC title

• B01D39/1661

  sintered or bonded · CPC title

• B01J39/05

  in the strongly acidic form · CPC title

• B01J45/00

  Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties (ion-exchange chromatography processes B01D15/36) · CPC title