Method for designing formula of water-based printing ink based on low-field nuclear magnetic resonance

Patent metadata

Field	Value
Publication number	US-11747255-B2
Application number	US-202016947207-A
Country	US
Kind code	B2
Filing date	Jul 23, 2020
Priority date	Sep 6, 2019
Publication date	Sep 5, 2023
Grant date	Sep 5, 2023

Abstract

The low-field nuclear magnetic resonance (LF-NMR) is used in the design of a formula of a water-based printing ink and selection of the water-based printing ink or a wetting agent. The water-based printing ink or the wetting agent is quickly selected through the inversion data of an LF-NMR transverse relaxation time (T2). By using LF-NMR to detect the distribution of water in the water-based printing ink or wetting agent, the water-based printing ink is quickly detected in real-time and a high-quality water-based printing ink is selected, which contributes to the design and development of water-based printing inks. The state of water in the ink also is adjusted based on the relationship between the distribution state of water in the printing ink and the definition of the printed pattern, thereby ensuring the definition of the printed pattern.

First claim

What is claimed is:

1. A method for designing a formula of a water-based printing ink based on low-field nuclear magnetic resonance (LF-NMR), comprising the following steps:
(1) acquiring LF-NMR echo signals of the water-based printing ink by using a Carr-Purcell-Meiboom-Gill (CPMG) pulse sequence to obtain an echo attenuation curve, wherein the CPMG pulse sequence has the following parameters: 90° pulse width P1: 8.0 μs, 180° pulse width P2: 15 μs, waiting time: 12,000.00 ms, analog gain 20.0, digital gain: 3, preamp gain: 1, number of scans: 4, number of echoes: 12,000, receiver bandwidth: 100 KHz, and radio frequency delay: 0.150 ms;
(2) deriving a spectral curve of a transverse relaxation time T 2 by using an inversion algorithm thereof based on the echo attenuation curve;
(3) determining moisture retention and/or fluidity of the water-based printing ink according to a peak area and a displacement of immobile water and free water in the spectral curve of the transverse relaxation time T 2 ; stopping adjusting the formula of the water-based printing ink if the moisture retention and/or fluidity meets a target value; proceeding to step (4) if the moisture retention and/or fluidity does not meet the target value; and
(4) adjusting the formula of the water-based printing ink, and returning to step (1).

2. A method for selecting a water-based printing ink based on low-field nuclear magnetic resonance (LF-NMR), comprising the following steps:
(1) acquiring LF-NMR echo signals of one or more water-based printing inks by using a Carr-Purcell-Meiboom-Gill (CPMG) pulse sequence to obtain an echo attenuation curve, wherein the CPMG pulse sequence has the following parameters: 90° pulse width P1: 8.0 μs, 180° pulse width P2: 15 μs, waiting time: 12,000.00 ms, analog gain: 20.0, digital gain: 3, preamp gain: 1, number of scans: 4, number of echoes: 12,000, receiver bandwidth: 100 KHz, and radio frequency delay: 0.150 ms;
(2) deriving a spectral curve of a transverse relaxation time T 2 by using an inversion algorithm thereof based on the echo attenuation curve; and
(3) determining moisture retention and/or fluidity of the water-based printing inks according to a peak area and a displacement of immobile water and free water in the spectral curve of the transverse relaxation time T 2 , and selecting a water-based printing ink with moisture retention and/or fluidity meeting a target value.

3. A method for selecting a wetting agent based on low-field nuclear magnetic resonance (LF-NMR), comprising the following steps:
(1) acquiring LF-NMR echo signals of an aqueous solution of one or more wetting agents by using a Carr-Purcell-Meiboom-Gill (CPMG) pulse sequence to obtain an echo attenuation curve, wherein the CPMG pulse sequence has the following parameters: 90° pulse width P1: 8.0 μs, 180° pulse width P2: 15 μs, waiting time: 12,000.00 ms, analog gain: 20.0, digital gain: 3, preamp gain: 1, number of scans: 4, number of echoes: 12,000, receiver bandwidth: 100 KHz, and radio frequency delay: 0.150 ms;
(2) deriving a spectral curve of a transverse relaxation time T 2 by using an inversion algorithm thereof based on the echo attenuation curve; and
(3) determining moisture retention and/or fluidity of the wetting agent according to a peak area and a displacement of immobile water and free water in the spectral curve of the transverse relaxation time T 2 , and selecting a wetting agent with moisture retention and/or fluidity meeting a target value.

4. The method according to claim 1 , wherein step (1) further comprises drying the water-based printing ink at 55-65° C. before acquiring the LF-NMR echo signals.

5. The method according to claim 1 , wherein in step (4), the adjusting the formula of the water-based printing ink comprises changing a type and/or amount of a wetting agent.

6. The method according to claim 2 , wherein step (1) further comprises drying the water-based printing ink at 55-65° C. before acquiring the LF-NMR echo signals.

7. The method according to claim 3 , wherein step (1) further comprises drying the wetting agent at 55-65° C. before acquiring the LF-NMR echo signals.

8. The method according to claim 3 , wherein in step (1), the aqueous solution of the wetting agent has a concentration of 5-30 wt %.

Assignees

• Nantong Textile & Silk Industrial Tech Research Institute
• Univ Soochow

Inventors

• Chen Guoqiang
• Gao Chengyong
• Xing Tieling

Classifications

• Y02A90/30

  Assessment of water resources · CPC title

• G01N13/00 Primary

  Investigating surface or boundary effects, e.g. wetting power; Investigating diffusion effects; Analysing materials by determining surface, boundary, or diffusion effects (scanning-probe techniques or apparatus G01Q) · CPC title

• C09D11/38 Primary

  characterised by non-macromolecular additives other than solvents, pigments or dyes · CPC title

• G01N24/08

  by using nuclear magnetic resonance (G01N24/12 takes precedence) · CPC title

• G01R33/448

  Relaxometry, i.e. quantification of relaxation times or spin density (G01R33/50 takes precedence) · CPC title