Water electrolysis system and control method thereof

Patent metadata

Field	Value
Publication number	US-11746430-B2
Application number	US-202016990589-A
Country	US
Kind code	B2
Filing date	Aug 11, 2020
Priority date	Feb 14, 2020
Publication date	Sep 5, 2023
Grant date	Sep 5, 2023

Abstract

Disclosed are a water electrolysis system and a control method thereof. The water electrolysis system includes: i) a water electrolysis stack including active electrodes receiving an electrolyte and producing hydrogen and oxygen by electrolyzing the electrolyte; ii) a gas-liquid separation device receiving a product produced from the water electrolysis stack, separating the product into an electrolyte, oxygen, and hydrogen, and discharging the electrolyte, oxygen, and hydrogen; iii) a hydrogen sensor measuring a concentration of hydrogen in oxygen discharged from the gas-liquid separation device or a concentration of hydrogen in a circulating electrolyte; and iv) an electrolyte re-supplying module replenishing the electrolyte discharged from the gas-liquid separation device with water and then re-supplying the electrolyte to the water electrolysis stack, and selectively raising a temperature of the electrolyte on the basis of the concentration of hydrogen measured by the hydrogen sensor to remove gas in the electrolyte.

First claim

What is claimed is:

1. A water electrolysis system comprising:
a water electrolysis stack comprising active electrodes receiving an electrolyte and producing hydrogen and oxygen by electrolyzing the electrolyte;
a gas-liquid separation device receiving a product produced from the water electrolysis stack, separating the product into an electrolyte, oxygen, and hydrogen, and discharging the electrolyte, oxygen, and hydrogen;
a hydrogen sensor measuring a concentration of hydrogen in oxygen discharged from the gas-liquid separation device or a concentration of hydrogen in a circulating electrolyte; and
an electrolyte re-supplying module replenishing the electrolyte discharged from the gas-liquid separation device with water and then re-supplying the electrolyte to the water electrolysis stack, and selectively raising a temperature of the electrolyte on the basis of the concentration of hydrogen measured by the hydrogen sensor to remove gas in the electrolyte.

2. The water electrolysis system of claim 1 , further comprising a controller controlling the electrolyte re-supplying module, controlling a first channel through which the electrolyte circulating through the electrolyte re-supplying module is supplied on the basis of the concentration of hydrogen measured by the hydrogen sensor, and controlling a heating temperature of the electrolyte.

3. The water electrolysis system of claim 2 , wherein the controller controls the electrolyte re-supplying module to heat the electrolyte circulating through the electrolyte re-supplying module to a temperature equal to or greater than a normal operating temperature to remove a residual gas dissolved in the electrolyte, replenish the electrolyte with the water, and then supply the electrolyte to the water electrolysis stack, when the concentration of hydrogen measured by the hydrogen sensor is equal to or greater than a reference value, and
the controller controls the electrolyte re-supplying module to maintain the electrolyte circulating through the electrolyte re-supplying module at the normal operating temperature, replenish the electrolyte with the water, and then supply the electrolyte to the water electrolysis stack, when the concentration of hydrogen measured by the hydrogen sensor is less than the reference value.

4. The water electrolysis system of claim 3 , wherein the controller controls the electrolyte re-supplying module to maintain the electrolyte circulating through the electrolyte re-supplying module at the normal operating temperature of the water electrolysis system, and controls the electrolyte re-supplying module to heat the electrolyte to the temperature equal to or greater than the normal operating temperature in a case of heating the electrolyte.

5. The water electrolysis system of claim 4 , wherein the normal operating temperature of the water electrolysis system is about 60° C. or greater and about 80° C. or less.

6. The water electrolysis system of claim 4 , wherein the controller controls the electrolyte re-supplying module to heat the electrolyte to a temperature of about 100° C. or greater in a case of heating the electrolyte.

7. The water electrolysis system of claim 1 , wherein the electrolyte re-supplying module controls a heating temperature of the electrolyte on the basis of a concentration of electrolyte.

8. The water electrolysis system of claim 1 , wherein the electrolyte re-supplying module comprises a first heat exchange unit heating the electrolyte discharged from the gas-liquid separation device to raise the temperature of the electrolyte and replenishing the electrolyte with the water and a second heat exchange unit connected to the first heat exchange unit, replenishing the electrolyte supplied from the first heat exchange unit with the water, and then supplying the electrolyte to the water electrolysis stack.

9. The water electrolysis system of claim 8 , wherein the electrolyte re-supplying module further comprises a branch point which is formed on a connection line between the first heat exchange unit and the second heat exchange unit and at which the electrolyte bypasses the second heat exchange unit to be introduced into the water electrolysis stack, such that the electrolyte passing through the first heat exchange unit is introduced into the second heat exchange unit or bypasses the second heat exchange unit to be directly introduced into the water electrolysis stack.

10. The water electrolysis system of claim 9 , wherein the electrolyte re-supplying module further comprises a first control valve provided at a branch point at which the electrolyte is branched from the first heat exchange unit to the second heat exchange unit or the water electrolysis stack and controlling a second channel through which the electrolyte is supplied.

11. The water electrolysis system of claim 10 , wherein the electrolyte re-supplying module further includes a water tank in which the water to be supplied to the electrolyte is stored and connected to the first heat exchange unit and the second heat exchange unit, and
the water tank is connected to the first heat exchange unit and the second heat exchange unit so that the water discharged from the water tank is selectively branched into the first heat exchange unit or the second heat exchange unit.

12. The water electrolysis system of claim 11 , wherein the electrolyte re-supplying module further includes a second control valve provided at a point at which the water is branched from the water tank into the first heat exchange unit or the second heat exchange unit and controlling a third channel through which the water is supplied.

13. The water electrolysis system of claim 12 , wherein when the concentration of hydrogen measured by the hydrogen sensor is a reference value or greater,
the first control valve controls the second channel so that the first heat exchange unit and the second heat exchange unit are connected to each other, such that the electrolyte is heated in the first heat exchange unit to remove a residual gas dissolved in the electrolyte and is then introduced into the second heat exchange unit, and
the second control valve controls the third channel so that the water tank and the second heat exchange unit are connected to each other, such that the electrolyte passing through the first heat exchange unit is replenished with the water in the second heat exchange unit and is then supplied to the water electrolysis stack.

14. The water electrolysis system of claim 13 , wherein the first heat exchange unit heats the electrolyte at a high temperature so that the residual gas dissolved in the electrolyte is discharged.

15. The water electrolysis system of claim 12 , wherein when the concentration of hydrogen measured by the hydrogen sensor is less than the reference value, the second control valve controls the third channel so that the water tank and the first heat exchange unit are connected to each other, such that the water is introduced into the first heat exchange unit to be replenished in the electrolyte, and the first control valve controls the second channel so that the first heat exchange stack and the water electrolysis stack are connected to each other, such that the electrolyte passing through the first heat exchange unit bypasses the second heat exchange unit to be supplied to the water electrolysis stack.

Assignees

• Hyundai Motor Co Ltd
• Kia Motors Corp

Inventors

• Lee Se Yeong

Classifications

• C25B15/087 Primary

  Recycling of electrolyte to electrochemical cell · CPC title

• B01D19/0073

  by a method not covered by groups B01D19/0005 - B01D19/0042 · CPC title

• C25B1/04 Primary

  by electrolysis of water · CPC title

• C25B9/17

  Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof · CPC title

• C25B9/67

  Heating or cooling means · CPC title