Cathode, lithium-air battery comprising the same, and method of preparing the cathode
US-2021242469-A1 · Aug 5, 2021 · US
US11764364B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11764364-B2 |
| Application number | US-202117153271-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 20, 2021 |
| Priority date | Feb 4, 2020 |
| Publication date | Sep 19, 2023 |
| Grant date | Sep 19, 2023 |
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A cathode configured to use oxygen as a cathode active material includes: a porous film including a metal oxide, where a porosity of the porous film is about 50 volume percent to about 95 volume percent, based on a total volume of the porous film, and an amount of an organic component in the porous film is 0 to about 2 weight percent, based on a total weight of the porous film.
Opening claim text (preview).
What is claimed is: 1. A cathode configured to use oxygen as a cathode active material, the cathode comprising: a porous film comprising a metal oxide, wherein a porosity of the porous film is about 50 volume percent to about 95 volume percent, based on a total volume of the porous film, and an amount of an organic component in the porous film is 0 weight percent to about 2 weight percent, based on a total weight of the porous film, wherein a loading level of the porous film is about 4 milligrams per square centimeter to about 10 milligrams per square centimeter, and wherein the porous film is a self-standing film. 2. The cathode of claim 1 , wherein the metal oxide comprises a lithium-containing metal oxide. 3. The cathode of claim 1 , wherein the porous film is an inorganic film. 4. The cathode of claim 1 , wherein a size of pores included in the porous film is from about 1 nanometer to about 1 micrometer. 5. The cathode of claim 2 , wherein the lithium-containing metal oxide is a crystalline lithium ion conductor. 6. The cathode of claim 2 , wherein the lithium-containing metal oxide is a crystalline electronic conductor. 7. The cathode of claim 2 , wherein the lithium-containing metal oxide is a mixed conductor. 8. The cathode of claim 2 , wherein the lithium-containing metal oxide comprises at least one of a perovskite compound or a spinel compound. 9. The cathode of claim 2 , wherein the lithium-containing metal oxide comprises a perovskite compound represented by Formula 1: Li x A y G z O 3−δ Formula 1 wherein, in Formula 1, A and G are each independently at least one of a Group 2 to a Group 16 element, and 0<x<1, 0<y<1, 0<x+y≤1, 0<z≤1.5, is an oxygen vacancy content, and 0≤ ≤1.5. 10. The cathode of claim 9 , wherein A is at least one of H, Na, K, Rb, Cs, Ca, Sr, Ba, Y, La, Ce, Pr, Nd, Pm, Sm, Gd, Tb, Dy, Ho, or Er, G is at least one of Ti, Pd, Pb, Fe, Ir, Co, Rh, Mn, Cr, Ru, Re, Sn, V, Ge, W, Zr, Ti, Mo, Hf, U, Nb, Th, Ta, Bi, Ca, Sr, Ba, Y, La, Ce, Pr, Nd, Pm, Sm, Gd, Tb, Dy, Ho, Er, Mg, Al, Si, Sc, Zn, Ga, Rb, Ag, Cd, In, Sb, Pt, Au, or Pb, and 0.2<x≤0.7, 0<y≤0.7, 0<x+y<1, 0<z≤1.2, and 0≤ ≤1.2. 11. The cathode of claim 9 , wherein A is at least one of La, Ce, Pr, Gd, Ca, Sr, or Ba, M is at least one of Ti, Mn, Ni, Ru, Cr, Co, Ir, Fe, Pd, Pb, Rh, Sn, V, Re, Ge, W, Zr, Mo, Nb, Ta, Hf, or Bi, and 0.2<x≤0.5, 0.4<y≤0.7, 0<x+y<1, 0.8<z≤1.2, and 0≤ ≤1.0. 12. The cathode of claim 9 , wherein the perovskite compound comprises at least one of Li 0.34 La 0.55 TiO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 MnO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 NiO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 CrO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 CoO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 IrO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 RuO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 FeO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 PdO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 PbO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 RhO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 SnO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 VO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 ReO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 GeO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 WO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 ZrO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 MoO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 NbO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 TaO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 HfO 3−δ (0≤ ≤1.0), Li 0.34 La 0.55 BiO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 TiO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 MnO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 NiO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 CrO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 CoO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 IrO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 RuO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 FeO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 PdO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 PbO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 RhO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 SnO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 VO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 ReO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 GeO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 WO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 ZrO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 MoO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 NbO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 TaO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 HfO 3−δ (0≤ ≤1.0), Li 0.10 La 0.63 BiO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 TiO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 MnO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 NiO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 CrO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 CoO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 IrO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 RuO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 FeO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 PdO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 PbO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 RhO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 SnO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 VO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 ReO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 GeO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 WO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 ZrO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 MoO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 NbO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 TaO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 HfO 3−δ (0≤ ≤1.0), Li 0.20 La 0.60 BiO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 TiO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 MnO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 NiO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 CrO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 CoO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 IrO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 RuO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 FeO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 PdO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 PbO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 RhO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 SnO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 VO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 ReO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 GeO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 WO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 ZrO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 MoO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 NbO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 TaO 3−δ (0≤ ≤1.0), Li 0.30 La 0.57 HfO 3−δ (0≤δ≤1.0), Li 0.30 La 0.57 BiO 3−δ (0≤δ≤1.0), Li 0.40 La 0.53 TiO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 MnO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 NiO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 CrO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 CoO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 IrO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 RuO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 FeO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 PdO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 PbO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 RhO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 SnO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 VO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 ReO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 GeO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 WO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 ZrO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 MoO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 NbO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 TaO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 HfO 3−δ (0≤ ≤1.0), Li 0.40 La 0.53 BiO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 TiO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 MnO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 NiO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 CrO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 CoO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 IrO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 RuO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 FeO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 PdO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 PbO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 RhO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 SnO 3−δ (0≤ ≤1.0), Li 0.45 La0.52VO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 ReO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 GeO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 WO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 ZrO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 MoO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 NbO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 TaO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 HfO 3−δ (0≤ ≤1.0), Li 0.45 La 0.52 BiO 3−δ (0≤ ≤1.0), Li 0.34 Ce 0.55 TiO 3−δ (0≤ ≤1.0), Li 0.34 Ce 0.55 MnO 3−δ (0≤ ≤1.0), Li 0.34 Ce 0.55 NiO 3−δ (0≤δ≤1.0), Li 0.34 Ce 0.55 CrO 3−δ (0≤ ≤1.0), Li 0.34 Ce 0.55 CoO 3−δ (0≤ ≤1.0), Li 0.34 Ce 0.55 IrO 3−δ (0≤ ≤1.0), Li 0.34 Ce 0.55 RuO 3−δ (0≤ ≤1.0), Li 0.34 Ce 0.55 FeO 3−δ (0≤ ≤1.0), Li 0.34 Ce 0.55 PdO 3−δ (0≤ ≤1.0), Li 0.34 Ce 0.55 PbO 3−δ (0≤ ≤1.0), Li 0.34 Ce 0.55 RhO 3−δ (0≤ ≤1.0), Li 0.34 Ce 0.55 SnO 3−δ (0≤ ≤1.0), Li 0.34 Ce 0.55 VO 3−δ (0≤ ≤1.0), Li 0.
Gradient in composition · CPC title
Porous electrodes · CPC title
containing only metallic or ceramic material, e.g. made by sintering or sputtering · CPC title
consisting of more than one material, e.g. consisting of composites · CPC title
Coating with slurry or ink · CPC title
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