Configuration for olefins and aromatics production

Patent metadata

Field	Value
Publication number	US-11760947-B2
Application number	US-202217812803-A
Country	US
Kind code	B2
Filing date	Jul 15, 2022
Priority date	Mar 15, 2019
Publication date	Sep 19, 2023
Grant date	Sep 19, 2023

Abstract

Processes herein may be used to thermally crack various hydrocarbon feeds, and may eliminate the refinery altogether while making the crude to chemicals process very flexible in terms of crude. In embodiments herein, crude is progressively separated into at least light and heavy fractions. Depending on the quality of the light and heavy fractions, these are routed to one of three upgrading operations, including a fixed bed hydroconversion unit, a fluidized catalytic conversion unit, or a residue hydrocracking unit that may utilize an ebullated bed reactor. Products from the upgrading operations may be used as feed to a steam cracker.

First claim

We claim:

1. A process for converting whole crudes and other wide boiling hydrocarbon streams to produce olefins and/or aromatics, the process comprising:
separating a whole crude into at least a light boiling fraction, a medium boiling fraction, and a high boiling residue fraction;
hydrocracking the high boiling residue fraction to form a hydrocracked effluent, and separating the hydrocracked effluent to produce a resid hydrocracked fraction and a fuel oil fraction;
destructively hydrogenating and hydrocracking the medium boiling fraction and the resid hydrocracked fraction to produce a hydrotreated and hydrocracked effluent;
feeding the hydrotreated and hydrocracked effluent and the light boiling fraction to at least one of a steam cracker and an aromatics complex to convert hydrocarbons therein into petrochemicals and a pyrolysis oil and/or an ultra-low sulfur fuel oil (ULSFO).

2. The process of claim 1 , wherein the light boiling fraction has two or more of the following properties:
a 95% boiling point temperature in the range from about 130° C. to about 200° C.;
a hydrogen content of at least 14 wt %;
a BMCI of less than 5;
an API gravity of greater than 40°;
a sulfur content of less than 1000 ppm;
a nitrogen content of less than 10 ppm;
a viscosity, measured at 40° C., of less than 1 cSt;
less than 1 wt % MCRT; and
less than 1 ppm total metals.

3. The process of claim 1 , wherein the medium boiling fraction has two or more of the following properties:
a 5% boiling point temperature in the range from about 130° C. to about 200° C.;
a 95% boiling point temperature in the range from about 400° C. to about 600° C.;
a hydrogen content in the range from about 12 wt % to about 14 wt %;
a BMCI in the range from about 5 to less than 50;
an API gravity of in the range from about 10° to about 40°;
a sulfur content in the range from about 1000 ppm to about 10000 ppm;
a nitrogen content in the range from about 1 ppm to about 100 ppm;
a viscosity, measured at 40° C., of greater than 1 cSt;
less than 5 wt % MCRT; and
less than 50 ppm total metals.

4. The process of claim 1 , wherein the heavy boiling fraction has two or more of the following properties:
a 5% boiling point temperature in the range from about 400° C. to about 600° C.;
a hydrogen content of less than 12 wt %;
a BMCI of greater than 50;
an API gravity of less than 10°;
a sulfur content of greater than 10000 ppm;
a nitrogen content of greater than 100 ppm;
a viscosity, measured at 100° C., of greater than 100 cSt;
greater than 5 wt % MCRT; and
greater than 50 ppm total metals.

5. The process of claim 1 , wherein the resid hydrocracked fraction has a 95% boiling point temperature in the range from about 400° C. to about 560° C.

6. The process of claim 1 , wherein the high boiling residue fraction has a 5% boiling point temperature of greater than about 545° C.

7. The process of claim 1 , wherein the hydrocracking the high boiling residue fraction comprises contacting the high boiling residue fraction and the pyrolysis oil with an extrudate or slurry catalyst at conditions sufficient to convert at least a portion of the high boiling residue fraction hydrocarbons to lighter hydrocarbons.

8. The process of claim 1 , wherein hydrocracking the high boiling residue fraction comprises converting in excess of 70% of the hydrocarbons having a boiling point of greater than 565° C.

9. The process of claim 1 , wherein the destructively hydrogenating and hydrocracking the medium boiling fraction and the resid hydrocracked fraction comprises destructive hydrogenation the medium boiling fraction and the resid hydrocracked fraction in a common destructive hydrogenation unit, and hydrocracking an effluent from the common destructive hydrogenation unit in a hydrocracking unit.

10. The process of claim 1 , wherein the destructively hydrogenating and hydrocracking the medium boiling fraction and the resid hydrocracked fraction comprises:
destructively hydrogenating the medium boiling fraction in a first destructive hydrogenation unit;
destructively hydrogenating the resid hydrocracked fraction in a second destructive hydrogenation unit; and
combining the effluents from the first and second destructive hydrogenation units and hydrocracking the combined effluents in a hydrocracking unit.

11. The process of claim 10 , further comprising destructive hydrogenating the resid hydrocracked fraction in the first destructive hydrogenation unit during a time period when catalyst is being replaced in the second destructive hydrogenation unit.

12. The process of claim 1 , further comprising hydrodesulfurizing the fuel oil fraction to produce an ultra-low sulfur fuel oil.

13. The process of claim 1 , wherein an overall petrochemicals production is at least 65 wt %, based on a total amount of olefins and aromatics produced as compared to a total feedstock feed rate, inclusive of the whole crude and any additional feeds.

14. The process of claim 1 , wherein feeding the hydrotreated and hydrocracked effluent and the light boiling fraction to at least one of a steam cracker and an aromatics complex comprises:
separating the hydrotreated and hydrocracked effluent and the light boiling fraction to a separator to produce a light naphtha fraction and a heavy naphtha fraction;
feeding the light naphtha fraction to the steam cracker unit; and
feeding the heavy naphtha fraction to the aromatics complex.

15. The process of claim 1 , comprising feeding the hydrotreated and hydrocracked effluent and the light boiling fraction directly to the steam cracker.

16. A process for converting whole crudes and other wide boiling hydrocarbon streams to produce olefins and/or aromatics, the process comprising:
separating a whole crude into at least a light boiling fraction, a medium boiling fraction, and a high boiling residue fraction;
hydrocracking the high boiling residue fraction and a heavy fraction to form a hydrocracked effluent, and separating the hydrocracked effluent to produce a resid hydrocracked fraction and a fuel oil fraction;
destructively hydrogenating and hydrocracking the medium boiling fraction and the resid hydrocracked fraction to produce a hydrotreated and hydrocracked effluent;
separating the hydrotreated and hydrocracked effluent to produce a light fraction and the heavy fraction;
feeding the light fraction and the light boiling fraction to a separator to recover a light naphtha fraction and a heavy naphtha fraction;
feeding the light naphtha fraction to a steam cracker to convert the light naphtha fraction into petrochemicals including ethylene, propylene, and butenes; and
feeding the heavy naphtha fraction to an aromatics complex to convert hydrocarbons therein into petrochemicals including benzene, toluene, and xylenes.

17. The process of claim 16 , further comprising mixing a slurry oil with the high boiling residue fraction prior to hydrocracking the high boiling residue fraction.

18. The process of claim 16 , further comprising mixing a light cycle oil with the medium boiling fraction prior to the destructively hydrogenating and hydrocracking the medium boiling fraction.

19. A process for converting whole crudes and other wide boiling hydrocarbon streams to produce olefins and/or aromatics, the process comprising:
separating a whole crude in a first separation device into a light boiling fraction and a remainder fraction;
separating the reminder fraction in a second separation device into a medium boiling fraction and a high boiling residue fr

Assignees

• Lummus Technology Inc
• Saudi Aramco Tech Co
• Chevron Lummus Global Llc

Inventors

• Shaik Kareemuddin
• Mukherjee Ujjal
• Al-Sayed Essam Abdullah
• Santos Pedro
• Maesen Theodorus
• Tamimi Mazin
• Chabot Julie
• Abba Ibrahim
• Sundaram Kandasamy
• Barnawi Sami
• Venner Ronald M

Classifications

• C10G47/00

  Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions (C10G15/00 takes precedence; destructive hydrogenation of non-melting solid carbonaceous or similar materials C10G1/06) · CPC title

• C10G45/00

  Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds · CPC title

• C10G69/14

  plural parallel stages only · CPC title

• C10G9/36 Primary

  with heated gases or vapours · CPC title

• C10G9/16

  Preventing or removing incrustation · CPC title