Porous sintered membranes and methods of preparing porous sintered membranes

Patent metadata

Field	Value
Publication number	US-11752471-B2
Application number	US-202016925212-A
Country	US
Kind code	B2
Filing date	Jul 9, 2020
Priority date	Jul 19, 2019
Publication date	Sep 12, 2023
Grant date	Sep 12, 2023

Abstract

Described are porous sintered bodies and methods of making porous sintered bodies by steps that include an injection molding step.

First claim

What is claimed is:

1. A method of making a porous sintered body by particle injection molding a liquid injection composition into a shaped mold cavity, the method comprising:
flowing the liquid injection composition into the shaped mold cavity, wherein the liquid injection composition comprises:
at least one polymeric binder, and
from 20 and 50 percent by volume solid metal particles, based on total volume of the liquid injection composition;

causing the polymeric binder to solidify within the shaped mold cavity to form a solidified injection composition comprising solid binder surrounding the solid metal particles;
removing the solidified injection composition from the mold cavity;
removing the solid binder from the solidified injection composition to form a porous non-sintered body; and
sintering the porous non-sintered body to form a porous sintered membrane, wherein the porous sintered membrane has a porosity in a range from 50 to 80 percent.

2. The method of claim 1 , wherein the solid metal particles are dendritic or fibrous and have an apparent density below 2.0 grams per cubic centimeter.

3. The method of claim 1 , wherein the solid metal particles have a relative apparent density that is in a range from 5 to 35 percent of a theoretical density of the particles.

4. The method of claim 1 , wherein the polymeric binder comprises thermoplastic polymer selected from: a wax, polypropylene, polyethylene glycol, polyoxymethylene, polymethyl methacrylate, ethyl vinyl acetate, and a combination thereof.

5. The method of claim 1 , wherein the polymeric binder comprises a primary binder that can be removed from the solidified injection composition by contacting the solidified injection composition with a liquid solvent selected from water, organic solvent, and a combination thereof, at a temperature in a range from 40 to 80 degrees Celsius.

6. The method of claim 5 , further comprising removing the primary binder from the solidified injection composition by contacting the solidified injection composition with a liquid solvent selected from water and an organic solvent at a temperature in a range from 40 to 100 degrees Celsius.

7. The method of claim 5 , wherein the polymeric binder comprises a secondary binder that can be removed from the solidified injection composition by heating the solidified injection composition to a temperature of not more than 600 degrees Celsius.

8. The method of claim 1 , wherein the porous sintered body is an annular filter membrane having a shape comprising a three-dimensional tube.

9. The method of claim 1 , wherein the porous sintered body is a three-dimensional non-tubular filter membrane.

10. A liquid injection composition comprising:
from 50 to 80 percent by volume polymeric binder, and
from 20 and 50 percent by volume solid metal particles having a relative apparent density in a range from 5 to 35 percent of a theoretical density of the metal particles, based on total volume of the liquid injection composition.

11. The composition of claim 10 , wherein the solid metal particles are dendritic or fibrous and have an apparent density below 2.0 grams per cubic centimeter.

Assignees

• Entegris Inc

Inventors

• Warke Virendra
• Dion Devon N
• Smith David
• Reddy Christopher
• Patrick Meghan

Classifications

• B01D69/06

  Flat membranes · CPC title

• B01D67/00411 Primary

  by sintering · CPC title

• B01D39/20 Primary

  of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires (porous ceramic material {C04B38/00} ; sintering metals C22C1/04; {making porous sintered metal bodies B22F3/10, honeycomb filters B01D46/2418, materials used for filtering exhaust gases of an internal combustion engine F01N3/022, ceramic honeycomb structures C04B38/0006}) · CPC title

• B01D2239/10

  Filtering material manufacturing · CPC title

• B01D2239/1208

  Porosity · CPC title