Composite materials comprising an open-cell polymer matrix and granules embedded therein
US-9056952-B2 · Jun 16, 2015 · US
US11752669B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11752669-B2 |
| Application number | US-202117563682-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 28, 2021 |
| Priority date | Dec 30, 2015 |
| Publication date | Sep 12, 2023 |
| Grant date | Sep 12, 2023 |
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A method of fabricating a vacuum insulated refrigerator structure includes positioning a first barrier film in a female mold cavity. Porous filler material is positioned on the barrier film, and a second barrier film is positioned over the porous filler material. A male mold is brought into contact with the second barrier film to deform and compress the porous filler material into a 3D shape. A vacuum is formed between the first and second barrier films, and the first and second peripheral edge portions are sealed together to form a vacuum insulated core. The vacuum insulated core may be positioned between a liner and a wrapper to form an insulated refrigerator cabinet, door, or other vacuum insulated component.
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What is claimed is: 1. A method of fabricating a vacuum insulated refrigerator structure, the method comprising: providing a female mold having a female mold cavity that is defined by a central surface portion and a plurality of inwardly facing side wall surface portions that are transverse to the central surface portion, the female mold further including edge surfaces extending transversely outward from the inwardly facing side wall surface portions and away from the female mold cavity; providing a male mold having a central surface portion and a plurality of outwardly facing side wall surface portions that are transverse to the central surface portion of the male mold, the male mold further including edge surfaces extending transversely outward from the outwardly facing side wall surface portions; positioning the male and female molds in a vacuum chamber; positioning an impermeable first barrier film having a first peripheral edge portion in the female mold cavity adjacent to the central surface portion and adjacent to the inwardly facing side wall surface portions; positioning the first peripheral edge portion of the impermeable first barrier film over the edge surfaces of the female mold; positioning porous powder filler material on the impermeable first barrier film; followed by positioning an impermeable second barrier film having a second peripheral edge portion over the porous powder filler material whereby the porous powder filler material is disposed between the impermeable first and second barrier films; positioning the second peripheral edge portion of the impermeable second barrier film over the first peripheral edge portion of the impermeable first barrier film; bringing the female and male molds together; causing the male mold to press against the impermeable second barrier film to thereby deform the impermeable second barrier film from a first shape into a second shape; causing the central surface portion of the male mold and at least a portion of the plurality of outwardly facing side wall surface portions of the male mold to enter the female mold cavity thereby causing the second barrier film and the porous powder filler material to deform into a shape including a central portion having a substantially uniform thickness, the shape including at least one sidewall portion extending transversely from the central portion; causing the porous powder filler material to contact the impermeable first and second barrier films; followed by pressing the first and second peripheral edge portions together between the edge surfaces of the male and female molds by bringing the male and female molds together to define a closed configuration; followed by evacuating air between the impermeable first and second barrier films by forming a vacuum in the vacuum chamber; followed by sealing the first and second peripheral edge portions together along a seal line while the male and female molds are in the closed configuration in the vacuum chamber to form a vacuum insulated core; followed by removing the vacuum insulated core from the vacuum chamber; followed by positioning the vacuum insulated core between a wrapper and a liner; and followed by connecting the wrapper to the liner to form the vacuum insulated refrigerator structure. 2. The method of claim 1 , wherein: outer edges of the impermeable first and second barrier films are disposed outside of the male and female molds when the male and female molds are in the closed configuration. 3. The method of claim 1 , wherein: the impermeable second barrier film is planar prior to causing the male mold to press against the impermeable second barrier film. 4. The method of claim 1 , including: positioning the impermeable second barrier film on the male mold before bringing the male and female molds together. 5. The method of claim 1 , wherein: the central surface portion of the female mold cavity is substantially planar and free of protrusions. 6. The method of claim 1 , wherein: the central surface portion of the male mold cavity is substantially planar and free of protrusions. 7. The method of claim 1 , wherein: the inwardly facing side wall surface portions of the female mold are substantially orthogonal to the central surface portion. 8. The method of claim 1 , wherein: the central surface portion of the female mold and the central surface portion of the male mold are rectangular; the impermeable first and second barrier films comprise multilayer films; and the porous powder filler material comprises silica powder. 9. The method of claim 1 , wherein: the vacuum insulated refrigerator structure comprises a door. 10. A method of fabricating a vacuum insulated refrigerator structure, the method comprising: providing a mold tool having a female mold and a male mold, wherein the female mold has a female mold cavity and a central surface portion, and wherein the male mold has a central surface portion; positioning a central portion of a first barrier film in the female mold cavity over the central surface portion; positioning porous powder filler material on the central portion of the first barrier film; positioning a central portion of a second barrier film over the female mold cavity; followed by bringing the female and male molds together; causing the male mold to deform the second barrier film from a first shape into a second shape, the second shape including a generally planar central portion and at least one sidewall portion extending transversely from the generally planar central portion; wherein bringing the female and male molds together further includes causing the female and male molds to compress the porous powder filler material; followed by forming at least a partial vacuum between the first and second barrier films; followed by sealing the first and second peripheral edge portions together to form a vacuum insulated core having porous powder filler material disposed in a vacuum formed between the first and second barrier films; followed by moving the female and male molds apart; followed by removing the vacuum insulated core from the mold tool; followed by positioning the vacuum insulated core between a wrapper and a liner; and connecting the wrapper to the liner to form the vacuum insulated refrigerator structure. 11. The method of claim 10 , wherein: the central surface portion of the female mold cavity is free of protrusions. 12. The method of claim 10 , wherein: the central surface portion of the male mold is free of protrusions. 13. The method of claim 10 , wherein: the central surface portion of the female mold is substantially planar; the female mold includes four inwardly facing side wall surface portions that are transverse to the central surface portion; the central surface portion of the male mold is substantially planar, the male mold including four outwardly facing side wall surface portions that are transverse to the central surface portion of the male mold. 14. The method of claim 10 , wherein: bringing the female and male molds together includes causing the central surface portion of the male mold to be disposed in the female mold cavity. 15. The method of claim 10 , wherein: the first and second barrier films comprise multilayer films. 16. The method of claim 10 , including: causing the first and second peripheral edge portions to overlap prior to sealing the first and second peripheral edge portions together. 17. A method of fabricating a vacuum insulated refrigerator structure, the method comprising: positioning a first b
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