Preparation and application of cube-like ZnSnO3 composite coated with highly graphitized fine ash

Patent metadata

Field	Value
Publication number	US-11760883-B2
Application number	US-202117341423-A
Country	US
Kind code	B2
Filing date	Jun 8, 2021
Priority date	Oct 15, 2020
Publication date	Sep 19, 2023
Grant date	Sep 19, 2023

Abstract

A preparation method of a cube-like ZnSnO 3 composite coated with highly graphitized fine ash comprises steps: S1: with the gasified fine slag of pulverized coal as a raw material, preparing the fine ash by adopting a three-step acidification method; and S2: adding the fine ash prepared in the S1 into a container filled with distilled water, ultrasonically dispersing for 20-40 min, adding equal molar masses of SnCl 4 ·5H 2 O and (Zn(NO 3 )·6H 2 O respectively, uniformly stirring, dropwise adding ammonia into the mixed solution and magnetically stirring until the pH value of the mixed solution is 12, heating the mixed solution, washing the product obtained with deionized water and ethanol for 2-4 times, and finally drying to obtain a ZnSnO 3 @fine composite. With the dielectric property and conductivity adjusted, the composite prepared reveals a good impedance matching performance and an improved MA performance.

First claim

What is claimed is:

1. A method for preparing a ZnSnO 3 composite coated with highly graphitized fine ash, characterized by comprising the following method steps:
S1: preparing fine ash with gasified fine slag of pulverized coal as a raw material by performing a three-step acidification method;
S2: adding the fine ash preparing in the S1 into a container filled with distilled water, ultrasonically dispersing for 20-40 min, adding equal molar masses of SnCl 4 ·5H 2 O and Zn(NO 3 )·6H 2 O respectively, uniform stirring, dropwise adding ammonia into the mixed solution and magnetically stirring until the pH value of the mixed solution is 12, heating the mixed solution, washing the product obtained with deionized water and ethanol 2-4 times, and finally drying to obtain the ZnSnO 3 composite coated with highly graphitized fine ash.

2. The method according to claim 1 , characterized in that the fine ash in the S1 is prepared in the following method steps:
S11: with the gasified fine slag of pulverized coal as a raw material, mixing with hydrochloric acid solution in a container, stirring and filtering;
S12: washing the solid filtered in the S11 to neutral with water, and drying;
S13: mixing the solid dried in the S12 with hydrofluoric acid solution in a container, stirring, filtering, washing to neutral with water, and drying; and
S14: mixing the solid dried in the S13 with hydrochloric acid solution in a container, stirring, filtering, washing to neutral with water, and drying to obtain fine ash.

3. The method according to claim 2 , characterized in that the concentration of the hydrochloric acid solution is 5 mol/L, and the mass-to-volume ratio of the gasified fine slag to the hydrochloric acid solution is 1 g:(8-12) mL in the S11.

4. The method according to claim 2 , characterized in that the mass fraction of the hydrofluoric acid solution is 40%, and the mass-to-volume ratio of the gasified fine slag to the hydrofluoric acid solution is 1 g:(8-12) mL in the S13.

5. The method according to claim 2 , characterized in that the mixing temperature is 50-70° C. in the S11, the S13 and the S14.

6. The method according to claim 2 , characterized in that the drying condition is drying at 100-110° C. for 10-14 h in the S12, the S13 and the S14.

7. The method according to claim 1 , characterized in that the mass molar ratio of the fine ash, SnCl 4 ·5H 2 O and Zn(NO 3 ) 2 ·6H 2 O is 1 mg:0.0125-0.0375 mol:0.0125-0.0375 mol in the S2.

8. The method according to claim 1 , characterized in that the mixed solution is reacted at 140-160° C. for 8-12 h in the S2.

9. The method according to claim 1 , characterized in that the drying condition is vacuum drying at 50-70° C. for 10-14 h in the S2.

Assignees

• Institute Of Energy Hefei Comprehensive Nat Science Center
• Univ Anhui Sci & Technology

Inventors

• Gao Shengtao
• Zhang Yuanchun
• Wu Chengli
• Li Hanxu

Classifications

• H05K9/0081 Primary

  Electromagnetic shielding materials, e.g. EMI, RFI shielding (H05K9/0003 takes precedence) · CPC title

• C01G19/00 Primary

  Compounds of tin · CPC title

• C09C1/04 Primary

  Compounds of zinc {(C09C1/0003, C09C1/0009, C09C1/0015, C09C1/0078 take precedence)} · CPC title

• C09C3/063

  Coating · CPC title

• C01P2004/38

  cube-like · CPC title