Configuration for olefins production

Patent metadata

Field	Value
Publication number	US-11753595-B2
Application number	US-202217843875-A
Country	US
Kind code	B2
Filing date	Jun 17, 2022
Priority date	Mar 15, 2019
Publication date	Sep 12, 2023
Grant date	Sep 12, 2023

Abstract

Processes herein may be used to thermally crack various hydrocarbon feeds, and may eliminate the refinery altogether while making the crude to chemicals process very flexible in terms of crude. In embodiments herein, crude is progressively separated into at least light and heavy fractions. Depending on the quality of the light and heavy fractions, these are routed to one of three upgrading operations, including a fixed bed hydroconversion unit, a fluidized catalytic conversion unit, or a residue hydrocracking unit that may utilize an ebullated bed reactor. Products from the upgrading operations may be used as feed to a steam cracker.

First claim

We claim:

1. A system for converting whole crudes and other heavy hydrocarbon streams to produce olefins, the system comprising:
a first integrated separation device for separating a hydrocarbon feedstock into at least a light boiling fraction, a medium boiling fraction, and a high boiling residue fraction;
a first hydroprocessing system configured for hydrotreating the high boiling residue fraction and producing a hydrotreated effluent;
a second integrated separation device configured for separating the hydrotreated and hydrocracked effluent and producing an ultra-low sulfur fuel oil and a hydroprocessed fraction;
a mixing unit configured for combining the medium boiling fraction and the hydroprocessed fraction to produce a mixed medium boiling and hydroprocessed fraction;
a second hydroprocessing system configured for hydrocracking the mixed medium boiling and hydroprocessed fraction and producing a steam cracker feedstream;
a steam cracker unit for converting the steam cracker feedstream and the light boiling fraction into one or more light olefins and a pyrolysis oil.

2. The system of claim 1 , wherein the first integrated separation device is configured to provide the light boiling fraction comprising hydrocarbons having a 95% boiling point temperature in the range from about 130° C. to about 200° C. a hydrogen content of at least 14 wt %, a BMCI of less than 5, an API gravity of greater than 40°, a sulfur content of less than 1000 ppm, a nitrogen content of less than 10 ppm, a viscosity, measured at 40° C., of less than 1 cSt, less than 1 wt % MCRT, and less than 1 ppm total metals, and the high boiling residue fraction comprising hydrocarbons having a 5% boiling point temperature of about 200° C. a hydrogen content of less than 12 wt %, an API gravity of up to about 10°, a viscosity, measured at 100° C., of greater than 100 cSt, greater than 5 wt % MCRT, and greater than 50 ppm total metals.

3. The system of claim 1 , where the first integrated separation device is configured to provide the light boiling fraction comprising hydrocarbons having a 95% boiling point temperature in the range from about 130° C. to about 200° C., a hydrogen content of at least 14 wt %, a BMCI of less than 5, an API gravity of greater than 40°, a sulfur content of less than 1000 ppm, a nitrogen content of less than 10 ppm, a viscosity, measured at 40° C., of less than 1 cSt, less than 1 wt % MCRT, and less than 1 ppm total metals, the medium boiling fraction comprising hydrocarbons having a 5% boiling point temperature in the range from about 130° C. to about 200° C. and a 95% boiling point temperature in the range from about 400° C. to about 600° C., a hydrogen content in the range from about 12 wt % to about 14 wt %, a BMCI in the range from about 5 to less than 50, an API gravity of in the range from about 10° to about 40°, a sulfur content in the range from about 1000 ppm to about 10000 ppm, a nitrogen content in the range from about 1 ppm to about 100 ppm, a viscosity, measured at 40° C., of greater than 1 cSt, less than 5 wt % MCRT, and less than 50 ppm total metals, and the high boiling residue fraction comprising hydrocarbons having a 5% boiling point temperature in the range from about 400° C. to about 600° C., a hydrogen content of less than 12 wt %, a BMCI of greater than 50, an API gravity of less than 10°, a sulfur content of greater than 10000 ppm, a nitrogen content of greater than 100 ppm, a viscosity, measured at 100° C., of greater than 100 cSt, greater than 5 wt % MCRT, and greater than 50 ppm total metals.

4. The system of claim 3 , further comprising a flow line configured to feed the medium boiling fraction to the second hydroprocessing system.

5. The system of claim 4 , wherein the second hydroprocessing system comprises a catalyst configured for converting hydrocarbons in the hydroprocessed fraction and the medium boiling fraction to primarily steam crackable products.

6. A system for the thermal conversion of crude oils to chemicals, the system comprising:
a conditioning system configured for hydrotreating and/or hydrocracking a whole crude, and producing a hydrotreated and/or hydrocracked whole crude; the conditioning system comprising:
a separator configured for separating a pre-heated hydrocarbon feedstock into a light boiling fraction, a medium boiling fraction, and a high boiling residue fraction;
a first hydroprocessing system configured for hydrotreating the high boiling residue fraction and producing a hydrotreated effluent;
an integrated separation device configured for separating the hydrotreated effluent and producing an ultra-low sulfur fuel oil and a hydroprocessed fraction;
a mixing unit configured for combining the medium boiling fraction and the hydroprocessed fraction;
a second hydroprocessing system configured for collectively hydrocracking the medium boiling fraction and the hydroprocessed fraction and producing a hydrotreated and/or hydrocracked steam cracker feed; and

a steam cracker configured for converting the hydrotreated and/or hydrocracked steam cracker feed into one or more chemicals including ethylene, propylene, and butenes;
wherein the conditioning system and the steam cracker are configured to have aligned run times.

7. The system of claim 6 , wherein the whole crude is a condensate hydrocarbon with a boiling range up to 565° C.

8. The system of claim 6 , further comprising:
a heater configured for receiving a crude oil feedstock, producing the pre-heated hydrocarbon feedstock.

9. The system of claim 6 , further comprising a feedline configured for feeding the hydrotreated and/or hydrocracked steam cracker feed and the light boiling fraction to the steam cracker.

10. A system for converting whole crudes and other heavy hydrocarbon streams and producing olefins and/or aromatics, the system comprising:
a conditioning system configured for hydrotreating and/or hydrocracking a whole crude, and producing a hydrotreated and/or hydrocracked whole crude, the conditioning system comprising:
a first integrated separator configured for separating a hydrocarbon feedstock into at least a light boiling fraction, a medium boiling fraction, and a high boiling residue fraction;
a first hydroprocessing unit configured for hydrocracking the high boiling residue and producing a hydrotreated effluent;
a mixing unit configured for combining the medium boiling fraction and the hydrotreated effluent;
a second hydroprocessing unit configured for destructively hydrogenating the medium boiling fraction and hydrotreated effluent, producing a steam cracker feedstream;

a steam cracker configured for receiving the light boiling fraction and the steam cracker feedstream and converting hydrocarbons therein into one or more light olefins and a pyrolysis oil.

11. The system of claim 10 , wherein the first hydroprocessing system is configured for converting hydrocarbons in the high boiling residue fraction to one or more naphtha range hydrocarbons.

12. The system of claim 10 , wherein the first integrated separator comprises:
a heater configured for receiving the hydrocarbon feedstock, producing a pre-heated hydrocarbon feedstock; and
a first separator configured for separating the pre-heated hydrocarbon feedstock into the light boiling fraction and an intermediate fraction.

13. The system of claim 12 , further comprising:
a recycle line configured for recycling the intermediate fraction back to the heater, producing a heated intermediate fraction.

14. The system of claim 13 , further comprising:
a hot hydrogen stripper configured for receiving a hydrogen stream and the intermediate fraction, producing a hot

Assignees

• Lummus Technology Inc
• Saudi Aramco Tech Co
• Chevron Lummus Global Llc

Inventors

• Mukherjee Ujjal
• Al-Sayed Essam Abdullah
• Santos Pedro
• Shaik Kareemuddin
• Maesen Theodorus
• Tamimi Mazin
• Chabot Julie
• Abba Ibrahim
• Sundaram Kandasamy
• Barnawi Sami
• Venner Ronald M
• Akhras Abdul Rahman Zafer

Classifications

• C10G47/00

  Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions (C10G15/00 takes precedence; destructive hydrogenation of non-melting solid carbonaceous or similar materials C10G1/06) · CPC title

• C10G45/00

  Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds · CPC title

• C10G69/14

  plural parallel stages only · CPC title

• C10G9/36 Primary

  with heated gases or vapours · CPC title

• C10G9/16

  Preventing or removing incrustation · CPC title