Method for preparing laminated precursor rolls

Patent metadata

Field	Value
Publication number	US-11746463-B2
Application number	US-201916720025-A
Country	US
Kind code	B2
Filing date	Dec 19, 2019
Priority date	Dec 19, 2019
Publication date	Sep 5, 2023
Grant date	Sep 5, 2023

Abstract

Laminate precursors are prepared by applying an aqueous foamed opacifying composition to a non-woven fabric, drying, optionally applying an anti-blocking material to the dried aqueous foamed opacifying composition, and densifying the dry foamed opacifying layer so that it will have a thickness that is at least 20% less than its thickness before densifying. Each laminate precursor is rolled up for immediate or later use to make laminate decorative articles when the unrolled laminate precursor is laminated with back side of a decorative fabric. The applied aqueous foamed opacifying composition has 35%-70% solids and a foam density of 0.1-0.5 g/cm3. It is composed of (a) porous particles, (b) a binder material, (c) two or more additives comprising at least one foaming surfactant and at least one foam stabilizer, (d) an aqueous medium, and (e) an opacifying colorant that absorbs electromagnetic radiation having a wavelength of 380-800 nm.

First claim

The invention claimed is:

1. A method comprising, in order:
A) independently providing one or more different non-woven fabrics, each non-woven fabric having a face side and a back side;
B) applying an aqueous foamed opacifying composition to the back side of the one or more different non-woven fabrics, the wet coverage of the applied aqueous foamed opacifying composition being the same or different on each of the one or more different non-woven fabrics;
C) drying each applied aqueous foamed opacifying composition to provide a dry coverage of less than or equal to 1000 g/m 2 of a dry foamed opacifying layer having a light blocking value (LBV oc ) of at least 2;
D) optionally, either between the B) applying step and the C) drying step, or immediately after the C) drying step, applying an anti-blocking composition formulation to each applied aqueous foamed opacifying composition to form one or more laminate precursors having an anti-blocking composition back side and a non-woven fabric face side, the one or more laminate precursors comprising one or more different non-woven fabrics on its face side and the same or different dry coverage of applied aqueous foamed opacifying composition on the anti-blocking composition back side;
E) simultaneously with or subsequent to the optional D) applying step, densifying the dry foamed opacifying layer so that it will have a thickness that is at least 20% less than its thickness before densifying;
F) rolling up each of the one or more laminate precursors, to provide one or more laminate precursor rolls,
wherein the aqueous foamed opacifying composition has at least 35% and up to and including 70% solids and a foam density of at least 0.1 g/cm 3 and up to and including 0.5 g/cm 3 , and comprises:
(a) porous particles in an amount of at least 0.05 weight % and up to and including 20 weight %, each porous particle comprising a continuous polymeric phase and discrete pores dispersed within the continuous polymeric phase, the porous particles having a mode particle size of at least 2 μm and up to and including 50 μm and a porosity of at least 20 volume % and up to and including 70 volume %;
(b) a binder material in an amount of at least 15 weight % and up to and including 70 weight %,
(c) two or more additives in an amount of at least 0.0001 weight % and up to and including 30 weight %, the two or more additives comprising at least one foaming surfactant and at least one foam stabilizer,
(d) an aqueous medium, and
(e) an opacifying colorant in an amount of at least 0.0001 weight % and up to and including 0.5 weight %, which opacifying colorant being different materials from the (a) porous particles, (b) binder material, and (c) two or more additives, and which opacifying colorant absorbs electromagnetic radiation having a wavelength of at least 380 nm and up to and including 800 nm,
all amounts of (a) porous particles, (b) binder material, (c) two or more additives, and (e) opacifying colorant being based on the total weight of the aqueous foamed opacifying composition.

2. The method of claim 1 , wherein the optional D) applying step is carried out, so that when the one or more laminate precursors are rolled up, the anti-blocking composition back side is in contact with the face side of a non-woven fabric.

3. The method of claim 1 , further comprising:
G) providing a decorative fabric having a face side and a back side; and
H) unrolling a laminate precursor roll from the one or more laminate precursor rolls and laminating the back side of the decorative fabric to the dry foamed opacifying layer of the unrolled laminate precursor roll,
to form a laminated light-blocking decorative article.

4. The method of claim 2 , further comprising:
G) providing a decorative fabric having a face side and a back side; and
H) unrolling a laminate precursor roll from the one or more laminate precursor rolls and laminating the back side of the decorative fabric to the anti-blocking material back side of the unrolled laminate precursor roll,
to form a laminated light-blocking decorative article.

5. The method of claim 1 , wherein the dry foamed opacifying layer is subjected in the E) densifying step to a densification pressure of at least 15 psi (103.4 kPa) at a temperature of at least 20° C. and up to and including 90° C.

6. The method of claim 3 , wherein the H) laminating step includes curing the dry foamed opacifying layer in the unrolled laminate precursor roll.

7. The method of claim 1 , wherein the C) drying step includes curing the applied aqueous foamed opacifying composition.

8. The method of claim 1 , further comprising:
before the A) providing step, forming the aqueous foamed opacifying composition by aerating an aqueous foamable opacifying composition to have a foam density of at least 0.1 g/cm 3 and up to and including 0.5 g/cm 3 .

9. The method of claim 1 , wherein the one or more different non-woven fabrics is a blended fabric.

10. The method of claim 1 , wherein the one or more different non-woven fabrics is a spunlaced non-woven fabric.

11. The method of claim 3 , wherein the decorative fabric is a woven fabric that is patterned or printed.

12. The method of claim 3 , wherein the decorative fabric is a woven fabric having a repeating design pattern that is woven or embroidered into the decorative fabric.

13. The method of claim 3 , wherein the decorative fabric is a double cloth jacquard.

14. The method of claim 1 , wherein the anti-blocking composition formulation comprises one or more of organic or inorganic particles.

15. The method of claim 3 , wherein either the one or more different non-woven fabrics or the decorative fabric, or both the one or more different non-woven fabrics and the decorative fabric, comprise an antimicrobial agent, a fire retardant, or a soil release agent, or any combination thereof.

16. The method of claim 1 , wherein the (e) opacifying colorant is present in the aqueous foamed opacifying composition in an amount of at least 0.001 weight % and up to and including 0.3 weight %, based on the total weight of the aqueous foamed opacifying composition.

17. The method of claim 1 , wherein the (e) opacifying colorant is a carbon black, a neutral black pigment or a dye other than a carbon black, or a combination of two or more of such materials.

18. The method of claim 1 , wherein the (e) opacifying colorant is located solely in the (a) porous particles.

19. The method of claim 1 , wherein the aqueous foamed opacifying composition further comprises an adhesive material.

20. The method of claim 1 , wherein the (b) binder material has a glass transition temperature (T g ) of less than 25° C.

21. The method of claim 1 , wherein the at least one foaming surfactant and the at least one foam stabilizer are independently one of the following compounds, or a mixture thereof: ammonium stearate, ammonium palmitate, sodium lauryl sulfate, ammonium lauryl sulfate, ammonium or sodium alkyl sulfosuccinate, disodium stearyl sulfosuccinate, diammonium n-octadecyl sulfosuccinamate, ethoxylated alcohols, a fatty acid soap, and a fatty acid condensation product with an alkylene oxide.

Assignees

• Eastman Kodak Co

Inventors

• Nair Mridula
• Herrick Diane Marie

Classifications

• D06M23/04 Primary

  Processes in which the treating agent is applied in the form of a foam · CPC title

• A47H23/08

  Selection of particular materials · CPC title

• C09D5/02

  Emulsion paints {including aerosols} · CPC title

• G02B5/003

  Light absorbing elements · CPC title

• C09D5/024 Primary

  characterised by the additives · CPC title