Methods for pre-lithiating lithium ion batteries

Patent metadata

Field	Value
Publication number	US-11749832-B2
Application number	US-201916689748-A
Country	US
Kind code	B2
Filing date	Nov 20, 2019
Priority date	Nov 20, 2019
Publication date	Sep 5, 2023
Grant date	Sep 5, 2023

Abstract

Lithiated electrodes, electrochemical cells including lithiated electrodes, and methods of making the same are provided. The method includes lithiating at least one electrode in an electrochemical cell by applying current across a first current collector of the at least one electrode to a second current collector of an auxiliary electrode. The electrochemical cell may be disposed within a battery packaging and the auxiliary electrode may be disposed within the battery packaging adjacent to an edge of the electrochemical cell. The at least one electrode may include a first electroactive layer disposed on or near one or more surfaces of the first current collector, and the auxiliary electrode may include a second electroactive layer disposed at or near one or more surfaces of the second current collector. The method may further include extracting the auxiliary electrode from the battery packaging and sealing the battery packaging, which includes the pre-lithiated electrochemical cell.

First claim

What is claimed is:

1. A method of lithiating an electrochemical cell disposed within a battery packaging, the method comprising:
lithiating at least one electrode in the electrochemical cell by applying current across a first current collector of the at least one electrode to a second current collector of an auxiliary electrode, wherein the auxiliary electrode is disposed within the battery packaging adjacent to an edge of the electrochemical cell, the at least one electrode comprises a first electroactive layer disposed on or near one or more surfaces of the first current collector, and the auxiliary electrode comprises a second electroactive layer disposed at or near one or more surfaces of the second current collector; and
after the applying of the current across the first current collector and the second current collector, dividing the packaging into first and second halves, where the first half includes the electrochemical cell including the at least one lithiated electrode and the second half includes the auxiliary electrode.

2. The method of claim 1 , wherein the packaging is divided by using a heat sealer.

3. The method of claim 1 , wherein the second current collector defines a major plane that is substantially perpendicular to a major plane defined by the second electroactive layer and the second current collector passes through the battery packaging and extends out of the battery packaging.

4. The method of claim 3 , wherein the second electroactive layer comprises one or more laminated layers.

5. The method of claim 4 , wherein a first end of the second current collector is disposed between first and second layers of the one or more laminated layers.

6. The method of claim 1 , wherein the second electroactive layer comprises one or more electroactive materials selected from the group consisting of: silicon, silicon oxide, graphite, graphene, carbon nanotubes (CNTs), lithium titanium oxide (Li 4 Ti 5 O 12 ), vanadium oxide (V 2 O 5 ), tin oxide (SnO), titanium dioxide (TiO 2 ), iron sulfide (FeS), lithium metal, and combinations thereof.

7. The method of claim 1 , wherein the second electroactive layer comprises one or more electroactive materials selected from the group consisting of: LiNi x Mn y Co 1-x-y O 2 (where 0≤x≤ 1 and 0≤ y≤1), LiNi x Mn 1-x O 2 (where 0≤ x≤1), Li 1+x MO 2 (where M is one of Mn, Ni, Co, and Al and 0≤x≤1), Li 2 MnO 3 , LiMn 2 O 4 , LiNi 0.5 Mn 1.5 O 4 , LiV 2 (PO 4 ) 3 , LiFePO 4 , LiCOPO 4 , LiMnPO 4 , LiVPO 4 F, LiFeBO 3 , LiCoBO 3 , LiMnBO 3 , Li 2 FeSiO 4 , Li 2 MnSiO 4 , LiMnSiO 4 F, LiFeSiO 4 , LiFe 0.5 M 0.5 SiO 4 (where M is one of magnesium (Mg) and aluminum (Al)), and combinations thereof.

8. The method of claim 1 , wherein the second electroactive layer is porous and has a porosity greater than or equal to about 10 vol. % to less than or equal to about 60 vol. %.

9. The method of claim 1 , wherein the second electroactive layer comprises one or more electrically conductive materials.

10. The method of claim 1 , wherein the second electroactive layer comprises one or more binders selected from poly(tetrafluoroethylene) (PTFE), sodium carboxymethyl cellulose (CMC), styrene-butadiene rubber (SBR), poly(vinylidene fluoride) (PVDF), nitrile butadiene rubber (NBR), styrene ethylene butylene styrene copolymer (SEBS), styrene butadiene styrene copolymer (SBS), lithium polyacrylate (LiPAA), sodium polyacrylate (NaPAA), sodium alginate, lithium alginate, and ethylene propylene diene monomer (EPDM).

11. The method of claim 1 , wherein the current is a constant current greater than or equal to about C/100 to less than or equal to about 10C.

12. A method of pre-lithiating an electrochemical cell including at least one electrode comprising a first current collector, the method comprises:
disposing within a battery packaging an auxiliary electrode adjacent to an edge of the electrochemical cell, wherein the auxiliary electrode comprises an electroactive layer and a second current collector extending perpendicularly from the electroactive layer, wherein a first end of the second current collector interfaces with the electroactive layer and a second end of the second current collector extends out of the battery packaging;
applying a current across the first current collector and the second current collector so as to pre-lithiate the at least one electrode; and
extracting the auxiliary electrode from the battery packaging.

13. The method of claim 12 , wherein extracting includes concurrently dividing the battery packaging into first and second halves and heat sealing at least one of the first and second halves, wherein the first half of the battery packaging includes the electrochemical cell including the at least one pre-lithiated electrode and the second half of the battery packaging includes the auxiliary electrode.

14. The method of claim 12 , wherein the electroactive layer comprises one or more laminated layers, wherein each of the laminated layer comprises one or more electroactive materials selected from the group consisting of: LiNi x Mn y Co 1-x-y O 2 (where 0≤x≤1 and 0≤y≤1), LiNi x Mn 1-x O 2 (where 0≤x≤1), Li 1+x MO 2 (where M is one of Mn, Ni, Co, and Al and 0≤x≤1), Li 2 MnO 3 , LiMn 2 O 4 , LiNi 0.5 Mn 1.5 O 4 , LiV 2 (PO 4 ) 3 , LiFePO 4 , LiCoPO 4 , LiMnPO 4 , LiVPO 4 F, LiFeBO 3 , LiCoBO 3 , LiMnBO 3 , Li 2 FeSiO 4 , Li 2 MnSiO 4 , LiMnSiO 4 F, LiFeSiO 4 , LiFe 0.5 M 0.5 SiO 4 (where M is one of magnesium (Mg) and aluminum (Al)), silicon, silicon oxide, graphite, graphene, carbon nanotubes (CNTs), lithium titanium oxide (Li 4 Ti 5 O 12 ), vanadium oxide (V 2 O 5 ), tin oxide (SnO), titanium dioxide (TiO 2 ), iron sulfide (FeS), lithium metal, and combinations thereof.

15. The method of claim 12 , wherein the electroactive layer comprises one or more laminated layers and the first end of the second current collector is disposed between first and second layers of the one or more laminated layers.

16. The method of claim 12 , wherein the electroactive layer is porous and has a porosity greater than or equal to about 10 vol. % to less than or equal to about 60 vol. %.

17. The method of claim 12 , wherein the electroactive layer further comprises one or more electrically conductive materials.

18. The method of claim 12 , wherein the electroactive layer further comprises one or more binders selected from poly(tetrafluoroethylene) (PTFE), sodium carboxymethyl cellulose (CMC), styrene-butadiene rubber (SBR), poly(vinylidene fluoride) (PVDF), nitrile butadiene rubber (NBR), styrene ethylene butylene styrene copolymer (SEBS), styrene butadiene styrene copolymer (SBS), lithium polyacrylate (LiPAA), sodium polyacrylate (NaPAA), sodium alginate, lithium alginate, and ethylene propylene diene monomer (EPDM).

19. The method of claim 12 , wherein the current is a constant current greater than or equal to about C/100 to less than or equal to about 10C.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Xiao Xingcheng
• Yang Xingyi
• Verbrugge Mark W
• K Raghunathan
• Zhang Qinglin

Classifications

• H01M10/0525 Primary

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• C01G53/50

  of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 · CPC title

• H01M4/13 Primary

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title

• H01M4/139

  Processes of manufacture · CPC title

• H01M4/485

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title