Low-dust silica aerogel blanket and method for manufacturing same

Patent metadata

Field	Value
Publication number	US-11760646-B2
Application number	US-201816762675-A
Country	US
Kind code	B2
Filing date	Sep 19, 2018
Priority date	Nov 16, 2017
Publication date	Sep 19, 2023
Grant date	Sep 19, 2023

Abstract

Provided is a silica aerogel blanket capable of preventing deterioration of heat insulating performance while reducing dust generation, and method for manufacturing the same. The method manufactures a low-dust silica aerogel blanket by separately adding a silica sol to prevent an opacifying agent from being exposed to the surface of the silica aerogel blanket.

First claim

The invention claimed is:

1. A method for manufacturing silica aerogel blanket, the method comprising:
1) Adding a base catalyst to a first silica sol, impregnating a blanket substrate with the first silica sol, and gelling the first silica sol;
2) adding a base catalyst to a second silica sol comprising an opacifying agent, spraying the second silica sol onto the blanket substrate impregnated with the first silica sol and gelling the second silica sol; and
3) adding a base catalyst to a third silica sol, spraying the third silica sol onto the blanket substrate impregnated with the second silica sol and gelling the third silica sol,
wherein the first silica sol and the third silica sol do not further comprise an opacifying agent.

2. The method of claim 1 , wherein a volume ratio of the first silica sol, the second silica sol and the third silica sol is 10-40 vol %:20-80 vol %:10-40 vol %.

3. The method of claim 1 , wherein the opacifying agent is added in an amount of 1-30 wt % with respect to the weight of silica contained in the total silica sol.

4. The method of claim 1 , wherein the second silica sol is sprayed after gelation of the first silica sol is completed, and
the third silica sol is sprayed before the gelation of the second silica sol is completed.

5. The method of claim 1 , wherein the opacifying agent comprises at least one agent selected from the group consisting of TiO 2 , alumina, zirconia (ZrO 2 ), zinc oxide (ZnO), tin oxide (SnO 2 ), iron oxide and carbon black.

6. A silica aerogel blanket, comprising a first silica aerogel layer, a second silica aerogel layer, and a third silica aerogel layer,
wherein the second silica aerogel layer is interposed between the first silica aerogel layer and the third silica aerogel layer, and
the second silica aerogel layer further comprises an opacifying agent,
wherein the first silica aerogel layer and the third silica aerogel layer do not further comprise an opacifying agent.

7. The silica aerogel blanket of claim 6 , wherein a weight ratio of silica contained in the first silica aerogel layer, the second silica aerogel layer, and the third silica aerogel layer is 10-40 wt %:20-80 wt %: 10-40 wt %.

8. The silica aerogel blanket of claim 6 , wherein the opacifying agent is present in an amount of 1-30 wt % with respect to the total weight of silica contained in the first, second, and third silica aerogel layers.

9. The silica aerogel blanket of claim 6 , wherein:
a thickness of the first silica aerogel layer is 1-4 mm;
a thickness of the second silica aerogel layer is 2-8 mm; and
a thickness of the third silica aerogel layer is 1-4 mm.

10. The silica aerogel blanket of claim 6 , wherein the silica aerogel blanket has a weight reduction of 0.5% or less under a vibration condition of 18 Hz/6 hours.

11. An insulating material, comprising:
the silica aerogel blanket of claim 6 ; and
a layer which is impermeable to water and permeable to water vapor on a surface of the silica aerogel blanket.

Assignees

• Lg Chemical Ltd

Inventors

• Oh Myung Eun
• Lee Kyu Reon
• Lee Je Kyun

Classifications

• C01B33/1585 Primary

  Dehydration into aerogels · CPC title

• C01B33/158

  Purification; Drying; Dehydrating · CPC title

• C01P2006/32

  Thermal properties · CPC title

• C04B2111/28

  Fire resistance, i.e. materials resistant to accidental fires or high temperatures · CPC title

• C04B28/26

  Silicates of the alkali metals · CPC title