Glass article and method of manufacturing the same

Patent metadata

Field	Value
Publication number	US-11760688-B2
Application number	US-202016998062-A
Country	US
Kind code	B2
Filing date	Aug 20, 2020
Priority date	Jan 3, 2020
Publication date	Sep 19, 2023
Grant date	Sep 19, 2023

Abstract

A glass article includes a first surface, a second surface which is opposite the first surface, a first compressive region which extends to a first compression depth in a thickness direction from the first surface, a second compressive region which extends to a second compression depth from the second surface, and a tensile region which is disposed between the first compressive region and the second compressive region. A stress profile of the first compressive region includes a first point and a first inflection point, the first inflection point is located between the first point and the first surface, a depth from the first surface to the first point is 45 to 55% of the first compression depth from the first surface, stress at the first point is greater than 50% of compressive stress of the first surface, and a thickness of the glass article is 0.01 to 0.05 mm.

First claim

What is claimed is:

1. A glass article comprising:
a first surface;
a second surface which is opposite the first surface;
a first compressive region which extends to a first compression depth in a thickness direction of the glass article from the first surface;
a second compressive region which extends to a second compression depth in the thickness direction from the second surface; and
a tensile region which is disposed between the first compressive region and the second compressive region,
wherein a stress profile of the first compressive region comprises a first point and a first inflection point, the first inflection point is located between the first point and the first surface, a depth from the first surface to the first point is about 45 to about 55 percentages (%) of the first compression depth from the first surface, stress at the first point is greater than about 50% of compressive stress at the first surface,
wherein a second point in the first compressive region has 90% of a maximum distribution of potassium ions at a single significant figure, and
a third point, of which a depth from the first surface in the thickness direction is twice as a depth of the second point from the first surface in the thickness direction, has a value equal to 30% of the maximum distribution of potassium ions.

2. The glass article of claim 1 , wherein the stress profile of the first compressive region is convex upward when the stress profile is illustrated as a graph of which x axis represents the thickness direction and y axis represents a stress value.

3. The glass article of claim 2 , wherein a thickness of the glass article is about 0.01 to about 0.05 millimeters (mm), the first compression depth ranges from about 8 micrometers (μm) to about 12 μm, and the compressive stress at the first surface ranges from about 800 megapascals (MPa) to about 1100 MPa.

4. The glass article of claim 3 , wherein stress at the first inflection point is 60% or more of the compressive stress at the first surface.

5. The glass article of claim 4 , further comprising:
a first side surface located between the first surface and the second surface;
a first chamfer surface located between the first side surface and the first surface; and
a second chamfer surface located between the first side surface and the second surface.

6. The glass article of claim 4 , wherein the stress profile of the first compressive region is symmetrical to a stress profile of the second compressive region.

7. The glass article of claim 6 , further comprising hydrogen ions and hydronium ions.

8. The glass article of claim 6 , further comprising impurities, wherein a content of the impurities is about 0.02 percentages by weight (wt %) or more, and the impurities comprise copper ions, iron ions, or tin ions.

9. The glass article of claim 4 , wherein the first compression depth of the first compressive region is greater than the second compression depth of the second compressive region, and a magnitude of the compressive stress at the first surface is greater than a magnitude of compressive stress at the second surface.

10. A glass article comprising:
a first surface;
a second surface which is opposite the first surface;
a first compressive region which extends to a first compression depth in a thickness direction of the glass article from the first surface;
a second compressive region which extends to a second compression depth in the thickness direction from the second surface; and
a tensile region which is disposed between the first compressive region and the second compressive region,
wherein a stress profile of the first compressive region comprises a first point and a first inflection point, the first inflection point is located between the first point and the first surface, a depth from the first surface to the first point is about 45 to about 55 percentages (%) of the first compression depth from the first surface, stress at the first point is greater than about 50% of compressive stress of the first surface, the first compression depth of the first compressive region is greater than the second compression depth of the second compressive region, and a magnitude of the compressive stress at the first surface is greater than a magnitude of compressive stress at the second surface,
wherein a second point in the first compressive region has 90% of a maximum distribution of potassium ions at a single significant figure, and
a third point, of which a depth from the first surface in the thickness direction is twice as a depth of the second point from the first surface in the thickness direction, has a value equal to 30% of the maximum distribution of potassium ions.

11. The glass article of claim 10 , wherein the glass article is formed sequentially through an electric field applying operation in which a negative voltage is applied to the first surface and a positive voltage is applied to the second surface, and a chemical tempering operation.

12. A display device comprising:
a display panel which comprises a plurality of pixels;
a cover window which is disposed on the display panel; and
an optically-clear bonding layer which is disposed between the display panel and the cover window,
wherein the cover window comprises:
a first surface;
a second surface which is opposite the first surface;
a first compressive region which extends to a first compression depth in a thickness direction of the glass article from the first surface;
a second compressive region which extends to a second compression depth in the thickness direction from the second surface; and
a tensile region which is disposed between the first compressive region and the second compressive region,
wherein a stress profile of the first compressive region comprises a first point and a first inflection point, the first inflection point is located between the first point and the first surface, a depth from the first surface to the first point is about 45 to about 55 percentages (%) of the first compression depth from the first surface, stress at the first point is greater than about 50% of compressive stress at the first surface,
wherein a second point in the first compressive region has 90% of a maximum distribution of potassium ions at a single significant figure, and
a third point, of which a depth from the first surface in the thickness direction is twice as a depth of the second point from the first surface in the thickness direction, has a value equal to 30% of the maximum distribution of potassium ions.

13. The display device of claim 12 , wherein a thickness of the cover window is about 0.01 to about 0.05 millimeters (mm), the stress profile of the first compressive region is convex upward when the stress profile is illustrated as a graph of which x axis represents the thickness direction and y axis represents a stress value, the first compression depth ranges from about 8 micrometers (μm) to about 12 μm, the compressive stress at the first surface ranges from about 800 megapascals (MPa) to about 1100 MPa, and stress at the first inflection point is about 60% or more of the compressive stress at the first surface.

14. The display device of claim 13 , wherein the first compression depth of the first compressive region is greater than that the second compression depth of the second compressive region, and a magnitude of the compressive stress at the first surface is greater than a magnitude of compressive stress at the second surface.

Assignees

• Samsung Display Co Ltd

Inventors

• Lee Hoi Kwan

Classifications

• C03C23/007

  by thermal treatment · CPC title

• H10W74/43

  comprising oxides, nitrides or carbides, e.g. ceramics or glasses · CPC title

• G02F1/1333 Primary

  Constructional arrangements; {Manufacturing methods}(G02F1/135, G02F1/136 take precedence) · CPC title

• C03C23/009 Primary

  Poling glass · CPC title

• C03C21/002 Primary

  to perform ion-exchange between alkali ions (C03C21/005 takes precedence) · CPC title