Method for making antimicrobial article

Patent metadata

Field	Value
Publication number	US-11746462-B2
Application number	US-202217696492-A
Country	US
Kind code	B2
Filing date	Mar 16, 2022
Priority date	Oct 16, 2018
Publication date	Sep 5, 2023
Grant date	Sep 5, 2023

Abstract

A method of making an antimicrobial textile comprising TiO2 nanoparticles is described. The TiO2 nanoparticles are immobilized by first treating a textile with a base, and then contacting with TiO2 nanoparticles in a solution of an alcohol and acid. The textile may be subsequently irradiated with UV light prior to use. The antimicrobial textile shows high effectiveness against the growth and proliferation of microorganisms transmitted within indoor environments.

First claim

The invention claimed is:

1. A method for making an antimicrobial article from a woven cotton textile, the method comprising:
contacting the woven cotton textile with an inorganic base to produce a treated cotton textile;
rinsing the treated cotton textile to produce a rinsed cotton textile;
depositing a TiO 2 coating composition onto the rinsed cotton textile, wherein the TiO 2 coating composition contains TiO 2 nanoparticles, methanol, and an organic acid, and the depositing forms a coated textile, wherein the TiO 2 coating composition fully coats the cotton textile during the depositing and the TiO 2 coating composition contains 60-90 wt % of the organic acid and 10-40 wt % of the methanol relative to a total weight of the TiO 2 coating composition;
irradiating the coated textile with a UV light to form an antimicrobial textile, wherein the irradiating forms hydrogen bonds between the TiO 2 nanoparticles and surfaces of individual fibrils of the cotton textile; and
forming a bandage, a cast, a gown, a lab coat, a mask, a face covering, a bedcovering, or a head covering from the antimicrobial textile to make the antimicrobial article;
wherein the TiO 2 coating composition contains the TiO 2 nanoparticles at a concentration of 10-100 ppm by weight, and the TiO 2 nanoparticles are anatase TiO 2 nanoparticles having an average particle diameter of less than 21 nm.

2. The method of claim 1 , wherein the antimicrobial textile contains the TiO 2 nanoparticles at a weight percentage of 0.01-2.00 wt % relative to a total weight of the antimicrobial textile.

3. The method of claim 1 , wherein the woven cotton textile consists essentially of cotton fiber.

4. The method of claim 1 , wherein the antimicrobial textile comprises fibers having a surface area in which 15-40% of the surface area is covered by TiO 2 nanoparticles.

5. The method of claim 1 , wherein the antimicrobial textile has an antimicrobial activity at least 100 times greater than a second textile that was treated with an essentially identical method that did not have TiO 2 nanoparticles, when the antimicrobial textile and the second textile are contacted with similar bacteria and/or fungal cells and a growth medium.

6. The method of claim 5 , wherein the antimicrobial textile and the second textile are contacted with similar bacteria, which are gram-positive cocci.

7. The method of claim 5 , wherein the antimicrobial textile and the second textile are contacted with similar fungal cells, which are yeast cells.

Assignees

• Univ Imam Abdulrahman Bin Faisal

Inventors

• Salama Khaled
• Al Jindan Reem Y

Classifications

• D06M11/46 Primary

  Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates · CPC title

• D06M10/001

  Treatment with visible light, infrared or ultraviolet, X-rays · CPC title

• D06M10/06

  Inorganic compounds or elements · CPC title

• D06M10/08

  Organic compounds · CPC title

• D06M11/38

  Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table · CPC title