Evaluating changes in bonding interactions between inclusions and a thermoplastic matrix

Patent metadata

Field	Value
Publication number	US-11761869-B2
Application number	US-202117169080-A
Country	US
Kind code	B2
Filing date	Feb 5, 2021
Priority date	Feb 7, 2020
Publication date	Sep 19, 2023
Grant date	Sep 19, 2023

Abstract

Assessing an interaction between solid particles and a thermoplastic material in which the solid particles are dispersed includes combining a thermoplastic material with a multiplicity of solid particles to yield a heterogeneous mixture, processing the heterogeneous mixture to yield an unconditioned sample, conditioning the unconditioned sample to yield a conditioned sample, subjecting the conditioned sample to a ramping shear rate from an initial shear rate to a final shear rate, assessing a viscosity of the conditioned sample at a plurality of shear rates between the initial shear rate and the final shear rate, and assessing a value of a slope of a shear-thinning region for the unconditioned sample using a power-law equation.

First claim

What is claimed is:

1. A method of assessing an interaction between solid particles and a thermoplastic material in which the solid particles are dispersed, the method comprising:
combining a thermoplastic material with a multiplicity of solid particles to yield a heterogeneous mixture;
processing the heterogeneous mixture to yield an unconditioned sample, wherein processing the heterogeneous mixture comprises one or both of:
heating the heterogeneous mixture, and
molding the heterogeneous mixture into a selected shape and size;

conditioning the unconditioned sample to yield a conditioned sample, wherein conditioning the unconditioned sample comprises one or more of:
aging the unconditioned sample,
subjecting the unconditioned sample to a freeze-thaw cycle, and
exposing the unconditioned sample to a liquid;

subjecting the conditioned sample to a ramping shear rate from an initial shear rate to a final shear rate;
assessing a viscosity of the conditioned sample at a plurality of shear rates between the initial shear rate and the final shear rate;
assessing a value of a slope of a shear-thinning region for the unconditioned sample using a power-law equation; and
assessing an effect on a bond strength between the solid particles and the thermoplastic material based on the value of the slope.

2. The method of claim 1 , further comprising:
subjecting the unconditioned sample to a ramping shear rate from the initial shear rate to the final shear rate;
assessing a viscosity of the unconditioned sample at a plurality of shear rates between the initial shear rate and the final shear rate; and
assessing a value of a slope of a shear-thinning region for the conditioned sample using a power-law equation.

3. The method of claim 2 , further comprising assessing a difference between the value of the slope of the shear-thinning region for the unconditioned sample and the value of the slope of the shear-thinning region for the conditioned sample.

4. The method of claim 3 , further comprising identifying, for a non-zero difference, a susceptibility of thermoplastic material to the conditioning, wherein the susceptibility corresponds to a change in bond strength between the solid particles and the thermoplastic material.

5. The method of claim 1 , wherein processing the heterogeneous mixture comprises heating the heterogeneous mixture.

6. The method of claim 1 , wherein conditioning the unconditioned sample comprises aging the unconditioned sample.

7. The method of claim 1 , wherein conditioning the unconditioned sample comprises subjecting the unconditioned sample to a freeze-thaw cycle.

8. The method of claim 1 , wherein conditioning the unconditioned sample comprises exposing the unconditioned sample to a liquid.

9. The method of claim 8 , wherein conditioning the unconditioned sample comprises exposing the unconditioned sample to the liquid for a length of time between 2 hours and 48 hours.

10. The method of claim 8 , wherein the liquid comprises an aqueous solution, a solvent, or an oil.

11. The method of claim 10 , wherein the liquid comprises the aqueous solution, and the aqueous solution is acidic.

12. The method of claim 11 , wherein a pH of the aqueous solution is less than 5.

13. The method of claim 10 , wherein the liquid comprises the aqueous solution, and the aqueous solution comprises one or more of salt, carbon dioxide, sulfur dioxide, and nitrogen oxide.

14. The method of claim 1 , further comprising adjusting the viscosity of the conditioned sample to an initial viscosity before assessing the viscosity of the conditioned sample at the plurality of shear rates.

15. The method of claim 14 , wherein adjusting the viscosity of the conditioned sample comprises heating the conditioned sample.

16. The method of claim 14 , wherein the initial viscosity is about 1000 Pa·s.

17. The method of claim 1 , wherein the thermoplastic matrix comprises bitumen.

18. The method of claim 1 , wherein the solid particles comprise glass beads.

19. The method of claim 1 , wherein combining the thermoplastic material with the multiplicity of solid particles comprises forming a composite comprising the multiplicity of solid particles dispersed in a matrix of the thermoplastic material.

20. The method of claim 1 , wherein processing the heterogeneous mixture to yield an unconditioned sample comprises molding the heterogeneous mixture into a selected shape and size.

Assignees

• Fini Elham
• Oldham Daniel
• Univ Arizona State

Inventors

• Fini Elham
• Oldham Daniel

Classifications

• G01N13/00 Primary

  Investigating surface or boundary effects, e.g. wetting power; Investigating diffusion effects; Analysing materials by determining surface, boundary, or diffusion effects (scanning-probe techniques or apparatus G01Q) · CPC title

• G01N11/00 Primary

  Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties · CPC title