Fiber-optic integrated membrane reactor

Patent metadata

Field	Value
Publication number	US-11760663-B2
Application number	US-202017063510-A
Country	US
Kind code	B2
Filing date	Oct 5, 2020
Priority date	Apr 27, 2016
Publication date	Sep 19, 2023
Grant date	Sep 19, 2023

Abstract

A reactor for water splitting or water treatment includes a first electrode, a second electrode electrically coupled to the first electrode, and a proton exchange membrane separating the first electrode and the second electrode. The first electrode includes a first optical fiber coated with a photocatalytic material.

First claim

What is claimed is:

1. A reactor comprising:
a flexible assembly comprising:
a first electrode layer comprising a multiplicity of first electrodes positioned between a first proton exchange membrane layer and a second proton exchange membrane layer, wherein each of the first electrodes comprises an optical fiber coated with an electrically conductive, photocatalytic material;
a second electrode layer comprising a multiplicity of second electrodes positioned between a third proton exchange membrane layer and a fourth proton exchange membrane layer, wherein each of the second electrodes comprises an optical fiber coated with an electrically conductive, photocatalytic material; and
a third electrode layer positioned between and electrically coupled to the first electrode layer and the second electrode layer, wherein the third electrode layer is a flexible electrically conductive material,

wherein the flexible assembly is in the form of a sheet.

2. The reactor of claim 1 , wherein the flexible assembly is wound around a porous conduit.

3. The reactor of claim 2 , wherein the porous conduit has a first end and a second end.

4. The reactor of claim 3 , further comprising a water inlet, wherein the water inlet is configured to direct water toward the first end of the porous conduit.

5. The reactor of claim 4 , further comprising a water outlet, wherein the reactor is configured to allow water to flow from the first end of the porous conduit toward the second end of the conduit via gravity.

6. The reactor of claim 1 , further comprising a light source coupled to each of the first electrodes and each of the second electrodes.

7. The reactor of claim 6 , wherein the light source is an artificial light source.

8. The reactor of claim 7 , wherein the light source is a light emitting diode.

9. The reactor of claim 1 , wherein each of the first electrodes and second electrodes is configured to be coupled to a sunlight-collecting device.

10. The reactor of claim 1 , wherein each of the first electrodes and second electrodes is configured to be coupled to a laser.

11. The reactor of claim 1 , wherein each of the first electrodes and second electrodes is coated with an electrically conductive material.

12. A method of producing hydrogen and oxygen from water, the method comprising:
providing water to a reactor comprising:
a reservoir; and
a flexible assembly positioned in the reservoir, the flexible assembly comprising:
a first electrode layer comprising a multiplicity of first electrodes positioned between a first proton exchange membrane layer and a second proton exchange membrane layer, wherein each of the first electrodes comprises an optical fiber coated with an electrically conductive, photocatalytic material;
a second electrode layer comprising a multiplicity of second electrodes positioned between a third proton exchange membrane layer and a fourth proton exchange membrane layer, wherein each of the second electrodes comprises an optical fiber coated with an electrically conductive, photocatalytic material; and
a third electrode layer positioned between and electrically coupled to the first electrode layer and the second electrode layer, wherein the third electrode layer is a flexible electrically conductive material,
wherein the flexible assembly is in the form of a sheet and wound around a porous conduit;

providing light into the optical fibers of the first and second electrode layers, thereby yielding photogenerated electrons, wherein the photogenerated electrons flow along the electrically conductive, photocatalytic material of the first and second electrode layers to the third electrode layer; and
converting the water into oxygen gas and hydrogen gas.

13. The method of claim 12 , wherein the water flows through the proton exchange membrane layers from a first end of the reactor to a second end of the reactor via gravity.

14. The method of claim 13 , wherein the oxygen gas exits the reactor at the second end of the reactor.

15. The method of claim 14 , wherein some of the water exits the reactor at the second end of the reactor.

16. The method of claim 13 , wherein the hydrogen gas exits the reactor at the first end of the reactor.

17. The method of claim 16 , wherein the hydrogen gas exits the reactor through the porous conduit.

18. The method of claim 12 , wherein a flow of the water across the proton exchange membrane layers provides turbulence, thereby improving evolution of the hydrogen gas.

19. The method of claim 12 , wherein converting the water into oxygen gas and hydrogen gas comprises producing hydrogen at the third electrode layer using the photogenerated electrons.

Assignees

• Westerhoff Paul K
• Hristovski Kiril D
• Sinha Shahnawaz
• Univ Arizona State

Inventors

• Westerhoff Paul K
• Hristovski Kiril D
• Sinha Shahnawaz

Classifications

• C02F1/467 Primary

  by electrochemical disinfection; {by electrooxydation or by electroreduction} · CPC title

• C02F3/005

  Combined electrochemical biological processes (aeration by electrolytically produced oxygen bubbles C02F3/202) · CPC title

• C02F3/325

  as symbiotic combination of algae and bacteria · CPC title

• C02F2305/023

  Reactive oxygen species, singlet oxygen, OH radical · CPC title

• Y02W10/37

  using solar energy · CPC title